METHOD FOR PRODUCING 1,1-BIS-(4-HYDROXYPHENYL)-3,3,5-TRIMETHYLCYCLOHEXANE
    51.
    发明公开
    METHOD FOR PRODUCING 1,1-BIS-(4-HYDROXYPHENYL)-3,3,5-TRIMETHYLCYCLOHEXANE 有权
    生产1,1-双(4-羟基苯基)-3,3,5-三甲基环己烷的方法

    公开(公告)号:EP1318133A1

    公开(公告)日:2003-06-11

    申请号:EP00957101.9

    申请日:2000-09-11

    摘要: A process for production of 1,1-bis(4-hydroxyphenyl)-3,3,5-trimethylcyclohexane which comprises reacting phenol with 3,3,5-trimethylcyclohexanone in the presence of an acid catalyst, adding an aqueous solution of an alkali to the resulting reaction mixture to neutralize it, removing a water phase from the thus neutralized reaction mixture, cooling the resulting oil phase to crystallize phenol adduct crystals of 1, 1-bis(4-hydroxyphenyl)-3,3,5-trimethylcyclohexane while obtaining a primary crystallization filtrate, wherein the primary crystallization filtrate is heated to a temperature of 150-250°C in the presence of an alkali catalyst in an inert gas atmosphere under a reduced pressure to thermally decompose 1,1-bis(4-hydroxyphenyl)-3,3,5-trimethylcyclohexane in the primary crystallization filtrate.

    摘要翻译: 一种生产1,1-双(4-羟苯基)-3,3,5-三甲基环己烷的方法,该方法包括在酸催化剂存在下苯酚与3,3,5-三甲基环己酮反应,加入碱水溶液 向所得反应混合物中和,从如此中和的反应混合物中除去水相,冷却所得油相以结晶1,1-双(4-羟基苯基)-3,3,5-三甲基环己烷的苯酚加合物晶体,同时 得到初级结晶滤液,其中初级结晶滤液在碱催化剂存在下在惰性气体气氛中在减压下加热至150-250℃的温度以热分解1,1-双(4-羟基苯基 )-3,3,5-三甲基环己烷在初级结晶滤液中。

    Process for the preparation of condensed cyclopentadiene derivatives, 1, 3 disubstituted derivatives and metallocene type compounds containing them as ligand
    53.
    发明公开
    Process for the preparation of condensed cyclopentadiene derivatives, 1, 3 disubstituted derivatives and metallocene type compounds containing them as ligand 有权
    一种用于制备稠合环戊二烯,1,3-二取代的衍生物,以及含有相同的金属茂类化合物的方法

    公开(公告)号:EP1122229A1

    公开(公告)日:2001-08-08

    申请号:EP01300942.8

    申请日:2001-02-02

    摘要: A process for producing a crosslink-cyclized cyclopentadiene, comprising the steps of reacting a cyclopentenone with an alkali metal hydride to thereby reduce the cyclopentenone (reduction step A) into a cyclopentenol; and reacting the cyclopentenol with a dehydrating agent to thereby dehydrate the cyclopentenol (dehydration step B) into a crosslink-cyclized cyclopentadiene of the general formula (III):
       wherein each of R 1 and R 2 independently represents a hydrogen atom or a linear or branched saturated alkyl group having 1 to 6 carbon atoms, n is an integer of 3 to 10, and the broken line in the 5-membered ring denotes that the 5-membered ring has two double bonds.

