PHOTOCURABLE INK COMPOSITION FOR INKJET PRINTING, PRINTED MATTER, AND MOLDED ARTICLE
    53.
    发明公开
    PHOTOCURABLE INK COMPOSITION FOR INKJET PRINTING, PRINTED MATTER, AND MOLDED ARTICLE 审中-公开
    LICHTHÄRTBARETINTENZUSAMMENSETZUNGFÜRTINTENSTRAHLDRUCK SOWIE DRUCKERZEUGNIS UNDFORMKÖRPER

    公开(公告)号:EP2749610A1

    公开(公告)日:2014-07-02

    申请号:EP12825036.2

    申请日:2012-08-17

    申请人: Sakata INX Corp.

    IPC分类号: C09D11/00 B41J2/01 B41M5/00

    摘要: The present invention provides a photocurable inkjet printing ink composition including at least a photopolymerizable compound component and a photopolymerization initiator, wherein in the photopolymerizable compound component, a monofunctional monomer is included in a content of 91.0 to 99.5% by mass and a multifunctional monomer is included in a content of 0.5 to 9.0% by mass; in the monofunctional monomer component, acryloylmorpholine is included in a content of 30.0 to 85.0% by mass; the monofunctional monomer component includes at least one selected from benzyl acrylate, ethyl carbitol acrylate, tetrahydrofurfuryl acrylate and phenoxyethyl acrylate in a content of 5.0 to 40.0% by mass in the monofunctional monomer component; and the stretching rate at 180°C of the cured coating obtained by photopolymerizing the photocurable inkjet printing ink composition is 120% or more.

    摘要翻译: 本发明提供一种光固化性喷墨印刷油墨组合物,其至少含有光聚合性成分和光聚合引发剂,其中,在光聚合性成分中,单官能单体的含量为91.0〜99.5质量%,包含多官能单体 的含量为0.5〜9.0质量% 在单官能单体成分中,丙烯酰吗啉的含量为30.0〜85.0质量% 单官能单体成分包括在单官能单体成分中含有5.0〜40.0质量%的丙烯酸苄酯,乙基卡必醇丙烯酸酯,丙烯酸四氢糠酯和丙烯酸苯氧基乙酯中的至少一种。 通过光固化性喷墨印刷用油墨组合物的光聚合得到的固化涂层在180℃下的拉伸速度为120%以上。

    PHOTOCURABLE INKJET PRINTING INK COMPOSITION AND PRINT
    56.
    发明公开
    PHOTOCURABLE INKJET PRINTING INK COMPOSITION AND PRINT 有权
    DRUCKERZEUGNIS的照片FARBSTRAHLDRUCKTINTENZUSAMMENSETZUNG

    公开(公告)号:EP2292706A1

    公开(公告)日:2011-03-09

    申请号:EP09758391.8

    申请日:2009-06-04

    申请人: Sakata INX Corp.

    摘要: An object of the present invention is to provide a photocurable ink composition for ink-jet printing, which exhibits excellent curing properties in response to light from light emitting diodes (LEDs), is adhered well to a polyvinyl chloride sheet such as tarpaulin or a vinyl chloride resin sheet, can sufficiently reduce cockling, has a low viscosity but a high flash point, and can achieve both of good jetability at a normal temperature and good safety properties owing to these properties.
    The ink composition for ink-jet printing includes at least: photopolymerizable compounds; a photopolymerization initiator; and a sensitizer, and has a flash point of higher than 60°C when measured with a SETA closed-cup flash point tester by a method in accordance with JIS K2256. The photopolymerizable compounds include 2-methoxyethyl acrylate and/or 2-ethoxyethyl acrylate, and N-vinyl caprolactam, and an acrylated amine compound having two photopolymerizable functional groups and two amino groups in the molecule. The total amount of 2-methoxyethyl acrylate and/or 2-ethoxyethyl acrylate is 20 to 50% by mass of the photocurable ink composition for ink-jet printing. The photopolymerization initiator includes a compound that comes to function as an initiator in response to light having a wavelength of 450 to 300 nm. The sensitizer includes a compound that comes to function as a sensitizer in response to light having a wavelength of 400 nm or longer.

    摘要翻译: 本发明的目的是提供一种用于喷墨打印的可光固化油墨组合物,其响应于来自发光二极管(LED)的光而显示优异的固化特性,良好地粘附到聚氯乙烯片如篷布或乙烯基 氯化物树脂片可以充分降低起皱,具有低粘度但闪点高,并且由于这些特性,可以在常温下达到良好的喷射性和良好的安全性能。 用于喷墨打印的油墨组合物至少包括:可光聚合的化合物; 光聚合引发剂; 和敏化剂,当用SETA闭杯闪点测试仪通过JIS K2256的方法测量时,闪点高于60℃。 可光聚合化合物包括丙烯酸2-甲氧基乙酯和/或丙烯酸2-乙氧基乙酯,和N-乙烯基己内酰胺,以及分子中具有两个可光聚合官能团和两个氨基的丙烯酸酯化胺化合物。 丙烯酸2-甲氧基乙酯和/或丙烯酸2-乙氧基乙酯的总量为喷墨印刷用可光固化油墨组合物的20〜50质量%。 光聚合引发剂包括响应于波长为450〜300nm的光而发挥作为引发剂的化合物。 敏化剂包括响应于波长为400nm或更长的光而起到敏化剂的作用的化合物。