Abstract:
A method for producing a bisphenol or the like by using a chemical recycling method that is moderate, has a small environmental load, and can efficiently degrade a polycarbonate resin is provided. In addition, a method for producing a recycled polycarbonate resin or the like by using a useful substance such as the bisphenol or the like is provided. A method for producing a bisphenol, comprising degrading a polycarbonate resin in the presence of an aromatic monoalcohol, water, and a catalyst. A method for producing carbon dioxide, comprising recovering carbon dioxide generated by the method for producing a bisphenol. A method for producing a carbonic acid diester by using the carbon dioxide. A method for producing a recycled polycarbonate resin by using the bisphenol and/or the carbonic acid diester. A method for producing an epoxy resin and a method for producing an epoxy resin cured product, by using the bisphenol
Abstract:
The invention relates to a method for producing organic carbonates (R 1 O 2 )CO by means of a catalysed reaction of appropriate alcohols R 1 OH with carbon dioxide, the starting products of the reaction including, as well as ROH and carbon dioxide, the end product (R 1 O 2 )CO, where R 1 is a straight-chain or branched-chain alkyl radical with 1-4 carbon atoms, and compounds of formula alkali 2 CO 3 are used as catalysts, alkali being an element selected from the group containing lithium, sodium, potassium, rubidium and caesium, preferably selected from K 2 CO 3 and Cs 2 CO 3 and mixtures of the two, particularly K 2 CO 3 .
Abstract translation:本发明涉及通过合适的醇R 1 OH与二氧化碳的催化反应制备有机碳酸酯(R 2 O 2)CO的方法,该反应的起始产物包括ROH和二氧化碳,最终产物(R 1 O 2) CO,其中R1是具有1-4个碳原子的直链或支链烷基,并且碱性碳酸二烃基化合物用作催化剂,碱是选自锂,钠,钾,铷和铯的元素 优选选自K 2 CO 3和Cs 2 CO 3以及这两者的混合物,特别是K 2 CO 3。
Abstract:
The present invention relates to a single-pot method for preparing dialkyl carbonates, the method comprises reaction of alkylene oxide with aliphatic or cyclic aliphatic alcohol, using wood ash catalyst, under CO2 pressure and heating the reaction mixture thereof to obtain dialkyl carbonates.
Abstract:
An alkyl tin compound having an alkyl group bonded to a tin atom, wherein the alkyl group is a branched alkyl or cyclic group-substituted alkyl group, the branched alkyl group being an alkyl group branched at at least one carbon atom of the first to third carbon atoms counting from the tin atom, and the cyclic group-substituted alkyl group being an alkyl group having a cyclic group bonded at at least one carbon atom of the first to third carbon atoms counting from the tin atom.
Abstract:
Process for the production of a chemical compound from a carbon dioxide starting material, comprising the steps of a) providing a feed stream consisting mainly of carbon dioxide; b) electrolyzing in an electrolysis stage the carbon dioxide in the feed stream to a first gas stream containing carbon monoxide and a second gas stream containing oxygen, wherein the molar ratio between carbon monoxide and oxygen is about 1:0.5 in an electrolysis stage; c) adjusting the composition of the first gas stream or the second gas stream or both gas streams to include carbon dioxide, either by operating at less than full conversion of CO2 or by sweeping one or both gas streams with a gas containing CO2 or by at some stage between the electrolysis cell and the oxidative carbonylation reactor diluting one or both gas streams with a gas containing CO2; all while maintaining an overall molar ratio of carbon monoxide to oxygen of about 1:0.5; and d) introducing the first and second process stream into a reaction stage and reacting the first and second process stream combined or in succession with a substrate to the chemical compound by means of an oxidative carbonylation reaction with the carbon monoxide and oxygen contained in the process feed stream.
Abstract:
It is an object of the present invention to provide a mixture for recovery utilization or transfer of carbon dioxide gas. According to the present invention, disclosed is a mixture containing carbon dioxide and an alkyltin alkoxide composition containing carbon dioxide complex of an alkyltin alkoxide, the mixture having a composition with a specified ratio.