DISENTANGLED ULTRA HIGH MOLECULAR WEIGHT POLYETHYLENE GRAFT COPOLYMERS AND A PROCESS FOR PREPARATION THEREOF
    5.
    发明公开
    DISENTANGLED ULTRA HIGH MOLECULAR WEIGHT POLYETHYLENE GRAFT COPOLYMERS AND A PROCESS FOR PREPARATION THEREOF 有权
    ENTWIRRTE ULTRAHOCHMOLEKULARE POLYETHYLENPFROPFCOPOLYMERE UND VERFAHREN ZUR HERSTELLUNG DAVON

    公开(公告)号:EP2892933A2

    公开(公告)日:2015-07-15

    申请号:EP13838511.7

    申请日:2013-09-10

    IPC分类号: C08F255/02 C08L51/06

    摘要: In accordance with the present disclosure, there is provided a solid state graft copolymerization process for the preparation of disentangled ultrahigh molecular weight polyethylene graft copolymers in which disentangled ultrahigh molecular weight polyethylene is admixed with at least one functional monomer and a free radical initiator to obtain a mixture; and the mixture thus obtained is subjected to solid state polymerization to obtain a graft copolymer of disentangled ultrahigh molecular weight polyethylene. The graft copolymers of disentangled ultrahigh molecular weight polyethylene shows better crystallization temperature that ranges between 117°C to 121°C and improved decomposition temperature (T
    100 ) that ranges between 460°C to 480°C.

    摘要翻译: 根据本公开内容,提供了一种用于制备解开的超高分子量聚乙烯接枝共聚物的固态接枝共聚方法,其中将解开的超高分子量聚乙烯与至少一种官能单体和自由基引发剂混合以获得 混合物; 将由此获得的混合物进行固态聚合,得到解开的超高分子量聚乙烯的接枝共聚物。 分离的超高分子量聚乙烯的接枝共聚物显示出在117℃至121℃之间更好的结晶温度和在460℃至480℃之间的改进的分解温度(T100)。