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公开(公告)号：EP0915854B1
公开(公告)日：2002-09-25
申请号：EP97932833.3
申请日：1997-07-16
申请人： Vantico AG
CPC分类号： C07D233/54 , Y10T428/31511 , Y10T428/31515
摘要： Curable mixtures comprising: a) an epoxy resin having more than 1,2-epoxy group per molecule and b) as curing catalyst, an imidazole compound of formula (I), wherein R1, R2 and R3 are each independtly of the others a hydrogen atom, a halogen atom, alkyl having from 1 to 20 carbon atoms, alkoxy having from 1 to 20 carbon atoms, unsubstituted or halo-, nitro-, C1-4alkyl- or C1-4alkoxy-substituted aralkyl having from 7 to 20 carbon atoms, or unsubstituted or halo-, nitro-, C1-4alkyl- or C1-4alkoxy-substituted aryl having from 6 to 20 carbon atoms, and R4 is alkyl having from 1 to 20 carbon atoms, alkenyl having from 2 to 20 carbon atoms, alkynyl having from 2 to 20 carbon atoms, unsubstituted or halo-, nitro-, C1-4alkyl- or C1-4alkoxy-substituted aralkyl having from 7 to 20 carbon atoms or unsubstituted or halo-, nitro-, C1-4alkyl- or C1-4alkoxy-substituted aryl having from 6 to 20 carbon atoms, are suitable for the manufacture of moulding compounds and coatings, especially for the manufacture of foamed materials.
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公开(公告)号：EP1194437A1
公开(公告)日：2002-04-10
申请号：EP00945913.2
申请日：2000-07-12
申请人： Solvias AG
发明人： PUGIN, Benoît
CPC分类号： C07F9/5027 , C07B35/02 , C07F9/5722 , C07F9/5726 , C07F15/008 , C07F17/02
摘要： Chiral or nonchiral ditertiary diphosphines having solubilizing substituents, for example -NH-C(O)-NH-C(CH2-O-CH2CH2CO2H)3, in the diphosphine framework are excellent ligands for d8 metal complexes which are soluble in polar media, for example water or alcohols, and which can be used as asymmetric or symmetric hydrogenation catalysts for compounds having carbon-carbon or carbon-heteroatom double bonds.
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33.发明公开Catalytic halogenation of activated methylene and methine compound 审中-公开Katalytische Halogenierung von aktivierten Methylen-和Methinverbindungen
公开(公告)号：EP1151980A1
公开(公告)日：2001-11-07
申请号：EP01110667.1
申请日：2001-05-02
申请人： Solvias AG
IPC分类号： C07B39/00 , C07B53/00 , C07C67/307
CPC分类号： C07B53/00 , C07B39/00 , C07B2200/07 , C07C67/307 , C07C69/716
摘要： A process for the halogenation of activated methylene and methine compounds with at least equimolar amounts of an electrophilic halogenation reagent, which comprises reacting said activated methylene and methine compounds in the presence of catalytic amounts of a titanium compound of the formula I or of a titanium compound of the formula II R 1 TiX 1 X 2 X 3 R 2 R 3 TiX 1 X 2 in which
R 1 is chlorine, bromine or iodine, a substituted or unsubstituted cyclopentadienyl or indenyl, and X 1 , X 2 and X 3 are, independently of one another, chlorine, bromine or iodine, or X 1 , X 2 and X 3 are an organic sulfonate group where R 1 is a substituted or unsubstituted cyclopentadienyl or indenyl;
R 2 and R 3 are a substituted or unsubstituted cyclopentadienyl or indenyl, R 2 and R 3 together are a substituted or unsubstituted and bridged or unbridged biscyclopentadienyl or bisindenyl, or R 2 and R 3 together are a substituted or unsubstituted 1,3-, 1,4- or 1,5-diolate, and X 1 and X 2 are, independently of one another, chlorine, bromine or iodine or an organic sulfonate group.
