Rubber-modified polymer composition
    45.
    发明公开
    Rubber-modified polymer composition 失效
    Mit Kautschuk modifizierte Polymerzusammensetzung

    公开(公告)号:EP0785234A1

    公开(公告)日:1997-07-23

    申请号:EP96203694.3

    申请日:1996-12-23

    申请人: DSM N.V.

    摘要: The invention relates to a polymer composition comprising 5 to 79 wt.% of a graft copolymer of vinyl aromatic monomer units and monomer units chosen from the group of C 1 -C 4 alkyl methacrylates, C 1 -C 4 alkyl acrylates, methacrylonitrile and acrylonitrile on a rubber, 90 to 20 wt.% of a thermoplastic polymer with polar groups, and 1 to 50 wt.% of a terpolymer comprising a vinyl aromatic monomer, at least one monomer chosen from the group of C 1 -C 4 alkyl methacrylates, C 1 -C 4 alkyl acrylates, methacrylonitrile and acrylonitrile, and 0.2 to 5 mol% of an α,β-unsaturated compound containing dicarboxylic anhydride, the wt.% of components (A), (B) and (C) being relative to the total weight of components (A), (B) and (C), characterized in that the molar mass of component (C) is comprised between 160,000 g/mol and 230,000 g/mol. The polymer composition has excellent mechanical properties, in particular a high impact resistance at low temperatures.

    摘要翻译: 本发明涉及一种聚合物组合物,其包含5-79重量%的乙烯基芳族单体单元和选自甲基丙烯酸C 1 -C 4烷基酯,丙烯酸C 1 -C 4烷基酯,甲基丙烯腈和丙烯腈的单体单元在橡胶上的接枝共聚物, 90至20重量%的具有极性基团的热塑性聚合物和1至50重量%的包含乙烯基芳族单体的三元共聚物,至少一种选自甲基丙烯酸C 1 -C 4烷基酯,丙烯酸C 1 -C 4烷基酯 ,甲基丙烯腈和丙烯腈,以及0.2至5mol%的含有二羧酸酐的α,β-不饱和化合物,组分(A),(B)和(C)的重量百分数相对于组分(A ),(B)和(C),其特征在于组分(C)的摩尔质量为160,000g / mol至230,000g / mol。 聚合物组合物具有优异的机械性能,特别是在低温下的高耐冲击性。

    TRANSPARENTE FORMMASSEN AUS GLUTARIMIDHALTIGEN POLYMEREN UN STYROL-ACRYLNITRIL-COPOLYMEREN
    46.
    发明授权
    TRANSPARENTE FORMMASSEN AUS GLUTARIMIDHALTIGEN POLYMEREN UN STYROL-ACRYLNITRIL-COPOLYMEREN 失效
    聚合物GLUTARIMIDHALTIGEN联合国苯乙烯 - 丙烯腈共聚物的透明封化合物

    公开(公告)号:EP0654066B1

    公开(公告)日:1997-04-16

    申请号:EP93915946.3

    申请日:1993-07-17

    IPC分类号: C08L25/12 C08L25/14

    摘要: Transparent moulding compounds containing A) 1 to 99 wt % of a copolymer obtainable by polymerizing a mixture of monomers of a1) 50 to 90 wt % of a vinyl aromatic monomer, a2) 10 to 50 wt % acrylonitrile or methacrylonitrile or a mixture thereof, and a3) 0 to 30 wt % of another monomer, and B) 99 to 1 wt % of a polymer based on a vinyl aromatic monomer obtainable by 1) polymerizing a monomer mixture of b1) 60 to 99 wt % of a mixture consisting of b11) 100 to 50 wt % of a vinyl aromatic monomer and b12) 0 to 50 wt % acrylonitrile or methacrylonitrile or a mixture thereof, and b2) 40 to 1 wt % of a C1-C20 alkyl ester of methacrylic or acrylic acid or mixtures of such esters and 2) causing the polymers obtained according to 1) to react with an amine of the general formula (I): RNH2, in which R is C2-C10 alkyl, C5-C8 cycloalkyl, C6-C10 aryl or C6-C10-aryl-C1-C4 alkyl, where these radicals, except for the C2-C10 alkyl radical, can be substituted up to three times by radicals selected from the group consisting of C1-C4 alkyl, C1-C4 alkoxy and halogen.