公开(公告)号：EP2514525A1

公开(公告)日：2012-10-24

申请号：EP10837473.7

申请日：2010-12-07

申请人： Cosmo Oil Co., Ltd.

发明人： SATO Kazuhito ,  NAKASHIZU Shigenori

IPC分类号： B01J29/48 ,  C10G2/00 ,  C10G45/64

CPC分类号： C10G2/334 ,  B01J23/6562 ,  B01J23/8892 ,  B01J27/232 ,  B01J29/076 ,  B01J29/48 ,  C10G2400/02

摘要： There are provided a catalyst composition for producing hydrocarbons and a method for producing hydrocarbons which exhibit a high CO conversion rate, generates minimal amount of gaseous components, and is also capable of efficiently obtaining, from a syngas, a gasoline fraction which is selective for and rich in the components having a high octane number, such as aromatic, naphthenic, olefinic and branched paraffinic hydrocarbons, by using a Fischer-Tropsch synthesis catalyst that contains at least one type of metal exhibiting activity in Fischer-Tropsch reaction and manganese carbonate and a zeolite serving as a solid acid.

摘要翻译： 提供了用于生产烃和催化剂组合物用于生产显示出高的CO转化率的烃，基因率的气态组分的最小量的方法，并因此能够有效地获得，从合成气体，汽油馏分所有这些是选择性的和 富含具有高辛烷值组分，色：例如芳族，环烷，烯烃和支链烯烃的烃，通过使用费 - 托合成催化剂确实包含在费 - 托反应和碳酸锰和参展活性的至少一种类型的金属 沸石用作固体酸。

公开(公告)号：EP1762299A4

公开(公告)日：2012-08-01

申请号：EP05733042

申请日：2005-03-31

申请人： CHINA PETROLEUM & CHEMICAL ,  RES INST PETROLEUM PROCESSING

发明人： LONG JUN ,  DA ZHIJIAN ,  TIAN HUIPING ,  CHEN ZHENYU ,  ZHANG WEILIN ,  SHU XINGTIAN ,  ZHANG JIUSHUN ,  ZHU YUXIA ,  LIU YUJIAN

IPC分类号： B01J29/42 ,  B01J29/08 ,  B01J29/40 ,  B01J29/48 ,  B01J29/80 ,  C10G11/05

CPC分类号： B01J29/42 ,  B01J29/084 ,  B01J29/40 ,  B01J29/405 ,  B01J29/48 ,  B01J29/80 ,  B01J2229/42 ,  C10G11/05 ,  C10G2300/807 ,  C10G2400/20

摘要： A catalyst for converting hydrocarbons, which catalyst contains, based on the weight of the catalyst, 1-60% by weight of a zeolite, 0.1-10% by weight of an assistant catalytic component, 5-98% by weight of a thermotolerant inorganic oxide, and 0-70% by weight of a clay in terms of the oxide. Said zeolite is a MFI-structured zeolite containing phosphor and transition metal(s) or a mixture of said zeolite and a macroporous zeolite, which comprises, based on the weight of the mixture, 75-100% by weight of said MFI-structured zeolite containing phosphor and transition metal(s) and 0-25% by weight of the macroporous zeolite. In terms of the mass of the oxide, said MFI-structured zeolite containing phosphor and transition metal(s) has the following anhydrous chemical formula: €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ(0-0.3)Na 2 O · (0.3-5.5)Al 2 O 3 · (1.0-10)P 2 O 5 · (0.7-15)M1 x O y · (0.01-5)M2 m O n · (0-10)RE 2 O 3 · (70-97)SiO 2 €ƒ€ƒ€ƒ€ƒ€ƒI or €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ(0-0.3)Na 2 O · (0.3-5)Al 2 O 3 · (1.0-10)P 2 O 5 · (0.7-15)M p O q · (0-10)RE 2 O 3 · (70-98)SiO 2 €ƒ€ƒ€ƒ€ƒ€ƒII Said assistant catalytic component is one or more selected from the group consisting of the alkali earth metals, Group IVB metals, non-noble metals of Group VIII, and rare earth metals of the Periodic Table of the Elements. This catalyst has a higher ability to convert petroleum hydrocarbons and higher yields for propylene, ethylene, and light aromatics.

