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    METHOD FOR PRODUCING METHACRYLIC ACID ESTER
    1.
    发明授权
    METHOD FOR PRODUCING METHACRYLIC ACID ESTER 有权

    公开(公告)号：EP2960228B1

    公开(公告)日：2018-09-12

    申请号：EP14775559.9

    申请日：2014-03-19

    Applicant: Sumitomo Chemical Company, Limited

    Inventor： SEKI, Kohei ,  SUZUTA, Tetsuya ,  MIURA, Naoki

    IPC: C07C67/38 ,  C07C69/54 ,  C07C1/24 ,  C07C5/25 ,  C07C11/22 ,  C07C11/14

    CPC classification number: C07C67/38 ,  C07C1/2076 ,  C07C1/24 ,  C07C5/2506 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2523/04 ,  Y02P20/582 ,  C07C69/54 ,  C07C11/24 ,  C07C11/14

    Abstract: The method for producing a methacrylic acid ester of the present invention comprises a dehydration reaction step of having acetone undergo a dehydration reaction in the presence of a dehydration reaction catalyst to obtain a reaction mixture; a propyne/propadiene separation step of separating a mixture containing propyne and propadiene as main components from the obtained reaction mixture; a propyne purification step of separating the separated mixture containing propyne and propadiene as main components into a liquid, gas, or gas-liquid mixture containing propyne as a main component, and a liquid, gas, or gas-liquid mixture containing propadiene as a main component; and a carbonylation reaction step of bringing the obtained liquid, gas, or gas-liquid mixture containing propyne as a main component into contact with carbon monoxide and an alcohol having 1 to 3 carbon atoms in the presence of a catalyst containing at least one selected from the group consisting of Group 8 metal elements, Group 9 metal elements, and Group 10 metal elements to obtain a methacrylic acid ester. According to the method of the present invention, it is possible to provide a method for producing a methacrylic acid ester, which is less likely to receive location restrictions and is also economically and industrially advantageous.

    A CONTINUOUS PROCESS FOR THE CARBONYLATION OF ETHYLENE
    2.
    发明授权
    A CONTINUOUS PROCESS FOR THE CARBONYLATION OF ETHYLENE 有权

    公开(公告)号：EP2513031B1

    公开(公告)日：2018-08-22

    申请号：EP10795449.7

    申请日：2010-12-15

    Applicant: Lucite International UK Limited

    Inventor： EASTHAM, Graham, Ronald ,  TINDALE, Neil

    IPC: C07C67/38 ,  C07C69/24

    CPC classification number: C07C67/38 ,  C07C69/24

    Abstract: A continuous process for carbonylation of ethylene in a liquid phase using carbon monoxide, a co-reactant and a suitable catalyst system, including: (i) forming a liquid phase comprising the co-reactant and a suitable catalyst system obtainable by combining: (a) a group VIII metal/compound; (b) a ligand of general formula (I) and c) optionally, a source of anions; wherein Q1 is optionally phosphorous; (ii) forming a gaseous phase in contact with the liquid phase by providing at least an ethylene gas input feed stream and a carbon monoxide gas input feed stream wherein the ethylene:CO molar ratio entering the liquid phase from the input feed streams is greater than 2:1; (iii) reacting ethylene with carbon monoxide in the presence of the co-reactant, and of the suitable catalyst system in the liquid phase; wherein the ethylene:CO gas molar ratio in the gaseous phase is between 20:1 and 1000:1 or wherein the molar ratio of ethylene:CO in the liquid phase is greater than 10:1.

    VERFAHREN ZUR ALKOXYCARBONYLIERUNG VON OLEFINEN IN EINEM MEDIUM MIT GERINGER BRØNSTEDSÄURENKONZENTRATION
    3.
    发明公开
    VERFAHREN ZUR ALKOXYCARBONYLIERUNG VON OLEFINEN IN EINEM MEDIUM MIT GERINGER BRØNSTEDSÄURENKONZENTRATION 审中-公开
    低浓度含量介质中烯烃的烷氧基羰基化方法

    公开(公告)号：EP3272733A1

    公开(公告)日：2018-01-24

    申请号：EP16180058.6

    申请日：2016-07-19

    Applicant: Evonik Degussa GmbH

    Inventor： FANG, Xiangjie ,  DONG, Kaiwu ,  NEUMANN, Helfreid ,  JACKSTELL, Ralf ,  BELLER, Matthias ,  FRIDAG, Dirk ,  HESS, Dieter ,  DYBALLA, Katrin Marie ,  GEILEN, Frank ,  FRANKE, Robert

