摘要:
A process for production of 1,1-bis(4-hydroxyphenyl)-3,3,5-trimethylcyclohexane which comprises reacting phenol with 3,3,5-trimethylcyclohexanone in the presence of an acid catalyst, adding an aqueous solution of an alkali to the resulting reaction mixture to neutralize it, removing a water phase from the thus neutralized reaction mixture, cooling the resulting oil phase to crystallize phenol adduct crystals of 1, 1-bis(4-hydroxyphenyl)-3,3,5-trimethylcyclohexane while obtaining a primary crystallization filtrate, wherein the primary crystallization filtrate is heated to a temperature of 150-250°C in the presence of an alkali catalyst in an inert gas atmosphere under a reduced pressure to thermally decompose 1,1-bis(4-hydroxyphenyl)-3,3,5-trimethylcyclohexane in the primary crystallization filtrate.
摘要:
A process for producing a crosslink-cyclized cyclopentadiene, comprising the steps of reacting a cyclopentenone with an alkali metal hydride to thereby reduce the cyclopentenone (reduction step A) into a cyclopentenol; and reacting the cyclopentenol with a dehydrating agent to thereby dehydrate the cyclopentenol (dehydration step B) into a crosslink-cyclized cyclopentadiene of the general formula (III): wherein each of R 1 and R 2 independently represents a hydrogen atom or a linear or branched saturated alkyl group having 1 to 6 carbon atoms, n is an integer of 3 to 10, and the broken line in the 5-membered ring denotes that the 5-membered ring has two double bonds.
摘要:
A method of producing styrene derivatives expressed the general formula (2) by reacting a benzaldehyde derivative expressed by the general formula (1) with dibromomethane under the existence of zinc metal as well as an active chloride for producing various types of oxystyrene which are polymerized monomers as a photoresist material used in a high density integrated circuit process from easily available materials which also can easily be handled: (wherein R indicates a an alkyl group, alkoxyalkyl group, an alkylcarbonyl group, an alkoxycarbonyl group, a 5 or 6-atom heterocylclic groups, or an alkylsilyl group); (wherein R indicates any of the same substituents as those described above.)
摘要:
A process for producing an aminophenol, which comprises
(A) a step of reacting a dihydric phenol with an aminating reagent in the liquid state under heat in the presence of water and a water-soluble catalyst, (B) a step of removing the unreacted aminating reagent from the reaction mixture, and then precipitating the crude aminophenol from the reaction mixture from which the aminating reagent has been removed, thereby to obtain a crystallization mixture containing the crude aminophenol. (C) a step of separating the crystallization mixture into crystals of the crude aminophenol and the reaction mother liquor containing the catalyst, (D) a step of circulating part or the whole of the reaction mother liquor to the aminating step, and (E) a step of washing the crude aminophenol crystals with a washing liquor to obtain the washed crude aminophenol crystals and the washing mother liquor, and thereafter separating the aminophenol from the washed crude aminophenol crystals and purifying it.
摘要:
An object is to provide a novel method for producing 2,2'-bis(carboxymethoxy)-1,1'-binaphthyl suitable as a resin raw material having excellent optical properties. As a solution, a method for producing 2,2'-bis(carboxymethoxy)-1,1'-binaphthyl, including a step (1) of performing crystallization, wherein the amount of water in a solution containing 2,2'-bis(carboxymethoxy)-1,1'-binaphthyl and one or more selected from linear or branched aliphatic ketones having 5 to 8 carbon atoms is in the range of 2.0 wt% or less and 0.01 wt% or more, is provided.
摘要:
The purpose of the present invention is to provide an aromatic polycarbonate oligomer solid with substantially reduced low-molecular-weight components, no or a substantially reduced amount of chlorine-containing compounds, high loose bulk density, and ease of handling. The aromatic polycarbonate oligomer solid contains a repeating unit represented by general formula (1), has a weight average molecular weight of 500 to 10000, low-molecular-weight components less than or equal to 5.0 area% measured with high-speed liquid chromatography, and a loose bulk density of greater than or equal to 0.30 g/cm 3 .
摘要:
The purpose of the present invention is to provide an aromatic polycarbonate oligomer solid which has a markedly reduced amount of a low molecular weight component, has no or a markedly reduced amount of chlorine-containing compounds, has a high loose bulk density and is easy to handle. The purpose is met by an aromatic polycarbonate oligomer solid which includes a repeating unit represented by general formula (1), has a weight average molecular weight of 500 to 10000, has a low molecular weight component of less than or equal to 5.0 area% as measured by high performance liquid chromatography, and has a loose bulk density of greater than or equal to 0.20g/cm 3 .