摘要:
A single layer multi-silane coating construct displays controlled covalent attachment between biological materials and microscope slide substrates. Choice of various silanation reagents and their mix ratios provides control over the overall hydrophilic/hydrophobic surface behavior, attachment site density, and reactive moiety type. Both two-dimensional (2d) and three-dimensional (3d) configurations use the same foundation basics. Improved biological adhesion and fluid flow during subsequent processing is achieved. The 3d configuration offers conformal adhesion for those tissue materials that are not monotonically flat as well as multiple point capture of protein/peptides.
摘要:
The hydrophobic, rheologically effective products, based on clays and/or clay minerals with ion-exchange properties, contain quaternary ammonium ions of general formula (I) as cations for generating hydrophobicity, where R1 and R4 may be chemically similar or different and may be a hydrogen atom, a straight-chain or branched, cyclic or heterocyclic, unsubstituted or substituted, saturated or unsaturated hydrocarbon group with 1 to 40 carbon atoms, whereby R1 is not necessarily linked to the nitrogen atom by the COO group, but can be directly linked to the nitrogen atom, R2 is a hydrogen atom, a short chain hydrocarbon group with 1 to 24 carbon atoms, optionally substituted by a hydroxy group, or an aromatic or heterocyclic group, R3 is a hydrogen atom, a straight chain or branched, saturated or unsaturated, hydrocarbon group with 1 to 24 carbon atoms, CaHb represents a direct bond or a straight chain or branched, saturated or unsaturated hydrocarbon group with 1 to 24 carbon atoms and Yn- is an anion with no corroding effect, but rather a protective effect on metals, with the exception of N,N-di(acyloxy-2-ethyl)-N-hydroxy-2-ethyl, N-methyl ammonium-methosulfate, -methophosphate and/or -dimethophosphate.
摘要:
An organophilic clay comprising the reaction product of: (a) a smectite-type clay; and (b) a quaternary ammonium compound or compounds selected from the group consisting of: wherein R1 is an alkyl or aralkyl- ester group having 8 to 30 carbon atoms and R2, R3 and R4 are independently selected from the group consisting of (i) R1, (ii) long chain linear or branched alkyl (including methyl), aliphatic or aromatic groups having 1 to 30 carbon atoms (such groups can also include hydroxylated groups); (iii) aralkyl groups, which are benzyl and substituted benzyl moieties, including such groups having fused ring moieties having linear chains or branches of 1 to 30 carbon atoms; (iv) aryl groups such as phenyl and substituted phenyl including fused ring aromatic substituents; (v) beta, gamma unsaturated groups having six or less carbon atoms or hydroxyalkyl groups having 2 to 6 carbon atoms; and (vi) hydrogen and M is an anion selected from the group consisting of chloride, methylsulfate, acetate, iodide and bromide. The organophilic clay is used in a non-aqueous fluid system such as paints, inks, and coatings to provide rheological properties.
摘要:
An aluminum nitride powder having the surface treated with an organosilane represented by formula, R I a R II b SiY 4-1-b , and/or a partial hydrolysis condensate thereof to acquire excellent moisture-proof, wherein R I represents a 6-20C alkyl group or a group formed by substituting halogen atom or atoms for part or all of the hydrogen atoms attached to carbon atoms of the 6-20C alkyl group, R II represents a 1-20C hydrocarbon group or a group formed by substituting halogen atom or atoms for part or all of the hydrogen atoms attached to carbon atoms of the 1-20C hydrocarbon group, Y represents a hydrolyzable group, a is an integer of 1 to 3 and b is an integer of 0 to 2, provided that a+b is an integer of 1 to 3; and a thermally conductive grease composition comprising (A) 50-95 weight % of the aforementioned surface-treated aluminum nitride powder and (B) 5 to 50 weight % of at least one base oil selected from the group consisting of liquid silicones, liquid hydrocarbons and fluorohydrocarbon oils, and further, if desired, (C) 0-30 weight % of a thicknener selected from the group consisting of zinc oxide, alumina, boron nitride and silicon carbide powders.
摘要翻译:具有由式R a a B b Si Y 4 -1-b表示的有机硅烷表面处理的氮化铝粉末和/或其部分水解缩合物以获得优异的防湿性,其中R 1表示 6-20C烷基或通过用卤原子或原子取代与6-20C烷基的碳原子连接的部分或全部氢原子形成的基团,R II代表1-20C烃基或基团 通过用1-20个碳原子的碳原子连接的部分或全部氢原子代替卤原子或原子而形成,Y表示可水解基团,a为1〜3的整数,b为0〜2的整数 条件是a + b为1〜3的整数。 和导热性油脂组合物,其包含(A)50-95重量%的上述表面处理的氮化铝粉末和(B)5至50重量%的至少一种基础油,其选自液体硅酮,液体烃 和氟代烃油,并且如果需要,(C)0-30重量%的选自氧化锌,氧化铝,氮化硼和碳化硅粉末的增稠剂。
摘要:
A process for producing an organophilic clay comprises:
(a) milling and refining a raw clay selected from the group of smectite clays in order to obtain a milled and refined clay; (b) replacing the exchangeable cations of the refined clay with sodium or ammonium cations, by means of a cation-exchange treatment; (c) contacting the cation-exchanged clay with a sulfonated condensed-ring polycyclic aromatic compound in order to obtain an organophilic clay; and (d) recovering the organophilic clay from the products obtained from the preceding (c) step.
The so obtained organophilic clay is particularly useful as a thixotropic agent in organic vehicles, in particular in oil-base drilling muds.