    IPC: C07C67/38 ,  C07C69/24

    CPC classification number: C07C67/38 ,  B01J27/13 ,  C07C69/24

    Abstract: Verfahren umfassend die Verfahrensschritte:
    a) Vorlegen einer ethylenisch ungesättigten Verbindung;
    b) Zugabe eines Ligand-Metall-Komplexes umfassend Pd und einen zweizähnigen Phosphinliganden,
    oder Zugabe eines zweizähnigen Phopshinliganden und einer Verbindung, welche Pd umfasst;
    c) Zugabe eines Alkohols;
    d) Zuführen von CO;
    e) Erwärmen des Reaktionsgemisches, wobei die ethylenisch ungesättigte Verbindung zu einem Ester umgesetzt wird,
    wobei dem Reaktionsgemisch weniger als 0,1 mol-%, bezogen auf die Stoffmenge der ethylenisch ungesättigten Verbindung, Brønstedsäuren mit einer Säurestärke von pks≤ 3 zugesetzt werden,
    dadurch gekennzeichnet, dass der Phosphinligand an wenigstens einem Phosphoratom mit wenigstens einem Heteroarylrest substituiert ist.

    Abstract translation: 包括以下工艺步骤的方法：a）烯属不饱和化合物的制备; b）加入包含Pd和双齿膦配体的配体 - 金属络合物，或加入双齿膦酸磷配体和包含Pd的化合物; c）加入酒精; d）供应一氧化碳; E）加热该反应混合物，其中所述烯属不饱和化合物反应为酯，其中所述反应混合物包含小于0.1摩尔％，基于烯属不饱和化合物的摩尔量，具有pks≤3的酸强度布朗斯台德酸的添加，其特征在于 因为膦配体在至少一个磷原子上被至少一个杂芳基取代。

    MONOPHOSPHINVERBINDUNGEN UND DARAUF BASIERENDE PALLADIUM-KATALYSATOREN FÜR DIE ALKOXYCARBONYLIERUNG ETHYLENISCH UNGESÄTTIGTER VERBINDUNGEN
    6.
    发明公开
    MONOPHOSPHINVERBINDUNGEN UND DARAUF BASIERENDE PALLADIUM-KATALYSATOREN FÜR DIE ALKOXYCARBONYLIERUNG ETHYLENISCH UNGESÄTTIGTER VERBINDUNGEN 有权
    MONOPHOSPHINVERBINDUNGEN与基于事实的钯催化剂的烯属不饱和化合物的烷氧基羰基

    公开(公告)号：EP3121181A2

    公开(公告)日：2017-01-25

    申请号：EP16180043.8

    申请日：2016-07-19

    Applicant: Evonik Degussa GmbH

    Inventor： DONG, Kaiwu ,  JACKSTELL, Ralf ,  BELLER, Matthias ,  FRANKE, Robert ,  HESS, Dieter ,  DYBALLA, Katrin Marie ,  FRIDAG, Dirk ,  GEILEN, Frank

    IPC: C07F9/6506 ,  C07F9/58 ,  C07F15/00

    CPC classification number: C07C67/38 ,  B01J31/2295 ,  B01J31/24 ,  B01J31/2404 ,  B01J31/2409 ,  B01J2231/321 ,  B01J2231/49 ,  B01J2531/0208 ,  B01J2531/824 ,  B01J2531/842 ,  C07F9/572 ,  C07F9/58 ,  C07F9/6506 ,  C07F9/65515 ,  C07F9/655345 ,  C07F15/006 ,  C07F17/02 ,  C07C69/24

