公开(公告)号：EP1695761A1

公开(公告)日：2006-08-30

申请号：EP04807495.9

申请日：2004-12-15

申请人： Daihatsu Motor Co., Ltd.

发明人： TANAKA, Hirohisa c/o SHIGA TECHNICAL CENTER ,  TAN, Isao c/o SHIGA TECHNICAL CENTER ,  UENISHI, Mari c/o SHIGA TECHNICAL CENTER ,  TANIGUCHI, Masashi c/o SHIGA TECHNICAL CENTER

IPC分类号： B01J23/58 ,  B01J23/89 ,  B01D53/86 ,  C01G55/00

CPC分类号： B01D53/945 ,  B01D2255/402 ,  B01J23/002 ,  B01J23/58 ,  B01J23/63 ,  B01J23/8946 ,  B01J35/002 ,  B01J35/1009 ,  B01J35/1014 ,  B01J2523/00 ,  B82Y30/00 ,  C01G55/002 ,  C01P2002/34 ,  C01P2002/72 ,  C01P2004/03 ,  C01P2004/04 ,  C01P2004/64 ,  C01P2006/12 ,  Y02T10/22 ,  B01J2523/25 ,  B01J2523/47 ,  B01J2523/822 ,  B01J2523/24 ,  B01J2523/31 ,  B01J2523/828 ,  B01J2523/23 ,  B01J2523/48 ,  B01J2523/821 ,  B01J2523/842 ,  B01J2523/3706 ,  B01J2523/22

摘要： To provide a catalyst composition which prevents the activity from deteriorating due to grain growth of Rh and/or Pt and exhibits satisfactory catalytic performance over a long time, the catalyst composition is prepared so that it comprises a perovskite-type composite oxide represented by the following general formula (1):

        A 1-x A' x B 1-(y+z) B' y N z O 3      (1)

wherein A represents at least one element selected from alkaline earth metals; A' represents at least one element selected from rare earth elements; B represents at least one element selected from Ti, Zr, and Hf; B' represents at least one element selected from transition elements (excluding rare earth elements, Ti, Zr, Hf, Rh, and Pt) and Al; N represents at least one element selected from Rh and Pt; x represents an atomic ratio satisfying the following condition: 0 ≤ x ≤ 0.4; y represents an atomic ratio satisfying the following condition: 0 ≤ y

摘要翻译： 为了提供一种催化剂组合物，其防止由于Rh和/或Pt的晶粒生长而导致的活性劣化并且长时间显示出令人满意的催化性能，所以制备催化剂组合物，使其包含由以下化合物表示的钙钛矿型复合氧化物 一般公式（1）：€ƒ€ƒ€ƒ€ƒ€ƒ€ƒA1-x A'x B 1-（y + z）B'y N z O 3€ƒ€ƒ€€ ƒ€ƒ（1）其中A表示选自碱土金属的至少一种元素; A'表示选自稀土元素中的至少一种元素; B表示选自Ti，Zr和Hf中的至少一种元素; B'表示选自过渡元素（不包括稀土元素，Ti，Zr，Hf，Rh和Pt）和Al中的至少一种元素; N表示选自Rh和Pt中的至少一种元素; x表示满足以下条件的原子比：0‰¤x‰¤0.4; y表示满足以下条件的原子比：0‰¤y <0.5; z表示满足以下条件的原子比：0

公开(公告)号：EP1626806A1

公开(公告)日：2006-02-22

申请号：EP04739319.4

申请日：2004-05-19

申请人： Albemarle Netherlands B.V.

