HIGH-CIS POLYBUTADIENE RUBBER IN BENIGN SOLVENTS AND PROCESS FOR PREPARATION THEREOF
    33.
    发明公开
    HIGH-CIS POLYBUTADIENE RUBBER IN BENIGN SOLVENTS AND PROCESS FOR PREPARATION THEREOF 审中-公开
    聚丁二烯高顺式含量无害的溶剂和方法及其制造

    公开(公告)号:EP2523978A2

    公开(公告)日:2012-11-21

    申请号:EP11715278.5

    申请日:2011-01-14

    CPC分类号: C08F136/06 C08F4/12

    摘要: Disclosed is an improved process for production of relatively gel free high cis-1,4-polybutadiene by polymerizing 1,3-butadiene monomer in presence of organocobalt-alkyl aluminum catalysts and a cycloalkane solvent system, the improvement comprising conducting said process in a predetermined sequence avoiding alkyl or alkoxy substituted benzene as polymerization regulator.

    摘要翻译: 公开了通过在有机铝烷基催化剂和环烷烃溶剂体系的存在下聚合1,3-丁二烯单体生产相对无凝胶高顺式1,4-聚丁二烯的改进方法,其改进包括所述传导过程中的预定 避免序列的烷基或烷氧基取代的苯作为聚合调节剂。

    AN IMPROVED PROCESS FOR THE PRODUCTION OF SLOW CRYSTALLIZING POLYESTER RESIN
    36.
    发明公开
    AN IMPROVED PROCESS FOR THE PRODUCTION OF SLOW CRYSTALLIZING POLYESTER RESIN 审中-公开
    改进方法SLOW KRISTALLIERENDEM聚酯树脂的制备

    公开(公告)号:EP1963396A2

    公开(公告)日:2008-09-03

    申请号:EP06842717.8

    申请日:2006-08-14

    IPC分类号: C08G63/16

    摘要: Continuous process for slow crystallizing polyester resin comprising esterification of at least one dicarboxylic acid or mono-esters thereof or di-esters thereof with at least one polyol, melt polymerizing the esterified mixture, preparing uniform crystalline hemispherical prepolymer by particle former process, adding at least one diol having tertiary or quaternary carbon atoms with pendant groups such as neopentyl glycol or 2-methyl-1,3propanediol or any suitable diol at any stage during esterification or melt polymerization but before the particle former process; and solid state polymerizing the prepolymer to obtain high molecular weight slow crystallizing polyester. Using the slow crystallizing polyester resin process to prepare low molecular weight crystalline hemispherical prepolymer of uniform hemispherical shape, uniform particle size, and uniform crystallinity as a precursor to high molecular weight resin or to prepare high molecular weight polyester resin for thick walled transparent preforms, large containers, films or sheets with accepted clarity.