    Abstract: Die Erfindung betrifft Verbindungen gemäß Formel ( I )

    wobei
    R 1 ausgewählt ist aus -(C 1 -C 12 )-Alkyl, -(C 3 -C 12 )-Cycloalkyl, -(C 3 -C 12 )-Heterocycloalkyl;
    R 2 ausgewählt ist aus -(C 3 -C 12 )-Heterocycloalkyl, -(C 6 -C 20 )-Aryl, -(C 3 -C 20 )-Heteroaryl;
    R 3 -(C 3 -C 20 )-Heteroaryl ist;
    und R 1 , R 2 und R 3 jeweils unabhängig voneinander mit einem oder mehreren Substituenten ausgewählt aus -(C 1 -C 12 )-Alkyl, -(C 3 -C 12 )-Cycloalkyl, -(C 3 -C 12 )-Heterocycloalkyl, -O-(C 1 -C 12 )-Alkyl, -O-(C 1 -C 12 )-Alkyl-(C 6 -C 20 )-Aryl, -O-(C 3 -C 12 )-Cycloalkyl, -S-(C 1 -C 12 )-Alkyl, -S-(C 3 -C 12 )-Cycloalkyl, -COO-(C 1 -C 12 )-Alkyl, -COO-(C 3 -C 12 )-Cycloalkyl, -CONH-(C 1 -C 12 )-Alkyl, -CONH-(C 3 -C 12 )-Cycloalkyl,-CO-(C 1 -C 12 )-Alkyl, -CO-(C 3 -C 12 )-Cycloalkyl, -N-[(C 1 -C 12 )-Alkyl] 2 , -(C 6 -C 20 )-Aryl, -(C 6 -C 20 )-Aryl-(C 1 -C 12 )-Alkyl, -(C 6 -C 20 )-Aryl-O-(C 1 -C 12 )-Alkyl, -(C 3 -C 20 )-Heteroaryl, -(C 3 -C 20 )-Heteroaryl-(C 1 -C 12 )-Alkyl, -(C 3 -C 20 )-Heteroaryl-O-(C 1 -C 12 )-Alkyl, -COOH, -OH, -SO 3 H, -NH 2 , Halogen substituiert sein können.
    Die Erfindung betrifft des Weiteren Pd-Komplexe umfassend die erfindungsgemäße Verbindung sowie deren Verwendung bei der Alkoxycarbonylierung.

    Abstract translation: 本发明涉及的化合物根据式（I）其中R 1选自 - （C 1 -C 12）烷基， - （C 3 -C 12）环烷基， - （C 3 -C 12）杂环烷基; （C 3 -C 12）杂环烷基， - - （C 6 -C 20） - 芳基， - R 2为选自（C 3 -C 20） - 杂芳基; ，R 3 - （C 3 -C 20） - 杂芳基; 且R 1，R 2和R 3各自独立地选自彼此被一个或多个取代基取代的 - （C 1 -C 12）烷基， - （C 3 -C 12）环烷基， - （C 3 -C 12） - 杂环烷基，-O-（C 1 -C 12）烷基，-O-（C 1 -C 12）烷基 - （C 6 -C 20） - 芳基，-O-（C 3 -C 12）环烷基 ，-S-（C 1 -C 12）烷基，-S-（C 3 -C 12）环烷基，-COO-（C 1 -C 12） - 烷基，-COO-（C 3 -C 12） 环烷基，-CONH-（C 1 -C 12）烷基， - CONH-（C 3 -C 12） - 环烷基，CO-（C 1 -C 12）烷基，-CO-（C 3 -C 12）环烷基，-N - [（C 1 -C 12）烷基] 2， - （C 6 -C 20） - 芳基， - （C 6 -C 20） - 芳基 - （C 1 -C 12） 烷基， - （C 6 -C 20）芳基-O-（C 1 -C 12）烷基， - （C 3 -C 20） - 杂芳基， - （C 3 -C 20）杂芳基 - （C 1 -C 12）烷基， - （C 3 -C 20）杂芳基-O-（C 1 -C 12）烷基，-COOH，-OH，-SO 3 H，-NH 2，卤素，可以被取代的 ， 本发明还涉及为Pd包含本发明的化合物和它们在烷氧基羰基用复合物。

    METHOD FOR PREPARING POLYOXYMETHYLENE DIMETHYL ETHER CARBONYL COMPOUND AND METHYL METHOXYACETATE
    8.
    发明公开
    METHOD FOR PREPARING POLYOXYMETHYLENE DIMETHYL ETHER CARBONYL COMPOUND AND METHYL METHOXYACETATE 审中-公开
    制造方法聚甲醛二甲醚羰基化合物和甲氧基乙酸甲酯的