发明人： JONES, William ,  O'CONNOR, Paul ,  STAMIRES, Dennis

IPC分类号： B01J23/00 ,  B01J23/22 ,  B01J23/847 ,  B01J23/885 ,  B01J37/30 ,  C01B13/14 ,  C01G1/02 ,  B01D53/50 ,  B01D53/56

CPC分类号： B01D53/508 ,  B01D53/565 ,  B01D53/8609 ,  B01D53/8628 ,  B01D2255/2047 ,  B01D2255/20723 ,  B01D2255/20761 ,  B01D2255/20769 ,  B01D2255/20776 ,  B01D2255/9202 ,  B01D2257/2045 ,  B01D2257/2064 ,  B01D2257/406 ,  B01D2257/408 ,  B01J23/002 ,  B01J23/007 ,  B01J23/06 ,  B01J23/22 ,  B01J23/30 ,  B01J23/72 ,  B01J23/83 ,  B01J23/8472 ,  B01J23/885 ,  B01J29/0308 ,  B01J29/041 ,  B01J37/04 ,  B01J37/30 ,  B01J2523/00 ,  C01B13/145 ,  C01G1/02 ,  C01G31/00 ,  C01G39/00 ,  C01G41/00 ,  C01P2002/22 ,  C01P2004/62 ,  C10G2/33 ,  C10G11/182 ,  C10G29/06 ,  C10G29/16 ,  C10G45/04 ,  C10G45/58 ,  Y02P20/154 ,  B01J2523/12 ,  B01J2523/27 ,  B01J2523/31 ,  B01J2523/69 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/17 ,  B01J2523/3712 ,  B01J2523/22

摘要： Metal-containing composition and use thereof in catalytic reactions, which metal-containing composition is obtainable by contacting a metal hydroxy salt with a solution comprising one or more pH-dependent anions selected from the group consisting of pH-dependent boron-containing anions, vanadium-containing anions, tungsten-containing anions, molybdenum-containing anions, iron-containing anions, niobium-containing anions, tantalum-containing anions, aluminium-containing anions, and gallium-containing anions.

公开(公告)号：EP1407819A2

公开(公告)日：2004-04-14

申请号：EP03255811.6

申请日：2003-09-17

申请人： ROHM AND HAAS COMPANY

发明人： Gaffney, Anne Mae ,  Song, Ruozhi

IPC分类号： B01J23/28 ,  B01J23/34 ,  B01J23/887 ,  B01J27/057 ,  B01J27/132 ,  B01J37/10 ,  B01J23/652 ,  B01J35/00 ,  C07C51/215 ,  C07C253/24

CPC分类号： C07C51/215 ,  B01J23/002 ,  B01J23/02 ,  B01J23/06 ,  B01J23/08 ,  B01J23/10 ,  B01J23/14 ,  B01J23/20 ,  B01J23/24 ,  B01J23/28 ,  B01J23/34 ,  B01J23/64 ,  B01J23/6525 ,  B01J23/8877 ,  B01J27/0576 ,  B01J27/132 ,  B01J35/002 ,  B01J37/06 ,  B01J37/10 ,  B01J37/22 ,  B01J2523/00 ,  C07C253/24 ,  C07C253/26 ,  Y02P20/52 ,  C07C57/04 ,  B01J2523/44 ,  B01J2523/55 ,  B01J2523/56 ,  B01J2523/64 ,  B01J2523/68 ,  B01J2523/67 ,  B01J2523/13 ,  B01J2523/3706 ,  B01J2523/845 ,  B01J2523/822 ,  B01J2523/842 ,  B01J2523/22 ,  B01J2523/33 ,  B01J2523/3737 ,  B01J2523/828 ,  B01J2523/824 ,  B01J2523/70 ,  B01J2523/72 ,  B01J2523/27 ,  B01J2523/11 ,  B01J2523/23 ,  B01J2523/847 ,  C07C255/08

摘要： Catalysts comprising a mixed metal oxide Mo a V b M c Nb d X e O f wherein M is Te or Sb are synthesized by a hydrothermal method. In another embodiment, the catalysts have a specific XRD pattern. These catalysts are obtainable by hydrothermal synthesis followed by treatment with acid or H 2 O 2 . The catalysts are utilized to produce unsaturated carboxylic acids by the vapor phase oxidation of an alkane, or a mixture of an alkane and an alkene, in the presence thereof; or to produce unsaturated nitriles by the vapor phase oxidation of an alkane, or a mixture of an alkane and an alkene, and ammonia in the presence thereof.