If the diolate is enantiopure, the process is enantioselective on use of racemic activated methine compounds.摘要翻译： 一种用至少等摩尔量的亲电卤化试剂卤化活化的亚甲基和次甲基化合物的方法，其包括在催化量的式I的钛化合物或钛化合物的存在下使所述活化的亚甲基和次甲基化合物反应 式（II）中，R 1是氯，溴或碘，取代或未取代的，其中R 1是氯，溴或碘， 环戊二烯基或茚基，X 1，X 2和X 3彼此独立地为氯，溴或碘，或X 1，X 2和X 3为有机磺酸酯基，其中R 1为取代或未取代的环戊二烯基或茚基; R2和R3是取代或未取代的环戊二烯基或茚基，R2和R3一起是取代或未取代的和桥连的或未桥连的双环戊二烯基或双茚基，或者R 2和R 3一起是取代或未取代的1,3-，1,4-或1 ，5-二醇酯，X 1和X 2彼此独立地为氯，溴或碘或有机磺酸酯基。 如果二醇酯是对映体纯，则该方法对于使用外消旋的活化次甲基化合物是对映选择性的。
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34.发明公开Coupling of nucleophiles, vinyl compounds or CO with water, alcohols or amines to organic compounds 有权通过亲核试剂的偶联，乙烯基化合物或与水，醇或胺CO有机化合物
公开(公告)号：EP1132361A1
公开(公告)日：2001-09-12
申请号：EP01105511.8
申请日：2001-03-05
申请人： Solvias AG
发明人： Indolese, Adriano , Schnyder, Anita
CPC分类号： C07F15/006 , B01J31/1805 , B01J31/181 , B01J31/2226 , B01J31/24 , B01J31/2404 , B01J2231/42 , B01J2231/4211 , B01J2231/4261 , B01J2531/824 , C07B37/04 , C07C2/861 , C07C41/30 , C07C45/68 , C07C67/343 , C07C67/36 , C07C201/12 , C07C209/10 , C07C227/10 , C07C253/30 , C07C2531/24 , C07D213/57 , C07D295/192 , C07C49/782 , C07C69/734 , C07C69/65 , C07C69/76 , C07C69/738 , C07C69/618 , C07C211/55 , C07C229/44 , C07C255/33 , C07C255/57 , C07C205/06 , C07C205/56 , C07C43/205
摘要： Process for the coupling of
a) nucleophiles selected from the group alcohols, thioles, amines, metallised hydrocarbons, CH-acidic compounds and metal cyanides, or of
b) carbon monoxide mixed with water, alcohols, ammonia, primary or secondary amines, to organic compounds selected from the group of leaving-group-containing aromatics, hetero-aromatics with a C-bonded leaving group, aromatic or hetero-aromatic methyl compounds with a leaving group bonded to the methyl group, ethylenically unsaturated organic compounds with a C-bonded leaving group, or organic allyl compounds with a leaving group in allyl position, or
c) vinyl compounds with leaving-group-containing aromatics,
whilst cleaving the leaving group in the presence of Pd complexes with monophospholine ligands as the catalyst, whereby variants b) and c) are carried out in the presence of an inorganic base or organic nitrogen base, the process being characterised in that the Pd complex contains secondary monophosphines with aliphatic, branched or cyclic substituents as ligands.摘要翻译： 对的一连接器）处理的亲核试剂选自醇，thioles，cardamines，镀金属烃，CH-酸性化合物和金属氰化物，或b）将一氧化碳与水，醇，氨，伯或仲cardamines，混合有机 从以下组中选择的化合物含有离去基团的芳族化合物，杂芳族化合物与C键合的离去基团，芳族或杂芳族甲基化合物与键合至甲基，烯属不饱和有机化合物具有结合的C-离去基团 离去基团，或有机烯丙基化合物与离去基团在烯丙基位置上，或c）与含有离去基团的芳族化合物的乙烯基化合物，而裂解离去基团在钯复合物的存在与monophospholine配体作为催化剂，由此，变体b）中 和c）在无机碱或有机氮碱的存在下进行，该方法是DASS中的钯络合物包含具有alipha次级单膦 抽动，支链或环状的取代基作为配体。
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公开(公告)号：EP0918984B1
公开(公告)日：2001-06-27
申请号：EP97941922.3
申请日：1997-08-08
申请人： Zeptosens AG
CPC分类号： G01N21/648 , B01J2219/00707 , G01N21/7703
摘要： An optical detector for carrying out chemical analyses has at least one light source, at least one electric detection unit and at least one measurement cell. One or several optical paths coupled to the measurement cell(s) are formed between the light source(s) and the photoelectric detection unit(s). Separate edge-emitting semiconductor lasers applied on a substrate have been used in the prior art when miniaturising such detection devices arranged in arrays to simultaneously detect a plurality of analytes. The invention provides instead the use of surface-emitting semiconductor lasers as light sources, which have the advantage of being relatively easy to produce and of occupying considerably less space. The process hitherto required to separate the laser from the mother substrate and to glue it on a foreign substrate can be dispensed with in the disclosed detector.
