摘要:
In accordance with the present disclosure, there is provided a solid state graft copolymerization process for the preparation of disentangled ultrahigh molecular weight polyethylene graft copolymers in which disentangled ultrahigh molecular weight polyethylene is admixed with at least one functional monomer and a free radical initiator to obtain a mixture; and the mixture thus obtained is subjected to solid state polymerization to obtain a graft copolymer of disentangled ultrahigh molecular weight polyethylene. The graft copolymers of disentangled ultrahigh molecular weight polyethylene shows better crystallization temperature that ranges between 117° C. to 121° C. and improved decomposition temperature (T100) that ranges between 460° C. to 480° C.
摘要:
The purpose of the present invention is to provide a polar-group-containing propylene-type wax having excellent properties including a low melting point. A modified propylene-(α-olefin) copolymer (A) according to the present invention is produced by grafting at least one compound selected from an unsaturated carboxylic acid, a derivative of the unsaturated carboxylic acid and an unsaturated sulfonic acid salt onto a propylene-(α-olefin) copolymer (A1) and has an acid value of 1 to 100 KOHmg/g, wherein the propylene-(α-olefm) copolymer (A1) comprises 60 to 95 mol% of a propylene-derived constituent unit (a) and 5 to 40 mol% of a constituent unit (b) derived from an α-olefin having 4 or more carbon atoms, and satisfies the specific requirements (i) to (iii).
摘要:
A photocurable elastomer composition comprising: (A) a liquid polymer having a number average molecular weight of 5,000 or more, and mainly containing -[CH 2 C(CH 3 ) 2 ]- units; (B) a (meth)acrylate monomer; and (C) a photo polymerization initiator, the mass ratio ((A): (B)) between the component (A) and the component (B) being 10: 90 to 39: 61.
摘要:
In accordance with the present disclosure, there is provided a solid state graft copolymerization process for the preparation of disentangled ultrahigh molecular weight polyethylene graft copolymers in which disentangled ultrahigh molecular weight polyethylene is admixed with at least one functional monomer and a free radical initiator to obtain a mixture; and the mixture thus obtained is subjected to solid state polymerization to obtain a graft copolymer of disentangled ultrahigh molecular weight polyethylene. The graft copolymers of disentangled ultrahigh molecular weight polyethylene shows better crystallization temperature that ranges between 117° C. to 121° C. and improved decomposition temperature (T100) that ranges between 460° C. to 480° C.
摘要:
In accordance with the present disclosure, there is provided a solid state graft copolymerization process for the preparation of disentangled ultrahigh molecular weight polyethylene graft copolymers in which disentangled ultrahigh molecular weight polyethylene is admixed with at least one functional monomer and a free radical initiator to obtain a mixture; and the mixture thus obtained is subjected to solid state polymerization to obtain a graft copolymer of disentangled ultrahigh molecular weight polyethylene. The graft copolymers of disentangled ultrahigh molecular weight polyethylene shows better crystallization temperature that ranges between 117°C to 121°C and improved decomposition temperature (T 100 ) that ranges between 460°C to 480°C.
摘要:
The invention relates to a two-phase polymer blend, comprising: (a) a polyamide having a melting point at most equal to 210°C, (b) a polyolefin modified by grafting of carboxyl functions, the rheological behaviour of which in the melt state is characterized by the existence of a yield stress, and also to a process for the preparation thereof. The invention furthermore relates to the use of this polymer blend for the manufacture of composite structures and facings and also the resulting composite structures and facings.
摘要:
The composition and preparation of multiple graft low molecular weight polymers useful as dispersants are described. The dispersants described are suitable for controlling sludge and varnish as well as soot. The product is useful as a lubricant additive and a fuel additive.
摘要:
A modified α-olefin polymer which is produced by reacting the following components (i) to (iii) with one another: (i) an α-olefin polymer produced by the homo-polymerization of an α-olefin polymer having 3 or more carbon atoms or the co-polymerization of two or more α-olefin polymers each having 3 or more carbon atoms in the presence of a specific metallocen catalyst and having the following properties (1) to (3): (1) a mesopendad fraction of 40 to 75 mol% or an index of tacticity (M4) of 75 mol% or lower; (2) a molecular weight distribution in terms of PSt as measured by GPC method of 3.0 or lower; and (3) a limiting viscosity [η] (in tetralin, at 135˚C) of 0.01 to 5.0 dl/g; (ii) a radical initiator; and (iii) a monomer or silane coupling agent having a silane group and an ethylenically unsaturated group; and a process for producing a cross-linked product of the modified α-olefin polymer. The modified α-olefin polymer has proper molecular weight distribution and compositional distribution, shows a good coating property at low temperatures (which is a requirement in a reactive hot melt) because it has a low melting temperature, has higher reactivity, compatibility and adhesion property compared to a conventional unmodified α-olefin polymer, produces little decomposition gas because it is a polyolefin material, and has a good adhesion to a polyolefin.