摘要:
The present disclosure relates to a process for recovering a polyester component and products of a non-polyester component from an article containing a polyester blend. The polyester blend consists of a polyester component and a non-polyester component. Particularly, the polyester component of the present disclosure is polyethylene terephthalate and the non-polyester component is at least one selected from the group consisting of cotton and viscose. The process of the present disclosure includes hydrolyzing the article using at least one hydrolyzing agent having pH ranging from 7 to 14 to obtain a first mixture containing the polyester component, the non-polyester component, optionally, products of the non-polyester component and the hydrolyzing agent. This is followed by incubating the first mixture using at least one enzyme selected from the group consisting of cellulose and pectinase to further convert the non-polyester component into products of the non-polyester component thereby releasing the polyester component.
摘要:
The present disclosure relates to a fiber suitable for packaging. The fiber of the present disclosure comprises a photocatalyst bonded to it by means of a first functional group generated by a surface modifying agent and optionally, a second functional group generated by a silicon containing linker. The chemical bonding between the fiber and the photocatalyst imparts durability and wash ability to the fiber. A packaging material prepared using the fiber of the present disclosure can be used for the storage of plant produce.
摘要:
The present disclosure relates to a compact polymer gel consisting of ultrahigh molecular weight polyethylene (UHMWPE), at least one nucleator, at least one filler and at least one fluid medium. The present disclosure also provides a process for the preparation of the compact polymeric gel and fibers from the compact polymeric gel. The fibers prepared in accordance with the present process have tensile strength ranging from 2.5 to 10 GPa and tensile modulus ranging from 110 to 300 GPa.
摘要:
The present disclosure provides a composition for preparing terephthalic acid; said composition comprises p-Toluic acid in an amount of 0.05% to 4% with respect to the total mass of the composition; at least one catalyst in an amount of 0.02% to 2.5% with respect to the total mass of the composition; at least one ionic liquid in an amount of 0.04% to 50% with respect to the total mass of the composition; at least one carboxylic acid solvent; and p-xylene. The present disclosure also provides a process for preparing terephthalic acid.
摘要:
The present disclosure provides a heterogeneous Ziegler-Natta catalyst system to be used in the preparation of ultra-high molecular weight polymers (UHMWP). The system includes at least one procatalyst, at least one co-catalyst, at least one hydrocarbon medium and at least one external donor, wherein the ratio of elemental magnesium to elemental titanium to halide, in the procatalyst, is 1 : 1.3: 3.7; the ratio of elemental aluminum, present in the co-catalyst to elemental titanium, present in the procatalyst, ranges between 6:1 and 12: 1; and the ratio of elemental silicon, present in the external donor to elemental titanium, present in the procatalyst, ranges between 1 : 10 and 10: 1. The present disclosure also provides a process for preparation of UHMWPE using the heterogeneous Ziegler-Natta catalyst system of the present disclosure.
摘要:
The present disclosure provides a ziegler-natta pro-catalyst composition for the polymerization.of propylene to produce polypropylene with. reduced polymer-fines.
摘要:
The present disclosure relates to a process for the halogenation of hydrocarbon. In accordance with the process of the present disclosure a hydrocarbon and a halogen is introduced in a reaction vessel. Light having wavelength in the range of 390 to 780nm is then passed into the reaction vessel for a time period of 2 to 12 hrs. to obtain a halogenated hydrocarbon. The hydrocarbon is agitated before or after the introduction of the halogen in to the reaction vessel.
摘要:
In accordance with the present disclosure, there is provided a solid state graft copolymerization process for the preparation of disentangled ultrahigh molecular weight polyethylene graft copolymers in which disentangled ultrahigh molecular weight polyethylene is admixed with at least one functional monomer and a free radical initiator to obtain a mixture; and the mixture thus obtained is subjected to solid state polymerization to obtain a graft copolymer of disentangled ultrahigh molecular weight polyethylene. The graft copolymers of disentangled ultrahigh molecular weight polyethylene shows better crystallization temperature that ranges between 117°C to 121°C and improved decomposition temperature (T 100 ) that ranges between 460°C to 480°C.
摘要:
In the present disclosure, a process for separating aryl carboxylic acids from a mixture comprising a plurality of aryl carboxylic acids is provided, wherein the process comprising the steps of heating a first mixture that comprises at least two aryl carboxylic acids wherein each of said aryl carboxylic acids having a pre-determined liquefaction temperature and a pre-determined precipitation temperature, with at least one ionic compound, at a pre-determined temperature to obtain a liquefied composition; and cooling the liquefied composition under controlled temperature conditions to fractionally crystallize and precipitate an aryl carboxylic acid. The precipitated aryl carboxylic acid is isolated and the obtained mother liquor is subjected to iterated cooling steps until each of the remaining aryl carboxylic acids precipitates one by one. The mother liquor remains in liquefied form.
摘要:
A high activity polyolefin catalyst system comprising titanium containing pro- catalyst component, a co-catalyst component and an external electron donor compound is provided wherein the high activity polyolefin catalyst system is having controlled morphology and less fines. The present invention is more directed to provide a method for the preparation of titanium containing pro- catalyst component from solid spherical shaped magnesium containing pro- catalyst precursor wherein the spherical morphology of the pro-catalyst precursor is maintained through out the reaction in order to achieve titanium-containing pro- catalyst having controlled morphology. The polymerization of lower olefins in the presence of high activity polyolefin catalyst having controlled morphology provides polyolefins with minimal polymer fines.