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公开(公告)号：EP1078248A1
公开(公告)日：2001-02-28
申请号：EP99924961.8
申请日：1999-05-12
发明人： BRUNO-RAIMONDI, Alfredo, Emilio , VÖLKEL, Reinhard , DUVENECK, Gert, Ludwig , EFFENHAUSER, Carlo, Stefan , HERZIG, Hans-Peter , DÄNDLIKER, René
IPC分类号： G01N21/77 , G01N27/447
CPC分类号： G01N27/44782 , G01N21/474 , G01N27/44721 , G01N27/44791
摘要： An optical sensing unit is provided which comprises at least one sample measurement cell (20), at least one excitation light source acting upon the or each measurement cell to provide one or more sensor fields defining an array of measurement fields, a photoelectric detector array (17) for detecting the intensity of light emitted from the or each measurement cell in response to excitation light, and means for directing light emitted from each measurement field to a respective portion of the photoelectric detector array (14, 15, 16, 17). The sensing unit may be used in combination with multiplexed waveguide arrays or multiplexed planar capillary chromatography or electrophoresis chips.
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公开(公告)号：EP0571329A3
公开(公告)日：1997-11-26
申请号：EP93810346.2
申请日：1993-05-12
申请人： Japat Ltd
IPC分类号： H01G9/02
摘要： A solid electrolytic capacitor having a solid electrolyte layer, which layer comprises an electrically conductive thermoplastic organic polymer complex having an electric conductivity of 0.1 Scm -1 or more and a glass transition temperature of -100 to 150°C formed on a valve metal foil through a dielectric film. A small and larege-capacity solid electrolytic capacitor having excellent highfrequency characteristic and long-term stability is provided.
摘要翻译： 一种具有固体电解质层的固体电解电容器，该层包含导电性热塑性有机聚合物络合物，其电导率为0.1scm -1以上，玻璃化转变温度为-100〜150℃，形成于 阀金属箔通过电介质膜。 提供了具有优异的高频特性和长期稳定性的小型和容量的固体电解电容器。
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公开(公告)号：EP0625704A3
公开(公告)日：1997-01-02
申请号：EP94810190.2
申请日：1994-03-28
IPC分类号： G01N27/28 , G01N27/49 , G01N33/49 , G01N33/487
CPC分类号： C08F220/14 , G01N27/404 , G01N33/4925 , Y10T29/49117 , Y10T29/5313 , Y10T29/5317 , Y10T29/532 , Y10T29/53204
摘要： A planar, electrochemical sensor having a substrate, conductive strips deposited on the substrate, and a dielectric layer insulating portions of the conductive strips except those portions which define a working electrode and at least one second electrode. The working electrode may be defined by an open printed region of the dielectric, or by a needle-punched or laser-burned hole or opening in the dielectric which exposes a small region of one of the conductive strips. A solid electrolyte contacting the electrodes is covered by a semipermeable membrane which may comprise an acrylonitrile butadiene copolymer or an acrylate-based copolymer. A sample chamber is defined by the membrane, a cover member, and a gasket therebetween, and has a volume of from about 1 to about 2 ml. The gasket is formulated from the highly cross-linked polymerization product of epichlorohydrin. All sensor components are selected such that a sensor operable for at least 2 days under normal conditions is produced.