摘要翻译： 通过水热法合成包含M为Te或Sb的混合金属氧化物MoaVbMcNbdXeOf的催化剂。 在另一个实施方案中，催化剂具有特定的XRD图案。 这些催化剂可以通过水热合成，然后用酸或H 2 O 2处理。 催化剂用于在其存在下通过烷烃或烷烃和烯烃的混合物的气相氧化产生不饱和羧酸; 或通过烷烃或烷烃和烯烃的混合物以及氨的气相氧化产生不饱和腈。

公开(公告)号：EP1386661A1

公开(公告)日：2004-02-04

申请号：EP02714502.8

申请日：2002-04-05

申请人： Dia-Nitrix Co., Ltd.

发明人： TAGAWA, Yuichi, c/o Dia-Nitrix Co., Ltd. ,  MIYAKI, Kenichi, c/o Dia-Nitrix Co., Ltd. ,  MORI, Kunio, c/o Mitsubishi Rayon Co., Ltd.

IPC分类号： B01J23/88 ,  C07C253/26 ,  C07C255/08

CPC分类号： C07C253/26 ,  B01J23/002 ,  B01J23/31 ,  B01J23/887 ,  B01J23/8876 ,  B01J23/8878 ,  B01J37/0236 ,  B01J37/03 ,  B01J37/08 ,  B01J2523/00 ,  Y02P20/52 ,  B01J2523/13 ,  B01J2523/305 ,  B01J2523/3712 ,  B01J2523/41 ,  B01J2523/51 ,  B01J2523/54 ,  B01J2523/67 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/72 ,  B01J2523/824 ,  B01J2523/842 ,  B01J2523/847 ,  B01J2523/64 ,  B01J2523/53 ,  B01J2523/14 ,  B01J2523/27 ,  B01J2523/3718 ,  B01J2523/22 ,  B01J2523/3706 ,  B01J2523/48 ,  B01J2523/845 ,  C07C255/08

摘要： One object of the present invention is to provide a method for producing a molybdenum-bismuth-iron containing composite oxide fluid bed catalyst, which is useful for an ammoxidation and which produces a target ammoxidation product at high yield and an excellent reproducibility. In order to achieve this object, the present invention provides a method for producing a molybdenum-bismuth-iron containing composite oxide fluid bed catalyst which is used for ammoxidation of organic compounds, comprising the step in that a slurry, which contains the raw materials containing specific elements, is subjected to a concentration treatment at 50-120°C.

摘要翻译： 本发明的一个目的是提供一种生产含钼 - 铋 - 铁的复合氧化物流化床催化剂的方法，其可用于氨氧化，并以高产率产生目标氨氧化产物和优异的再现性。 为了实现上述目的，本发明提供了一种用于有机化合物的氨氧化的含钼 - 铋 - 铁复合氧化物流化床催化剂的方法，该方法包括以下步骤：含有含有 特定元素在50-120℃下进行浓缩处理

公开(公告)号：EP1358147A1

公开(公告)日：2003-11-05

申请号：EP01905424.6

申请日：2001-02-05

申请人： The Standard Oil Company

发明人： SURESH, Dev, D. ,  PAPARIZOS, Christos ,  MOSIER, Patrick, E. ,  WU, Ying ,  FRIEDRICH, Maria, Strada ,  SEELY, Michael, J.

IPC分类号： C07C51/25 ,  C07C57/05 ,  C07C57/055 ,  C07C45/35 ,  C07C47/22 ,  B01J23/887

CPC分类号： B01J23/8877 ,  B01J23/002 ,  B01J23/31 ,  B01J23/8871 ,  B01J23/8872 ,  B01J23/8876 ,  B01J35/0006 ,  B01J37/0045 ,  B01J2523/00 ,  C07C45/35 ,  C07C51/252 ,  C07C47/22 ,  C07C57/04 ,  B01J2523/13 ,  B01J2523/15 ,  B01J2523/22 ,  B01J2523/23 ,  B01J2523/3712 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/842 ,  B01J2523/845 ,  B01J2523/847

摘要： A process for the manufacture of acrylic acid comprising reacting propylene and oxygen (preferably in the form of air) in a reaction zone having a catalyst characterized by the following formula: AaBbCcCadFeeBifMo12=Ox, where A = one or more of Li, Na, K, Rb and Cs; B = one or more of Mg, Sr, Mn, Ni, Co and Zn; C = one or more of Ce, Cr, Al, Sb, P, Ge, Sn, Cu, V and W and; a = 0.01 to 1.0; b and e = 1.0 - 10; c = 0 to 5.0, preferably 0.05 to 5.0, especially preferred being 0.05 to 4.0, and x is a number determined by the valence requirements of the other elements present; at an elevated temperature to produce acrylic acid and acrolein.

