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公开(公告)号：EP0082692B1
公开(公告)日：1988-01-27
申请号：EP82306754.1
申请日：1982-12-17
IPC分类号： B01J23/89 , B01J27/24 , C07C1/04 , C07C27/20 , C07C29/15 , C07C29/14 , C07C29/136 , C07C51/10
CPC分类号： C07C51/10 , B01J23/89 , B01J23/8946 , B01J27/24 , C07C1/0435 , C07C1/0485 , C07C9/00 , C07C29/157 , C07C29/158 , C07C31/04 , C07C31/08 , C07C2521/04 , C07C2521/08 , C07C2521/12 , C07C2521/16 , C07C2523/04 , C07C2523/42 , C07C2523/46 , C07C2523/72 , C07C2523/89 , C07C2527/224 , C07C2527/24 , Y02P20/52 , C07C31/10 , C07C31/12 , C07C31/125
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2.发明公开Production of five-membered nitrogen-containing saturated heterocyclic compounds and catalyst suitable therefor 失效生产的五元含氮的饱和杂环化合物，以及合适的催化剂。
公开(公告)号：EP0027022A1
公开(公告)日：1981-04-15
申请号：EP80303427.1
申请日：1980-09-29
IPC分类号： C07D207/267 , C07D207/27 , B01J23/89
CPC分类号： B01J23/89 , C07D201/08
摘要： A process for the preparation of five-membered nitrogen-containing saturated heterocyclic compounds, such as pyrrolidone having high yield and selectivity results from carrying out a catalytic hydrogenation/amination of a five-membered heterocyclic anhydride or the corresponding acid in the presence of a complex catalyst containing ruthenium. Preferred catalysts have the formula:-
In a representative embodiment maleic anhydride is converted to pyrrolidone by hydrogenation/amination in the presence of a ruthenium containing catalyst at a pressure of approximately 70 kg/cm 2 at a temperature of approximately 250°C.摘要翻译： 一种用于制备过程的五元饱和杂环化合物，发色含氮：诸如具有吡咯烷酮高产率和选择性的结果从执行一个五元杂环酐的催化氢化/阿米娜和灰或在一个复杂的存在相应的酸 催化剂含钌。 优选的催化剂具有下式： - ... AaDbFecRudOx ...在在一个代表性的实施方式的马来酸酐是通过氢化/阿米娜和灰在含催化剂钌的存在下，在大约70公斤/平方厘米<2>所涉及的压力转换为吡咯烷酮 250℃的温度约
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公开(公告)号：EP0196732B1
公开(公告)日：1989-03-01
申请号：EP86200700.2
申请日：1982-12-17
CPC分类号： C07C51/10 , B01J23/89 , B01J23/8946 , B01J27/24 , C07C1/0435 , C07C1/0485 , C07C9/00 , C07C29/157 , C07C29/158 , C07C31/04 , C07C31/08 , C07C2521/04 , C07C2521/08 , C07C2521/12 , C07C2521/16 , C07C2523/04 , C07C2523/42 , C07C2523/46 , C07C2523/72 , C07C2523/89 , C07C2527/224 , C07C2527/24 , Y02P20/52 , C07C31/10 , C07C31/12 , C07C31/125
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4.发明授权
公开(公告)号：EP0027022B1
公开(公告)日：1983-01-26
申请号：EP80303427.1
申请日：1980-09-29
IPC分类号： C07D207/267 , C07D207/27 , B01J23/89
CPC分类号： B01J23/89 , C07D201/08
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公开(公告)号：EP0055512B1
公开(公告)日：1984-10-17
申请号：EP81305152.1
申请日：1981-10-29
IPC分类号： C07C27/04 , C07C29/136 , C07C29/17 , C07D307/08 , C07C31/20
CPC分类号： C07C29/149 , B01J23/60 , B01J23/8953 , C07C29/177 , C07D307/08 , C07C31/207
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6.发明授权Process for producing five, six or seven membered saturated nitrogen containing heterocyclic compounds 失效生产五，六种或七种含饱和氮氧化物的杂环化合物的方法
公开(公告)号：EP0023751B1
公开(公告)日：1983-12-14
申请号：EP80301559.3
申请日：1980-05-13
IPC分类号： C07D207/267 , C07D223/10 , C07D201/08 , C07D211/76 , C07D227/087 , B01J23/46
CPC分类号： B01J37/16 , B01J23/462 , B01J23/64 , B01J23/84 , B01J23/89 , B01J23/8906 , C07D201/08
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7.发明公开Process for upgrading synthesis gas and catalysts therefor 失效Verfahren und Katalysatoren zur Synthesegasaufwertung。
公开(公告)号：EP0082692A2
公开(公告)日：1983-06-29
申请号：EP82306754.1
申请日：1982-12-17
IPC分类号： B01J23/89 , B01J27/24 , C07C1/04 , C07C27/20 , C07C29/15 , C07C29/14 , C07C29/136 , C07C51/10
CPC分类号： C07C51/10 , B01J23/89 , B01J23/8946 , B01J27/24 , C07C1/0435 , C07C1/0485 , C07C9/00 , C07C29/157 , C07C29/158 , C07C31/04 , C07C31/08 , C07C2521/04 , C07C2521/08 , C07C2521/12 , C07C2521/16 , C07C2523/04 , C07C2523/42 , C07C2523/46 , C07C2523/72 , C07C2523/89 , C07C2527/224 , C07C2527/24 , Y02P20/52 , C07C31/10 , C07C31/12 , C07C31/125
摘要： A process of upgrading synthesis gas to hydrocarbons and oxygenated hydrocarbons, particularly olefins and carboxylic acids, comprises contacting synthesis gas with catalysts comprising the mixed oxides of ruthenium, copper, an alkali or alkaline earth metal, and optionally a metal selected from Ce, Cr, Fe, Mn, Mo, Th, Zn or mixtures thereof. The synthesis gas upgrading product may be contacted with a hydrogenation catalyst to provide alkanes, alcohols and esters, useful for fuels.
