摘要:
A negative active material (10) including: a composite (11) including a matrix (11) comprising silicon oxide, silicon carbide, carbon and silicon particles (12) dispersed in the matrix (11); and a carbon coating film (13) formed on a surface of the composite (11), wherein an intensity ratio of a SiC peak to a Si peak in an X-ray diffraction spectrum is at least 1, a method of preparing the negative active material, a negative electrode including the negative active material, and a lithium battery including the electrode.
摘要:
A composite powder in which highly dispersed metal oxide nanoparticle precursors are supported on carbon is rapidlyl heated under nitrogen atmosphere, crystallization of metal oxide is allowed to progress, and highly dispersed metal oxide nanoparticles are supported by carbon. The metal oxide nanoparticle precursors and carbon nanoparticles supporting said precursors are prepared by a mechanochemical reaction that applies sheer stress and centrifugal force to a reactant in a rotating reactor. The rapid heating treatment in said nitrogen atmosphere is desirably heating to 400°C - 1000°C. By further crushing the heated composite, its aggregation is eliminated and the dispersity of metal oxide nanoparticles is made more uniform. Examples of a metal oxide that can be used are manganese oxide, lithium iron phosphate, and lithium titanate. Carbons that can be used are carbon nanofiber and Ketjen Black.
摘要:
A solid state battery including at least one multilayered battery cell comprising: 1) a layer of negative electrode material; 2) a layer of positive electrode material; and 3) a layer of perovskite-type oxide material disposed between the layer of positive electrode material and the layer of negative electrode material, where said layer of perovskite-type oxide material is electrically insulating and capable of readily conducting or transporting protons.
摘要:
A method of producing a material capable of electrochemically storing and releasing a large amount of lithium ions is provided. The material is used as an electrode material for a negative electrode, and includes silicon or tin primary particles composed of crystal particles each having a specific diameter and an amorphous surface layer formed of at least a metal oxide, having a specific thickness. Gibbs free energy when the metal oxide is produced by oxidation of a metal is smaller than Gibbs free energy when silicon or tin is oxidized, and the metal oxide has higher thermodynamic stability than silicon oxide or tin oxide. The method of producing the electrode material includes reacting silicon or tin with a metal oxide, reacting a silicon oxide or a tin oxide with a metal, or reacting a silicon compound or a tin compound with a metal compound to react with each other.
摘要:
Disclosed are a negative active material of a rechargeable lithium battery and a rechargeable lithium battery including a negative electrode, and the negative electrode includes a negative active material layer including a negative active material represented by the following Chemical Formula 1.
X-Ra-Rb
In Chemical Formula 1, X is an active material which comprises a metal and whose functional group has been reacted with a silane coupling agent, Ra is a residual group from a silane coupling agent, and Rb is a polymer including a first repeating unit represented by the following Chemical Formula 2a.
In Chemical Formula 2a, R 10 to R 13 are the same or different, and are hydrogen; or a substituted or unsubstituted C1 to C5 alkyl group, and n 1 is an integer ranging from 1 to 100000 and * is a chemical bond.
摘要:
A secondary battery is provided that comprises a positive electrode including a positive active material, a negative electrode including a negative active material; and a separator interposed between the positive electrode and the negative electrode; wherein at least one of the positive electrode, negative electrode and separator comprises a metal molybdate, wherein at least a portion of the metal molybdate is amorphous. Also provided is a method of manufacturing a secondary battery comprising a positive electrode including a positive active material, a negative electrode including a negative active material and a separator interposed between the positive electrode and the negative electrode, wherein at least one of the positive electrode, negative electrode and separator comprises synthesized lithium molybdate, the method comprising forming the synthesized lithium molybdate by: mixing a lithium precursor with a molybdium precursor to form a mixture; heating the mixture to form crude lithium molybdate; heating the crude lithium molybdate to form synthesized lithium molybdate; wherein at least a portion of the synthesized lithium molybdate is amorphous.
摘要:
Disclosed is a positive electrode and a lithium battery including the positive electrode. The positive electrode includes a current collector, a first layer irreversibly deintercalating lithium ions, and a second layer allowing reversible intercalation and deintercalation of lithium ions. In an embodiment, the first layer further comprises a first sublayer and a second sublayer, in which the first sublayer is interposed between the current collector and the second sublayer. The first sublayer comprises a first active material represented by Formula 1 Li 2 Mo 1-n R 1 O 3 , and the second sublayer comprises a second active material represented by Formula 2 Li 2 Ni 1-m R 2 m O 2 . In Formula 1, 0≤n 1 is selected from the group consisting of manganese (Mn), iron (Fe), cobalt (Co), copper (Cu), zinc (Zn), magnesium (Mg), nickel (Ni), and combinations of at least two of the foregoing elements. In Formula 2, 0≤m 2 is selected from the group consisting of Mn, Fe, Co, Cu, Zn, Mg, Mo, and combinations of at least two of the foregoing elements.
摘要翻译:公开了包括正极的正极和锂电池。 正极包括集电体,第一层不可逆地脱嵌锂离子,以及允许锂离子的可逆嵌入和脱嵌的第二层。 在一个实施例中,第一层还包括第一子层和第二子层,其中第一子层插在集电器和第二子层之间。 第一子层包括由式1 Li 2 Mo 1-n R 1 O 3表示的第一活性物质,第二子层包含由式2 Li 2 Ni 1-m R 2 m O 2表示的第二活性物质。 在公式1中,0‰¤n<1; 并且R 1选自锰(Mn),铁(Fe),钴(Co),铜(Cu),锌(Zn),镁(Mg),镍(Ni) 两个前述要素。 在公式2中,0‰¤m<1; R 2选自Mn,Fe,Co,Cu,Zn,Mg,Mo,以及至少两种前述成分的组合。
摘要:
The present disclosure relates generally to indicating an end of life condition of an electrochemical device, and more particularly to systems and methods for sensing and determining an end of life condition in a cell comprising a high capacity cathode material suitable for use in a non-aqueous electrochemical cell. The high capacity cathode material has an amorphous or semi-crystalline form of copper manganese oxide, and optionally fluorinated carbon. The present disclosure additionally relates to transmitting the determined end of life condition to a user or monitoring device of the cell.