公开(公告)号：EP1321458A1

公开(公告)日：2003-06-25

申请号：EP02027604.4

申请日：2002-12-11

申请人： Sabic Americas, Inc.

发明人： Mamedov, Edouard A. ,  Bethke, Kathleen A.

IPC分类号： C07C253/24 ,  B01J23/00 ,  B01J23/18 ,  B01J23/22

CPC分类号： C07C253/24 ,  B01J23/002 ,  B01J23/16 ,  B01J23/18 ,  B01J23/22 ,  B01J23/8472 ,  B01J2523/00 ,  Y02P20/52 ,  C07C255/08 ,  B01J2523/31 ,  B01J2523/53 ,  B01J2523/55 ,  B01J2523/32 ,  B01J2523/33 ,  B01J2523/22 ,  B01J2523/41 ,  B01J2523/69 ,  B01J2523/35 ,  B01J2523/305 ,  B01J2523/48 ,  B01J2523/51 ,  B01J2523/36 ,  B01J2523/47 ,  B01J2523/13 ,  B01J2523/67 ,  B01J2523/57 ,  B01J2523/68 ,  B01J2523/54 ,  B01J2523/56 ,  B01J2523/43 ,  B01J2523/49 ,  B01J2523/17 ,  B01J2523/3712 ,  B01J2523/27 ,  B01J2523/845 ,  B01J2523/842 ,  B01J2523/24 ,  B01J2523/74 ,  B01J2523/28 ,  B01J2523/12 ,  B01J2523/25 ,  B01J2523/847 ,  B01J2523/23 ,  B01J2523/72

摘要： A catalyst composition for the vapor phase ammoxidation of alkanes and olefins of the general empirical formulae:

        VSb a M b O x



        VSb a M b M' b' O x



        VSb a M b Q c O x



        VSb a M b Q c Q' c' O x

wherein M and M' are at least one element selected from magnesium, aluminum, zirconium, silicon, hafnium, titanium and niobium, M and M' being different, Q and Q' are at least one element selected from rhenium, tungsten, molybdenum, tantalum, manganese, phosphorus, cerium, tin, boron, scandium, bismuth, gallium, indium, iron, chromium, lanthanum, yttrium, zinc, cobalt, nickel, cadmium, copper, strontium, barium, calcium, silver, potassium, sodium and cesium, Q and Q' being different, a is 0.5 to 20, b is 2 to 50, b' is 0 to 50, c is 0 to 10, c' is 0 to 10 and x is determined by the valence requirements of the elements present. The catalyst composition containing isolated vanadium and antimony species in an inert matrix is prepared by incorporating respective compounds of vanadium and antimony into the oxide of at least one or more M and adding by co-precipitation or impregnation one or more optional Q in the relative atomic proportions indicated by the subscripts.

摘要翻译： 用于烷烃的气相接触氨氧化和烯烃的一般经验公式餐饮的催化剂组合物：VSbaMbOx VSbaMbM'b'Ox VSbaMbQcOx VSbaMbQcQ'c'Ox worin M和M“是至少一种元素选自镁，铝，锆，硅， 铪，钛和铌，M和M“是不同的，Q和Q”是从铼钨，钼，钽，锰，磷，铈，锡，硼，钪，铋，镓，铟中选择的至少一种元素， 铁，铬，镧，钇，锌，钴，镍，镉，铜，锶，钡，钙，银，钾，钠和铯，Q和Q“是不同的，a是0.5-20，b是2至50 ，b“为0至50，c为0至10，C”为0至10和由存在的元素的化合价要求的x被确定性开采。 在惰性基质分离含有钒和锑的物种中的催化剂组合物是由钒和锑的respectivement化合物掺入至少一种或多种M的氧化物，并在相对原子通过共沉淀或浸渍一种或多种可选性Q，来制备 比例由标指示的。