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公开(公告)号：EP0658906A2
公开(公告)日：1995-06-21
申请号：EP94810713.1
申请日：1994-12-09
申请人： Japat Ltd
IPC分类号： H01B1/12 , C12N11/08 , G01N33/545 , C07K17/08
摘要： A protein adsorbed shapable electroconductive polymer film comprising
1) a film made of a composition comprising
a) at least one polyheteroaromatic compound or aniline in oxidized, polycationic form, and
b) at least one polyanion of a film-forming thermoplastic polymer containing sulfated alcoholic groups and/or sulfonatalkylated groups in repeating structural units, wherein the group -(C n H 2n )- is linear or branched C₂-C₁₂-alkylene containing 2 to 5 C-atoms in the carbon main chain, the alkylene being unsubstituted or substituted by C₁-C₄-alkoxy; and
2) a protein adsorbed on said film.
This protein adsorbed shapable electroconductive polymer film can be suitably applied as biosensors, bioreactor materials and immunosensors.摘要翻译： 一种蛋白质吸附的可成型导电聚合物膜，其包含1）由组合物制成的膜，所述组合物包含a）至少一种多氧杂芳族化合物或氧化聚阳离子形式的苯胺，和b）至少一种含硫酸化醇基团的成膜热塑性聚合物的聚阴离子 和/或磺酸烷基化基团，其中基团 - （CnH2n） - 是在碳主链中含有2至5个C原子的直链或支链C 2 -C 12亚烷基，该亚烷基是未取代的或被C 1 -C 4 烷氧基; 和2）吸附在所述膜上的蛋白质。 这种吸附蛋白质的可成型导电聚合物膜可适合用作生物传感器，生物反应器材料和免疫传感器。
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公开(公告)号：EP0628880A2
公开(公告)日：1994-12-14
申请号：EP94810311.4
申请日：1994-05-27
申请人： Japat Ltd
CPC分类号： C08G73/0273 , C08G18/3293 , C08G73/0644 , G03G5/0521 , G03G5/0589 , G03G5/0622 , G03G5/075 , G03G5/076 , G03G5/078
摘要： A photoreceptor comprises a charge generating layer and a charge transporting layer, the former containing:
(i) as a charge generating compound at least one selected from the group consisting of pyrrolopyrrol, mono- or dithio-pyrrolopyrrol, azo-pigments, quinacridone, phthalocyanine, indanthrone, flavathrone, pyranthrone, anthraquinon, perylene, dioxazine, perinone, thioindigo, isoindoline, isoindolinon and metal complexes ; and
(ii) 1-100 wt%, relative to the weight of the above charge generating compound, of a nitroxyl or hydroxylamino compound composed of at least an unsubstituted or substituted 5-, 6- or 7-membered heterocycle containing a divalent group of Formula
wherein R 1 and R 2 independently represent methyl, ethyl or phenyl or altogether form a 4-12 membered aliphatic ring, L represents an aromatic residue, Y means O. or OH, or an acid addition salts thereof, or
(iia) 0.01-100 wt%, relative to the weight of the above charge generating compound, of a condensation or addition polymer the repeating molecular unit of which contains at least a nitroxyl or hydroxylamino group containing residue, or is substituted by a nitroxyl or hydroxylamino group containing side group, as well as a mixture among them or a mixture with nitroxyl- or hydroxylamine-free components.摘要翻译： 感光体包含电荷产生层和电荷输送层，前者包含：（i）作为电荷产生化合物的至少一种选自吡咯并吡咯，单或二硫代吡咯并吡咯，偶氮颜料，喹吖啶酮，酞菁 ，阴丹酮，黄酮酮，皮蒽酮，蒽醌，苝，二恶嗪，紫环酮，硫靛，异吲哚啉，异吲哚啉酮和金属配合物; 和（ii）相对于上述电荷产生化合物的重量为1-100wt％的硝酰基或羟基氨基化合物，所述硝酰基或羟基氨基化合物由至少一个未取代或取代的含有二价基团的5-，6-或7-元杂环组成 其中R 1和R 2独立地表示甲基，乙基或苯基或者一起形成4-12元脂族环，L表示芳族残基，Y表示O或OH，或其酸加成盐，或（iia）0.01-100 相对于上述电荷产生化合物的重量，其重复分子单元含有至少一个含硝酰氧基或羟氨基残基或被含硝酰氧基或羟氨基基团的侧基取代的缩合或加成聚合物， 以及它们之间的混合物或与不含硝酰基或羟胺组分的混合物。
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