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    PROCESS FOR PRODUCING PHENOL
    66.
    发明公开
    PROCESS FOR PRODUCING PHENOL 审中-公开
    生产苯酚的方法

    公开(公告)号：EP2999685A1

    公开(公告)日：2016-03-30

    申请号：EP14726814.8

    申请日：2014-04-09

    申请人： ExxonMobil Chemical Patents Inc.

    发明人： COLEMAN, John, S. ,  PATEL, Bryan, A.

    IPC分类号： C07C37/08 ,  C07C39/04 ,  C07C45/53 ,  C07C49/403 ,  C07C2/74 ,  C07C13/28 ,  C07C409/14

    CPC分类号： C07C37/50 ,  C07C2/74 ,  C07C37/08 ,  C07C45/53 ,  C07C407/00 ,  C07C409/14 ,  C07C2529/70 ,  C07C2601/14 ,  C07C39/04 ,  C07C49/403 ,  C07C13/28

    摘要： In a process for producing phenol and cyclohexanone, reaction components comprising cyclohexylbenzene hydroperoxide and an acid catalyst are supplied to a cleavage reaction zone, mixed under mixing conditions effective to combine the reaction components into a reaction mixture and at least part of the cyclohexylbenzene hydroperoxide in the reaction mixture is converted under cleavage conditions to into phenol and cyclohexanone; and a cleavage effluent is recovered from the cleavage reaction zone. The cleavage and mixing conditions are controlled such that the ratio
    t
    R /
    t
    M is at least 10, where
    t
    R is the half-life of cyclohexylbenzene hydroperoxide under the cleavage conditions and
    t
    M is the time required after injection of a tracer material into the reaction mixture under the mixing conditions for at least 95% by volume of the entire reaction mixture to attain at least 95% of the volume-averaged tracer material concentration.

    摘要翻译： 在生产苯酚和环己酮的方法中，将包含环己基苯氢过氧化物和酸催化剂的反应组分供应到裂解反应区，在有效将反应组分结合到反应混合物中的混合条件下混合，并将至少部分环己基苯氢过氧化物 反应混合物在裂解条件下转化为苯酚和环己酮; 并从裂解反应区回收裂解流出物。 控制裂解和混合条件，使得比值t R / t M至少为10，其中t R是在裂解条件下环己基苯氢过氧化物的半衰期，t M是将示踪物质注入后所需的时间 反应混合物在混合条件下对于整个反应混合物的至少95体积％达到体积平均示踪物质浓度的至少95％。

    PROCESS FOR PRODUCING PHENOL AND/OR CYCLOHEXANONE FROM CYCLOHEXYLBENZENE
    69.
    发明公开
    PROCESS FOR PRODUCING PHENOL AND/OR CYCLOHEXANONE FROM CYCLOHEXYLBENZENE 审中-公开
    由环己基苯制备苯酚和/或环己酮的方法

    公开(公告)号：EP2895444A1

    公开(公告)日：2015-07-22

    申请号：EP13766442.1

    申请日：2013-09-12

    申请人： ExxonMobil Chemical Patents Inc.

    发明人： KUECHLER, Keith, H. ,  DAKKA, Jihad, M. ,  LATTNER, James, R. ,  BECKER, Christopher, L. ,  MOZELESKI, Edmund, J.

    IPC分类号： C07C1/24 ,  C07C2/74 ,  C07C5/03 ,  C07C13/28 ,  C07C37/08 ,  C07C39/04 ,  C07C45/53 ,  C07C49/403 ,  C07C407/00 ,  C07C409/14

    CPC分类号： C07C45/53 ,  C07C1/24 ,  C07C2/66 ,  C07C2/74 ,  C07C5/03 ,  C07C29/60 ,  C07C29/80 ,  C07C37/08 ,  C07C407/00 ,  C07C2529/70 ,  C07C2601/14 ,  C07C409/14 ,  C07C39/04 ,  C07C49/403 ,  C07C35/21 ,  C07C13/28

    摘要： In a process for producing phenol and/or cyclohexanone, cyclohexylbenzene is contacted with an oxygen-containing gas to produce an oxidation effluent containing cyclohexylbenzene hydroperoxide. At least a portion of the cyclohexylbenzene hydroperoxide is then contacted with a cleavage catalyst to produce a cleavage effluent containing phenol and cyclohexanone and by¬ products including phenylcyclohexanol. The cleavage effluent or a neutralized product thereof also comprises at least one compound comprising an atom not being carbon, hydrogen or oxygen, which is separated from the cleavage effluent and/or the neutralized product thereof to leave a cleavage fraction lean in the compound comprising an atom not being carbon, hydrogen or oxygen and containing at least a portion of the phenylcyclohexanol. At least a portion of the phenylcyclohexanol is then contacted with a dehydration catalyst comprising a molecular sieve of the MCM-22 type to convert at least a portion of the phenylcyclohexanol to phenylcyclohexene.

    摘要翻译： 在生产苯酚和/或环己酮的方法中，环己基苯与含氧气体接触以产生含环己基苯氢过氧化物的氧化流出物。 然后使至少一部分环己基苯氢过氧化物与裂解催化剂接触以产生含有苯酚和环己酮的裂解流出物和包括苯基环己醇的副产物。 裂解流出物或其中和产物还包含至少一种包含不是碳，氢或氧的原子的化合物，其从裂解流出物和/或其中和产物中分离出来，以使裂解馏分贫含在包含 原子不是碳，氢或氧并且含有至少一部分苯基环己醇。 然后使苯基环己醇的至少一部分与包含MCM-22型分子筛的脱水催化剂接触以将至少一部分苯基环己醇转化为苯基环己烯。