公开(公告)号：EP1321188A1

公开(公告)日：2003-06-25

申请号：EP03075784.3

申请日：1998-08-17

申请人： The Standard Oil Company

发明人： Drenski, Tama Lee ,  Friedrich, Maria Strada ,  Seely, Michael J. ,  Paparizos, Christos ,  Suresh, Dev Dhanaraj

IPC分类号： B01J23/881 ,  B01J23/887 ,  C01C3/02 ,  C07C253/26

CPC分类号： C07C253/18 ,  B01J23/002 ,  B01J23/31 ,  B01J23/8876 ,  B01J37/0045 ,  B01J37/08 ,  B01J2523/00 ,  C01C3/0216 ,  C01G53/006 ,  Y02P20/52 ,  B01J2523/13 ,  B01J2523/15 ,  B01J2523/22 ,  B01J2523/23 ,  B01J2523/3712 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/842 ,  B01J2523/847 ,  C07C255/08

摘要： A process for preparing acrylonitrile comprises ammoxidising propylene in the presence of a complex oxide catalyst having the empirical formula:

        A a B b C c D d Fe e Bi f Mo 12 O x



where A is Cs, K or mixtures thereof
B is one or more of Mg, Mn, Ni, Co, Ag, Pb, Re, Cd and Zn or mixtures
thereof
C is one or more of Ce, Cr, P, Ge and mixtures thereof
D is Ca and optionally one of Sr, Ba or mixtures thereof
and a = 0.01 to 1.0
b and e = 1.0 to 10
c, d and f = 0.1 to 5.0
and x is a number determined by the valence requirements of the other elements present.

摘要翻译： 制备丙烯腈的方法包括在具有以下经验式的复合氧化物催化剂存在下使丙烯氨氧化：AaBbCcDdFeeBifMo12Ox其中A为Cs，K或其混合物。B为Mg，Mn，Ni，Co，Ag，Pb，Re中的一种或多种 ，Cd和Zn或其混合物C是Ce，Cr，P，Ge及其混合物中的一种或多种，​​D是Ca和任选的Sr，Ba或其混合物中的一种，a = 0.01至1.0b且e = 1.0至10c ，d和f = 0.1至5.0，x是由其它存在的元素的化合价要求确定的数。

公开(公告)号：EP0864532B1

公开(公告)日：2001-08-01

申请号：EP98104392.0

申请日：1998-03-11

申请人： MITSUBISHI RAYON CO., LTD.

发明人： Sasaki, Yutaka, c/o Chuo Kenkyusho ,  Utsumi, Hiroshi, c/o Chuo Kenkyusho ,  Morishita, Kazuo, c/o Chuo Kenkyusho ,  Miyaki, Kenichi, c/o Chuo Kenkyusho

IPC分类号： C01C3/02 ,  B01J27/198 ,  B01J23/18 ,  B01J23/22

CPC分类号： C01C3/0241 ,  B01J23/002 ,  B01J23/8435 ,  B01J27/198 ,  B01J27/199 ,  B01J2523/00 ,  B01J2523/17 ,  B01J2523/41 ,  B01J2523/51 ,  B01J2523/53 ,  B01J2523/55 ,  B01J2523/842 ,  B01J2523/25 ,  B01J2523/27 ,  B01J2523/68 ,  B01J2523/54 ,  B01J2523/12 ,  B01J2523/31 ,  B01J2523/64 ,  B01J2523/72 ,  B01J2523/305 ,  B01J2523/847 ,  B01J2523/22 ,  B01J2523/13 ,  B01J2523/69 ,  B01J2523/845

公开(公告)号：EP1106246A1

公开(公告)日：2001-06-13

申请号：EP00310977.4

申请日：2000-12-08

申请人： NIPPON SHOKUBAI CO., LTD.