Catalysts comprising the mixed oxides of ruthenium, copper, at least one alkali metal and at least one of rhodium, iridium, palladium, and platinum are further disclosed which are useful in the upgrading of synthesis gas, particularly for obtaining alkanes and alcohols.摘要翻译： 将合成气升级成烃和含氧烃，特别是烯烃和羧酸的方法包括使合成气与包含钌，铜，碱金属或碱土金属的混合氧化物和任选的选自Ce，Cr， Fe，Mn，Mo，Th，Zn或其混合物。 合成气改质产物可以与氢化催化剂接触以提供可用于燃料的烷烃，醇和酯。 还公开了包含钌，铜，至少一种碱金属和铑，铱，钯和铂中的至少一种的混合氧化物的催化剂，其可用于合成气的升级，特别是用于获得烷烃和醇。
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8.发明公开Process for producing five, six or seven membered saturated nitrogen containing heterocyclic compounds 失效一种用于生产过程的五元饱和的，六元或七元含氮杂环化合物。
公开(公告)号：EP0023751A1
公开(公告)日：1981-02-11
申请号：EP80301559.3
申请日：1980-05-13
IPC分类号： C07D207/267 , C07D223/10 , C07D201/08 , C07D211/76 , C07D227/087 , B01J23/46
CPC分类号： B01J37/16 , B01J23/462 , B01J23/64 , B01J23/84 , B01J23/89 , B01J23/8906 , C07D201/08
摘要： Five, six and seven-member nitrogen-containing saturated heterocyclic compounds are prepared by the catalytic hydrogenation/cyclization of beta, gamma and delta- cyanoesters, in the presence of catalysts containing ruthenium and/or iron which give the desired product in high yield and with high selectivity. The conversion of methyl-3-cyano-propionate to pyrrolidone and methyl-5-cyanopropionate to caprolactam are particularly described.
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9.发明公开Process for upgrading synthesis gas and catalysts therefor 失效Verfahren und Katalysatoren zur Synthesegasaufwertung。
公开(公告)号：EP0196732A1
公开(公告)日：1986-10-08
申请号：EP86200700.2
申请日：1982-12-17
CPC分类号： C07C51/10 , B01J23/89 , B01J23/8946 , B01J27/24 , C07C1/0435 , C07C1/0485 , C07C9/00 , C07C29/157 , C07C29/158 , C07C31/04 , C07C31/08 , C07C2521/04 , C07C2521/08 , C07C2521/12 , C07C2521/16 , C07C2523/04 , C07C2523/42 , C07C2523/46 , C07C2523/72 , C07C2523/89 , C07C2527/224 , C07C2527/24 , Y02P20/52 , C07C31/10 , C07C31/12 , C07C31/125
摘要： Catalysts comprising the mixed oxides of ruthenium, copper, at least one alkali metal and at least one of rhodium, iridium, palladium, and platinum are disclosed which are useful in the upgrading of synthesis gas, particularly for obtaining alkanes and alcohols.
摘要翻译： 公开了包含钌，铜，至少碱金属和铑，铱，钯和铂中的至少一种的混合氧化物的催化剂，其可用于合成气的升级，特别是用于获得烷烃和醇。
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公开(公告)号：EP0082692A3
公开(公告)日：1984-09-12
申请号：EP82306754
申请日：1982-12-17
IPC分类号： B01J23/89 , B01J27/24 , C07C01/04 , C07C27/20 , C07C29/15 , C07C29/14 , C07C29/136 , C07C51/10
CPC分类号： C07C51/10 , B01J23/89 , B01J23/8946 , B01J27/24 , C07C1/0435 , C07C1/0485 , C07C9/00 , C07C29/157 , C07C29/158 , C07C31/04 , C07C31/08 , C07C2521/04 , C07C2521/08 , C07C2521/12 , C07C2521/16 , C07C2523/04 , C07C2523/42 , C07C2523/46 , C07C2523/72 , C07C2523/89 , C07C2527/224 , C07C2527/24 , Y02P20/52 , C07C31/10 , C07C31/12 , C07C31/125
摘要： A process of upgrading synthesis gas to hydrocarbons and oxygenated hydrocarbons, particularly olefins and carboxylic acids, comprises contacting synthesis gas with catalysts comprising the mixed oxides of ruthenium, copper, an alkali or alkaline earth metal, and optionally a metal selected from Ce, Cr, Fe, Mn, Mo, Th, Zn or mixtures thereof. The synthesis gas upgrading product may be contacted with a hydrogenation catalyst to provide alkanes, alcohols and esters, useful for fuels. Catalysts comprising the mixed oxides of ruthenium, copper, at least one alkali metal and at least one of rhodium, iridium, palladium, and platinum are further disclosed which are useful in the upgrading of synthesis gas, particularly for obtaining alkanes and alcohols.
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