    公开(公告)号：EP3088381A1

    公开(公告)日：2016-11-02

    申请号：EP13900195.2

    申请日：2013-12-23

    Applicant: Dalian Institute Of Chemical Physics Chinese Academy of Sciences

    Inventor： NI, Youming ,  ZHU, Wenliang ,  LIU, Hongchao ,  LIU, Yong ,  LIU, Zhongmin ,  MENG, Shuanghe ,  LI, Lina ,  LIU, Shiping ,  ZHOU, Hui

    IPC: C07C67/37 ,  C07C69/708

    CPC classification number: C07C67/37 ,  C07C67/38 ,  C07C69/708

    Abstract: This invention provides a method for preparing a polyoxymethylene dimethyl ether carbonyl compound and/or methyl methoxyacetate as intermediates for producing ethylene glycol, which comprises passing a raw material: polyoxymethylene dimethyl ether or methylal together with carbon monoxide and hydrogen gas through a reactor carrying an acidic molecular sieve catalyst, and performing a reaction to prepare a corresponding product under an appropriate condition where no other solvent is added, wherein the process of the reaction is a gas-liquid-solid three-phase reaction. In the method of this invention, the raw material of polyoxymethylene dimethyl ether or methylal has a high conversion rate, each product has a high selectivity, the catalyst has a long service life, additional solvents are not required to be used, and reaction conditions are relatively mild. The method of this invention enables continuous production and has the potential for industrial application. Also, ethylene glycol may be produced by subjecting the resultant product to hydrolysis after hydrogenation or hydrogenation after hydrolysis.

    METHOD FOR PRODUCING METHACRYLIC ACID ESTER
    9.
    发明公开
    METHOD FOR PRODUCING METHACRYLIC ACID ESTER 审中-公开
    生产甲基丙烯酸酯的方法

    公开(公告)号：EP2960228A1

    公开(公告)日：2015-12-30

    申请号：EP14775559.9

    申请日：2014-03-19

    Applicant: Sumitomo Chemical Co., Ltd

    Inventor： SEKI, Kohei ,  SUZUTA, Tetsuya ,  MIURA, Naoki

    IPC: C07C67/38 ,  C07C69/54 ,  C07B61/00

    CPC classification number: C07C67/38 ,  C07C1/2076 ,  C07C1/24 ,  C07C5/2506 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2523/04 ,  Y02P20/582 ,  C07C69/54 ,  C07C11/24 ,  C07C11/14

    Abstract: The method for producing a methacrylic acid ester of the present invention comprises a dehydration reaction step of having acetone undergo a dehydration reaction in the presence of a dehydration reaction catalyst to obtain a reaction mixture; a propyne/propadiene separation step of separating a mixture containing propyne and propadiene as main components from the obtained reaction mixture; a propyne purification step of separating the separated mixture containing propyne and propadiene as main components into a liquid, gas, or gas-liquid mixture containing propyne as a main component, and a liquid, gas, or gas-liquid mixture containing propadiene as a main component; and a carbonylation reaction step of bringing the obtained liquid, gas, or gas-liquid mixture containing propyne as a main component into contact with carbon monoxide and an alcohol having 1 to 3 carbon atoms in the presence of a catalyst containing at least one selected from the group consisting of Group 8 metal elements, Group 9 metal elements, and Group 10 metal elements to obtain a methacrylic acid ester. According to the method of the present invention, it is possible to provide a method for producing a methacrylic acid ester, which is less likely to receive location restrictions and is also economically and industrially advantageous.

    Abstract translation: 本发明的甲基丙烯酸酯的制造方法包括：在脱水反应催化剂的存在下使丙酮进行脱水反应而得到反应混合物的脱水反应工序; 从所得的反应混合物中分离以丙炔和丙二烯为主要成分的混合物的丙炔/丙二烯分离工序; 将以丙炔和丙二烯为主成分的分离混合物分离为以丙炔为主成分的液体，气体或气液混合物，以丙二烯为主体的液体，气体或气液混合物的丙炔精制工序 零件; 以及羰基化反应工序，将所得的含有丙炔作为主要成分的液体，气体或气液混合物与含有1〜3个碳原子的一氧化碳和醇在含有选自 由第8族金属元素，第9族金属元素和第10族金属元素组成的组以获得甲基丙烯酸酯。 根据本发明的方法，可以提供生产甲基丙烯酸酯的方法，其不太可能受到位置限制，并且在经济和工业上也是有利的。

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