发明人： Tanimoto, Michio ,  Nakamura, Daisuke ,  Yunoki, Hiromi

IPC分类号： B01J23/02 ,  B01J23/04 ,  B01J23/888 ,  B01J23/887 ,  C07C51/25 ,  C07C57/04

CPC分类号： B01J23/8885 ,  B01J23/002 ,  B01J23/02 ,  B01J23/04 ,  B01J23/8877 ,  B01J2523/00 ,  C07C51/252 ,  C07C57/04 ,  B01J2523/17 ,  B01J2523/22 ,  B01J2523/41 ,  B01J2523/53 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/31 ,  B01J2523/24 ,  B01J2523/12 ,  B01J2523/23 ,  B01J2523/25 ,  B01J2523/13 ,  B01J2523/842

摘要： A carrier which is characterized by carrying on at least a part of an inert carrier surface an oxide of formula (1):

        X a Y b Z c O d      (1)

Wherein X is one or more element selected from alkaline earth metals; Y is one or more element selected from silicon, aluminum, titanium and zirconium; Z is one or more element selected from Group IA elements and Group IIIB elements of the periodic table, boron, iron, bismuth, cobalt, nickel and manganese; and 0 is oxygen; a, b, c and d denote the atomic ratios of X, Y, Z and O, respectively, such that when a = 1, 0

摘要翻译： 这是通过执行对至少一种式氧化物的惰性载体表面的一部分为特征的载体（1）表示：其中XaYbZcOd X是一种或选自碱土金属中选择多种元素; Y是一个或选自硅，铝，钛和锆中的多种元素; Z是一个或从IA族元素和周期表，硼，铁，铋，钴，镍和锰的IIIB族元素中选出更多的元件; 并且O是氧; 的a，b，c和d分别表示X，Y，Z和O的原子比，分别检查的确当a = 1，0

公开(公告)号：EP0963788A3

公开(公告)日：2000-07-19

申请号：EP99303859.5

申请日：1999-05-18

申请人： Nippon Shokubai Co., Ltd

发明人： Kishimoto, Nobuji ,  Matsunami, Etsushige

IPC分类号： B01J23/34 ,  C07C5/48 ,  C07C11/02 ,  B01J27/053

CPC分类号： C07C45/35 ,  B01J23/002 ,  B01J23/34 ,  B01J2523/00 ,  C07C5/48 ,  C07C45/33 ,  C07C45/34 ,  C07C51/252 ,  C07C2523/34 ,  Y02P20/52 ,  C07C11/02 ,  C07C47/22 ,  C07C57/04 ,  B01J2523/53 ,  B01J2523/72 ,  B01J2523/842 ,  B01J2523/51 ,  B01J2523/67 ,  B01J2523/56 ,  B01J2523/69 ,  B01J2523/17 ,  B01J2523/3712 ,  B01J2523/305 ,  B01J2523/12 ,  B01J2523/22 ,  B01J2523/62 ,  B01J2523/74 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/13 ,  B01J2523/41 ,  B01J2523/54 ,  B01J2523/845

摘要： A catalyst of formula (1):Mn α E 1   β E 2   γ O x wherein E 1 is at least one element selected from P, As, Sb, B, S, Se, Te, F, Cl, Br, I, Nb, Ta, W, Re and Cu; E 2 is at least one element selected from Cr, Fe, Co, Ni, Ag, Au, Zn, Tl, Sn, Pb, Bi, Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Y, La, Ce, Nd and Sm; α = 1, β = 0.01-10, γ = 0-5, and x is a numerical value determined by the oxidation states of the elements other than oxygen.

摘要翻译： 式的催化剂（1）：锰的α-ë<1>的βË<2>伽马牛worinë<1>是选自P，砷，锑，B，S，硒，碲，氟，氯的至少一种元素 ，溴，I，铌，钽，钨，铼和Cu; ë<2>是从铬，铁，钴，镍，银，金，锌，铊，锡，铅，铋，锂，钠，钾，铷，铯，镁，钙，锶，钡中选择的至少一种元素 ，Y，镧，铈，钕和钐; 阿尔法= 1，β= 0.01〜10，γ= 0-5，并且x是由除了氧以外的元素的氧化态开采的数值确定的。