公开(公告)号：EP2253607A4

公开(公告)日：2011-06-15

申请号：EP09721291

申请日：2009-03-18

申请人： TORAY INDUSTRIES

发明人： YOSHIKAWA TAKAHIRO ,  WATANABE MASATOSHI ,  ICHIOKA RYOJI

IPC分类号： C07C4/18 ,  B01J29/48 ,  C07B61/00 ,  C07C7/04 ,  C07C15/04 ,  C07C15/08

CPC分类号： B01J29/48 ,  B01J37/0009 ,  B01J2229/20 ,  B01J2229/42 ,  C07C4/18 ,  C07C7/005 ,  C07C7/04 ,  C07C7/148 ,  C07C7/163 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2529/78 ,  Y02P20/52 ,  C07C15/04 ,  C07C15/08

公开(公告)号：EP2282835A1

公开(公告)日：2011-02-16

申请号：EP09729859.0

申请日：2009-04-01

申请人： BASF SE

发明人： KIESSLICH, Frank ,  COELHO TSOU, Joana ,  SCHULZ, Alexander

IPC分类号： B01J29/076 ,  B01J29/48 ,  B01J38/10 ,  C07C2/76 ,  C10G35/095 ,  B01J29/90

CPC分类号： B01J38/10 ,  B01J29/076 ,  B01J29/48 ,  B01J29/90 ,  B01J37/0009 ,  B01J37/18 ,  B01J2229/20 ,  B01J2229/42 ,  C07C2/76 ,  C07C2529/48 ,  Y02P20/584 ,  C07C15/00

摘要： The invention relates to a method for the non-oxidative dehydroaromatisation of aliphatic hydrocarbons by reacting an educt flow containing aliphatic hydrocarbons, in the presence of a catalyst containing at least one metalosillcate as a carrier, at least one element selected from the groups Mo, W and Re as active components and at least one additional transitional metal that is not a precious metal, as a dopant. The catalyst is regularly regenerated under non-oxidative conditions with hydrogen. Preferably, Fe, Ni, Cu and Co are used as additional transitional metals.

公开(公告)号：EP2140939A1

公开(公告)日：2010-01-06

申请号：EP08722278.2

申请日：2008-03-17

申请人： Meidensha Corporation

发明人： MA, Hongtao ,  OGAWA, Yuji

IPC分类号： B01J29/90 ,  B01J29/48 ,  B01J38/10 ,  B01J38/12 ,  C10G35/04

CPC分类号： B01J29/48 ,  B01J27/22 ,  B01J27/28 ,  B01J29/90 ,  B01J37/0009 ,  B01J38/10 ,  B01J38/12 ,  B01J2229/12 ,  B01J2229/123 ,  B01J2229/18 ,  B01J2229/32 ,  B01J2229/42 ,  C07C2/76 ,  Y02P20/584 ,  C07C15/00

摘要： To improve stability of catalytic performance, an aromatizing catalyst for converting lower hydrocarbons into aromatic compounds is regenerated. A regeneration process of the aromatizing catalyst according to the present invention includes the steps of: (a) reacting the aromatizing catalyst with a hydrogen gas in an atmosphere containing the hydrogen gas after using the aromatizing catalyst in an aromatizing reaction for converting lower hydrocarbons into aromatic compounds; (b) decreasing a temperature of the atmosphere containing the hydrogen gas reacted with the aromatizing catalyst, by supplying one of an inert gas and a reducing gas to the atmosphere; (c) reacting the aromatizing catalyst reacted with this inert gas, with an oxidizing gas; and (d) reacting the aromatizing catalyst reacted with the oxidizing gas, with a reducing gas. The reaction step between the aromatizing catalyst and hydrogen gas is conducted in a temperature region that is the same as the temperature of the aromatizing reaction. In the temperature decreasing step, an inert gas is supplied such that the temperature of the aromatizing catalyst becomes 400°C-550°C. In the step of reacting the aromatizing catalyst with an oxidizing gas, the temperature of an atmosphere, in which the aromatizing catalyst is reacted with the oxidizing gas, is set at 450°C-500°C.

