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公开(公告)号：EP1109763A2
公开(公告)日：2001-06-27
申请号：EP99945396.2
申请日：1999-09-01
发明人： BHARADWAJ, Sameer S. , SIDDALL, Jonathan, H. , MAJ, Joseph J. , BEARDEN, Mark, D. , MURCHISON, Craig, B. , LAZARUK, Gerald, E.
CPC分类号： C07C5/48 , B01J21/04 , B01J21/10 , B01J23/40 , B01J23/54 , B01J23/56 , B01J23/626 , B01J23/6445 , B01J23/70 , B01J23/76 , B01J23/8926 , B01J23/8966 , B01J23/96 , B01J35/04 , B01J35/06 , B01J37/0201 , B01J37/0207 , B01J37/0238 , B01J37/18 , C07C2521/02 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2521/12 , C07C2521/14 , C07C2523/04 , C07C2523/08 , C07C2523/14 , C07C2523/18 , C07C2523/42 , C07C2523/44 , C07C2523/50 , C07C2523/72 , C07C2527/224 , C10G2400/20 , Y02P20/52 , Y02P20/584 , Y10S502/514 , C07C11/04 , C07C11/02
摘要： A process and catalyst for the partial oxidation of paraffinic hydrocarbons, such as ethane, propane, naphtha, and natural gas condensates, to olefins, such as ethylene and propylene. The process involves contacting a paraffinic hydrocarbon with oxygen in the presence of hydrogen and a catalyst under autothermal process conditions. Preheating the feed decreases oxygen consumption and increases the net hydrogen balance. The catalyst comprises a Group 8B metal, preferably, a platinum group metal, and at least one promoter selected from Groups 1B, 6B, 3A, 4A, and 5A, optionally supported on a catalytic support, such as magnesia or alumina. In preferred embodiments, the support is pretreated with a support modifier selected from Groups 1A, 2A, 3B, 4B, 5B, 6B, 1B, 3A, 4A, 5A, the rare earth lanthanides, and the actinides. A modified fluidized bed reactor is disclosed for the process.
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52.发明公开
公开(公告)号：EP0804287A1
公开(公告)日：1997-11-05
申请号：EP95942035.0
申请日：1995-12-15
CPC分类号： C07C4/025 , B01J23/007 , B01J27/08 , C07C4/02 , C07C5/48 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2523/02 , C07C2523/04 , C07C2523/10 , C07C2523/14 , C07C2523/18 , C07C2527/224 , C07C2527/24 , C07C11/02
摘要： The invention proposes a method of oxidative dehydrogenation and cracking of C2-C5 paraffins (homogeneous hydrocarbons or mixtures with liquefied petroleum gas) to form C2-C5 olefins in the presence of an oxygen-containing gas and water vapor using a novel calcined oxidic catalyst that has the following composition: XaYbZcAdOx, wherein X is an element of groups II and/or IVb (Mg, Ca, Ti, Zr...), Y is a lanthanide and/or element of groups IVa or Va (Ce, La, Nd, Dy, Sn, Pr, Sb, Pb...), Z is an element of group I (Li, La, K...), A is an element of group VII (Cl, Br, J), and a is 0.4-0.9, b is 0.005-0.3, c is 0.05-1.5, d is 0.05-0.8 and x is a number determined by the valence requirements of the metals and halogens. The catalyst is used in the form of pressed spherical pellets or extrudates with added binder or deposited on a carrier material that consists of one of the above-mentioned oxidic components or of a separate carrier material. The weight-related space velocity relative to the hydrocarbons used is within the range of 0.1 to 20 h-1 and the temperature is 400 to 700° C.
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53.发明授权
公开(公告)号：EP0489585B1
公开(公告)日：1995-11-22
申请号：EP91311287.6
申请日：1991-12-04
申请人： NESTE OY
发明人： Knuuttila, Pekka , Hietala, Jukka , Linna, Anja
CPC分类号： B01J23/30 , C07C6/04 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2521/14 , C07C2523/30 , C07C2527/224 , C07C11/02
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公开(公告)号：EP0256857B1
公开(公告)日：1991-10-23
申请号：EP87307158.3
申请日：1987-08-13
CPC分类号： C07C2/84 , B01J27/16 , C07C2521/06 , C07C2521/08 , C07C2523/02 , C07C2523/06 , C07C2523/10 , C07C2523/14 , C07C2527/224 , C07C2527/24 , Y02P20/52 , C07C9/06 , C07C11/04
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公开(公告)号：EP0196732B1
公开(公告)日：1989-03-01
申请号：EP86200700.2
申请日：1982-12-17
CPC分类号： C07C51/10 , B01J23/89 , B01J23/8946 , B01J27/24 , C07C1/0435 , C07C1/0485 , C07C9/00 , C07C29/157 , C07C29/158 , C07C31/04 , C07C31/08 , C07C2521/04 , C07C2521/08 , C07C2521/12 , C07C2521/16 , C07C2523/04 , C07C2523/42 , C07C2523/46 , C07C2523/72 , C07C2523/89 , C07C2527/224 , C07C2527/24 , Y02P20/52 , C07C31/10 , C07C31/12 , C07C31/125
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