    摘要翻译: 一种用于生产交联环化环戊二烯,其包括超过碱金属氢化物反应的环戊烯酮,从而降低环戊烯酮(还原步骤A)到环戊烯醇以下步骤; 并用脱水剂反应的环戊烯醇,从而脱水环戊烯醇(脱水步骤B)到通式的交联环化环戊二烯(III):每个R worin <1>和R <2>unabhängigdarstellt一个 氢原子或直链或具有1至6个碳原子支链的饱和烷基,n表示3至10的整数,并且在5元环中的虚线表示的那样的5元环具有两个双键。

    Process for producing aminophenols
    55.
    发明公开
    Process for producing aminophenols 失效
    用于生产氨基苯酚的。

    公开(公告)号:EP0224625A1

    公开(公告)日:1987-06-10

    申请号:EP85308588.4

    申请日:1985-11-26

    IPC分类号: C07C215/46

    CPC分类号: C07C215/76 Y02P20/582

    摘要: A process for producing an aminophenol, which comprises

    (A) a step of reacting a dihydric phenol with an aminating reagent in the liquid state under heat in the presence of water and a water-soluble catalyst,
    (B) a step of removing the unreacted aminating reagent from the reaction mixture, and then precipitating the crude aminophenol from the reaction mixture from which the aminating reagent has been removed, thereby to obtain a crystallization mixture containing the crude aminophenol.
    (C) a step of separating the crystallization mixture into crystals of the crude aminophenol and the reaction mother liquor containing the catalyst,
    (D) a step of circulating part or the whole of the reaction mother liquor to the aminating step, and
    (E) a step of washing the crude aminophenol crystals with a washing liquor to obtain the washed crude aminophenol crystals and the washing mother liquor, and thereafter separating the aminophenol from the washed crude aminophenol crystals and purifying it.

    METHOD FOR PRODUCING BINAPHTHYL CARBOXYLIC ACID

    公开(公告)号:EP3967677A1

    公开(公告)日:2022-03-16

    申请号:EP20802749.0

    申请日:2020-04-30

    IPC分类号: C07C51/43 C07C59/66

    摘要: An object is to provide a novel method for producing 2,2'-bis(carboxymethoxy)-1,1'-binaphthyl suitable as a resin raw material having excellent optical properties. As a solution, a method for producing 2,2'-bis(carboxymethoxy)-1,1'-binaphthyl, including a step (1) of performing crystallization, wherein the amount of water in a solution containing 2,2'-bis(carboxymethoxy)-1,1'-binaphthyl and one or more selected from linear or branched aliphatic ketones having 5 to 8 carbon atoms is in the range of 2.0 wt% or less and 0.01 wt% or more, is provided.

    AROMATIC POLYCARBONATE OLIGOMER SOLID
    57.
    发明公开

    公开(公告)号:EP3632955A1

    公开(公告)日:2020-04-08

    申请号:EP18806741.7

    申请日:2018-05-17

    IPC分类号: C08G64/04

    摘要: The purpose of the present invention is to provide an aromatic polycarbonate oligomer solid with substantially reduced low-molecular-weight components, no or a substantially reduced amount of chlorine-containing compounds, high loose bulk density, and ease of handling. The aromatic polycarbonate oligomer solid contains a repeating unit represented by general formula (1), has a weight average molecular weight of 500 to 10000, low-molecular-weight components less than or equal to 5.0 area% measured with high-speed liquid chromatography, and a loose bulk density of greater than or equal to 0.30 g/cm 3 .

    AROMATIC POLYCARBONATE OLIGOMER SOLID
    58.
    发明公开

    公开(公告)号:EP3388466A1

    公开(公告)日:2018-10-17

    申请号:EP16872845.9

    申请日:2016-11-28

    IPC分类号: C08G64/06

    CPC分类号: C08G64/06 C08G64/326

    摘要: The purpose of the present invention is to provide an aromatic polycarbonate oligomer solid which has a markedly reduced amount of a low molecular weight component, has no or a markedly reduced amount of chlorine-containing compounds, has a high loose bulk density and is easy to handle. The purpose is met by an aromatic polycarbonate oligomer solid which includes a repeating unit represented by general formula (1), has a weight average molecular weight of 500 to 10000, has a low molecular weight component of less than or equal to 5.0 area% as measured by high performance liquid chromatography, and has a loose bulk density of greater than or equal to 0.20g/cm 3 .