公开(公告)号：EP2008988A1

公开(公告)日：2008-12-31

申请号：EP07739985.5

申请日：2007-03-28

申请人： TORAY INDUSTRIES, INC.

发明人： ICHIOKA, Ryoji ,  MINOMIYA, Eiichi ,  YAMAKAWA, Shinobu

IPC分类号： C07C4/18 ,  B01J29/48 ,  C07C5/27 ,  C07C15/04 ,  C07C15/06 ,  C07C15/08 ,  C07B61/00

CPC分类号： C07C5/2724 ,  B01J29/48 ,  B01J2229/186 ,  C07C4/18 ,  C07C5/2708 ,  C07C7/148 ,  C07C15/08 ,  C07C2529/48 ,  C07C2529/78 ,  Y02P20/52 ,  C07C15/04

摘要： A process for converting ethylbenzene, by which ethylbenzene in a feedstocks containing C8 aromatic hydrocarbon is converted to benzene at a high degree of conversion is disclosed. The process for converting ethylbenzene comprises the step of bringing a C8 aromatic hydrocarbon mixed feedstocks containing ethylbenzene into contact with an acid type catalyst containing at least one metal selected from the group consisting of the metals belonging to Group VII and Group VIII in the presence of H 2 to convert ethylbenzene to benzene. The feedstocks contains C9-C10 aromatic hydrocarbons including ethyltoluene, and the ethyltoluene is converted to toluene together with the conversion of ethylbenzene.

摘要翻译： 一种用于在高转化率在C8含烃原料的芳族转化成苯乙苯转化，通过该方法的乙苯是游离缺失盘。 乙苯的转化的方法，包括使C8芳香烃混合原料含乙苯接触到上酸型催化剂含有选自属于第VII族和第VIII族的H存在下的金属中选出的至少一种金属的步骤 2至乙苯转化成苯。 该原料中含有C9〜C10芳香烃，包括乙基甲苯和乙基甲苯与乙苯转化转化成甲苯一起。

公开(公告)号：EP1157082A4

公开(公告)日：2002-04-17

申请号：EP99972245

申请日：1999-10-25

申请人： EXXONMOBIL OIL CORP

发明人： SHIH STUART SHAN-SAN

IPC分类号： C10L1/00 ,  B01J29/46 ,  B01J29/48 ,  C10G45/04 ,  C10G45/06 ,  C10G45/08 ,  C10G45/12 ,  C10G69/04 ,  C10L10/10 ,  C10L10/14 ,  B01J29/076 ,  B01J23/882 ,  B01J27/051

CPC分类号： C10G45/12 ,  B01J29/46 ,  B01J29/48 ,  B01J2229/26 ,  B01J2229/42 ,  C10G45/08

摘要： Low sulfur gasoline of relatively high octane-barrel value is produced from cracked, sulfur containing olefinic naphtas by hydrodesulfurization at low temperature and low space velocity over either a conventional catalyst, such as CoMo/A12O3, or a dual functional catalyst, such as CoMo ZSM-5/A12O3. This approach also minimizes the olefins/hydrogen sulfide re-combination frequently observed at high temperature. The process produces a gasoline having a reduced sulfur content with a less than 5 % change in motor octane number and a less than 10 % change in research octane number.

公开(公告)号：EP0801027A4

公开(公告)日：1997-09-29

申请号：EP95941571

申请日：1995-12-25

申请人： CHINA PETROCHEMICAL CORP ,  DALIAN CHEMICAL PHYSICS INST ,  FUSHUN PETRO CHEMICAL COMPANY

发明人： WANG QINGXIA ,  ZHANG SHURONG ,  CAI GUANGYU ,  LI FENG ,  XU LONGYA ,  HUANG ZUXIAN ,  LI YUYING

IPC分类号： B01J29/48 ,  B01J29/40 ,  B01J29/70 ,  B01J29/80 ,  C01B39/36 ,  C07B37/00 ,  C07B37/02 ,  C07B61/00 ,  B01J29/04 ,  C01B39/04

