摘要:
Using the process described in the present invention, a gas is produced that is rich in methane and hydrogen and has a content of olefins below 1% v/v, which fully meets the necessary requirements for raw materials used for large-scale production of hydrogen or synthesis gas, in steam reforming units that already exist in a great many oil refineries and petrochemical units. Starting from ethanol, steam, nickel-based catalysts and the use of appropriate conditions of temperature, and H 2 O/ethanol and H 2 /ethanol molar ratios, the invention teaches the production of hydrogen and synthesis gas from biomass, stably for long periods without loss of catalyst performance over time, permitting its industrial application in new units or in existing units. As a solution for the production of ethanol, the present invention claims the replacement of the ZnO-based and hydrofining catalysts of the feed pre-treatment section, with nickel-based catalysts and process conditions in accordance with the present invention.
摘要:
A non-catalytic recuperative reformer has a flue gas flow path for conducting hot flue gas from a thermal process and a reforming mixture flow path for conducting a reforming mixture. At least a portion of the reforming mixture flow path is embedded in the flue gas flow path to permit heat transfer from the hot flue gas to the reforming mixture. The reforming mixture flow path contains substantially no material commonly used as a catalyst for reforming hydrocarbon fuel ( e.g ., nickel oxide, platinum group elements or rhenium), but instead the reforming mixture is reformed into a higher calorific fuel via reactions due to the heat transfer and residence time. In a preferred embodiment, extended surfaces of metal material such as stainless steel or metal alloy that are high in nickel content are included within at least a portion of the reforming mixture flow path.
摘要:
A synthesis gas production apparatus (reformer) to be used for a synthesis gas production step in a GTL (gas-to-liquid) process is prevented from being contaminated by metal components. A method of suppressing metal contamination of a synthesis gas production apparatus operating for a GTL process that includes a synthesis gas production step of producing synthesis gas by causing natural gas and gas containing steam and/or carbon dioxide to react with each other for reforming in a synthesis gas production apparatus in which, at the time of separating and collecting a carbon dioxide contained in the synthesis gas produced in the synthesis gas production step and recycling the separated and collected carbon dioxide as source gas for the reforming reaction in the synthesis gas production step, a nickel concentration in the recycled carbon dioxide is not higher than 0.05 ppmv.
摘要:
When the production of hydrogen and the recovery of carbon dioxide are simultaneously performed by using as a raw material a carbon-containing fuel, the increase of the system cost is suppressed and the efficiency is improved. Disclosed is a method for producing hydrogen and recovering carbon dioxide which method produces hydrogen from a carbon-containing fuel and recovers carbon dioxide, including: a hydrogen-containing gas producing step of obtaining a hydrogen-containing gas that contains hydrogen and carbon dioxide by reforming a carbon-containing fuel; a PSA step of separating, by using a pressure swing adsorption apparatus, the hydrogen-containing gas into a first hydrogen-enriched gas that is a gas enriched in hydrogen and a PSA offgas that is a gas enriched in the components other than hydrogen; and a step of obtaining, by treating the PSA offgas with a hydrogen separation membrane and a carbon dioxide separation membrane, a second hydrogen-enriched gas that is a gas enriched in hydrogen and a carbon dioxide-enriched gas that is a gas enriched in carbon dioxide. Also disclosed is an apparatus for embodying the method.
摘要:
It is avoided that the sulfur compounds originating from the castable is mixed into produced synthesis gas, the mixed sulfur compounds are separated and collected with carbon dioxide, the collected carbon dioxide is recycled as raw material gas and then the sulfur compounds is directly supplied to the reformer to consequently degrade the reforming catalyst in the reformer by sulfur poisoning. The carbon dioxide separated and collected in the carbon dioxide removal step is introduced into the desulfurization apparatus of the desulfurization step or the sulfur compounds adsorption apparatus before being recycled to the reformer to remove the sulfur compounds.
摘要:
Systems and methods are provided for generating and using decarbonized fuel for power generation. In particular, the integrated systems and methods are provided for generating a synthesis gas, removing carbon dioxide from the synthesis gas and using the synthesis gas for producing power.