CPC分类号： C01B39/365 ,  B01J29/40 ,  B01J29/70 ,  B01J29/80 ,  C01B39/36 ,  Y10S423/22 ,  Y10S423/29

摘要： This invention concerns a zeolite containing rare earth elements and possessing cocrystallization structure of ZSM-5 and ZSM-11, wherein, weight rate of crystal phase structure portion of ZSM-5 and ZSM-11 is from 0.1 to 10. Chemical composition of the prototype zeolite synthesized under anhydrous state is as follows: 0.1-1.0 Na2O, 0.01-1.0 RE2O3, Al2O3. 20-300 SiO2. X-ray diffraction spectral lines of the zeolite Na-type are shown in table 1. The zeolite possesses good acidic hydrothermal stability and anti-impurities contamination ability, and can be used as catalyst in varied hydrocarbon conversion processes.

摘要翻译： 本发明涉及含有稀土元素并具有ZSM-5和ZSM-11的共晶结构的沸石，其中ZSM-5和ZSM-11的晶相结构部分的重量比为0.1-10。原型的化学组成 在无水状态下合成的沸石如下：0.1-1.0Na 2 O，0.01-1.0 RE 2 O 3，Al 2 O 3。 20-300SiO2。 Na型沸石的X射线衍射谱线示于表1中。该沸石具有良好的酸性水热稳定性和抗杂质污染能力，并且可用作各种烃转化过程中的催化剂。

公开(公告)号：EP0645186A3

公开(公告)日：1995-08-23

申请号：EP94307033.4

申请日：1994-09-27

申请人： Intevep SA

发明人： Prada, Ricardo ,  Caliasso, Roberto ,  Romero, Yilda ,  Reyes, Edito ,  Rodriguez, Edilberto

IPC分类号： B01J29/48

CPC分类号： C10G65/12 ,  B01J21/04 ,  B01J21/063 ,  B01J21/12 ,  B01J23/8993 ,  B01J29/084 ,  B01J29/40 ,  B01J29/44 ,  B01J29/46 ,  B01J29/70 ,  B01J35/0006 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/1066 ,  B01J37/0201 ,  B01J37/0205 ,  B01J37/03 ,  B01J2229/26 ,  B01J2229/42 ,  C10G45/54 ,  C10G47/14 ,  C10G47/18 ,  C10G47/20 ,  C10G49/04 ,  C10G49/06 ,  C10G65/02 ,  F02B3/06

摘要： A tri-elemental catalyst on a support that includes a pentasil crystalline zeolite and is suitable for hydrocracking and hydrogenation of aromatics-containing petroleum hydrocarbon feedstocks such as hydrotreated cracked feedstock, virgin feedstock, vacuum distillate, middle distillate, mixtures thereof, and the like, is disclosed. The catalyst is suitable for hydrodesulfurization as well as hydrodenitrogenation, thus the feedstock can contain sulfur and nitrogen in addition to the aromatic components. Hydrocracking and aromatics hydrogenation of the petroleum hydrocarbon feedstocks is accomplished under a relatively wide range of process conditions in plural process zones using the tri-elemental catalyst that contains a catalytically active metal phase constituted by a Group VI-B element, a Group VIII first transition series element and a Group VIII second transition series element. In an upstream zone the catalytically active metal phase is supported on a titania-alumina support containing about 5% to about 30% by weight titania in the support. In a downstream zone the catalytically active metal phase is supported on a titania-alumina-pentasil crystalline zeolite support. The preferred pentasil crystalline zeolite is ZSM-5.

公开(公告)号：EP3103550B1

公开(公告)日：2024-10-23

申请号：EP15745863.9

申请日：2015-02-02

发明人： SHONO, Emi ,  SHIMIZU, Kana ,  HIKAZUDANI, Susumu

IPC分类号： B01J29/44 ,  B01D53/94 ,  B01J29/40 ,  B01J29/48 ,  B01J29/67 ,  B01J29/69 ,  F01N3/08 ,  F01N3/10