公开(公告)号：EP1934165B1

公开(公告)日：2009-11-11

申请号：EP06793777.1

申请日：2006-09-25

申请人： BASF SE

发明人： CAUWENBERGE, Gunther ,  MELDER, Johann-Peter ,  EVERS, Holger ,  GERLACH, Till ,  KIESSLICH, Frank ,  SCHWAB, Ekkehard ,  HOFFER, Bram Willem

IPC分类号： C07C209/16 ,  C07C211/10

CPC分类号： C07C209/16 ,  B01J21/04 ,  B01J23/755 ,  B01J35/023 ,  B01J37/0201 ,  B01J37/18 ,  C07D295/02 ,  C07D295/13 ,  C07C211/10 ,  C07C211/14

摘要： Process for producing ethyleneamines by reacting monoethanolamine (MEOA) with ammonia in the presence of a transition metal heterogeneous catalyst in which the catalytically active mass of the catalyst before the treatment with hydrogen contains oxygen-containing compounds of aluminium, copper, nickel and cobalt and the shaped catalyst body in the case of bead shape or rod shape in each case has a diameter of

公开(公告)号：EP2282835A1

公开(公告)日：2011-02-16

申请号：EP09729859.0

申请日：2009-04-01

申请人： BASF SE

发明人： KIESSLICH, Frank ,  COELHO TSOU, Joana ,  SCHULZ, Alexander

IPC分类号： B01J29/076 ,  B01J29/48 ,  B01J38/10 ,  C07C2/76 ,  C10G35/095 ,  B01J29/90

CPC分类号： B01J38/10 ,  B01J29/076 ,  B01J29/48 ,  B01J29/90 ,  B01J37/0009 ,  B01J37/18 ,  B01J2229/20 ,  B01J2229/42 ,  C07C2/76 ,  C07C2529/48 ,  Y02P20/584 ,  C07C15/00

摘要： The invention relates to a method for the non-oxidative dehydroaromatisation of aliphatic hydrocarbons by reacting an educt flow containing aliphatic hydrocarbons, in the presence of a catalyst containing at least one metalosillcate as a carrier, at least one element selected from the groups Mo, W and Re as active components and at least one additional transitional metal that is not a precious metal, as a dopant. The catalyst is regularly regenerated under non-oxidative conditions with hydrogen. Preferably, Fe, Ni, Cu and Co are used as additional transitional metals.

公开(公告)号：EP2032513A1

公开(公告)日：2009-03-11

申请号：EP07730051.5

申请日：2007-06-11

申请人： BASF SE ,  Schwab, Ekkehard

发明人： SCHUBERT, Markus ,  MUELLER, Ulrich ,  TEICH, Friedhelm ,  KIESSLICH, Frank ,  POPLOW, Frank

IPC分类号： C07C2/76 ,  C07C2/78 ,  C07C15/04 ,  C07C15/00 ,  C07C2/64 ,  C07C15/073

CPC分类号： C07C15/073 ,  C07C2/64 ,  C07C2/76 ,  C07C2/78 ,  C07C15/00 ,  C07C15/04

摘要： The present invention relates to a combined process for depleting or removing methane from a methane-containing gas mixture A and subsequent dehydrogenation, comprising the following steps 1) preparing a methane-enriched mixture B by contacting the methane-containing gas mixture A with at least one sorbent comprising a porous organometallic skeleton material, the skeleton material comprising at least one at least bidentate organic compound bound coordinatively to at least one metal ion; 2) preparing a methane-depleted gas mixture C by desorbing the compounds retained on the sorbent; 3) dehydrogenating aromatization of the saturated and unsaturated hydrocarbons present in mixture C or a portion thereof in the presence of a catalyst to aromatic hydrocarbons, to obtain a mixture D; 4) if appropriate separating the mixture D into a low boiler mixture E which comprises the majority of the H2 formed and of the unconverted hydrocarbons, and into at least one high boiler mixture F which comprises the majority of the aromatic hydrocarbons formed.

公开(公告)号：EP1934165A1

公开(公告)日：2008-06-25

申请号：EP06793777.1

申请日：2006-09-25

申请人： BASF SE

发明人： CAUWENBERGE, Gunther ,  MELDER, Johann-Peter ,  EVERS, Holger ,  GERLACH, Till ,  KIESSLICH, Frank ,  SCHWAB, Ekkehard ,  HOFFER, Bram Willem

IPC分类号： C07C209/16 ,  C07C211/10

CPC分类号： C07C209/16 ,  B01J21/04 ,  B01J23/755 ,  B01J35/023 ,  B01J37/0201 ,  B01J37/18 ,  C07D295/02 ,  C07D295/13 ,  C07C211/10 ,  C07C211/14

摘要： Process for producing ethyleneamines by reacting monoethanolamine (MEOA) with ammonia in the presence of a transition metal heterogeneous catalyst in which the catalytically active mass of the catalyst before the treatment with hydrogen contains oxygen-containing compounds of aluminium, copper, nickel and cobalt and the shaped catalyst body in the case of bead shape or rod shape in each case has a diameter of

摘要翻译： 通过使单乙醇胺（MEOA）与氨在过渡金属非均相催化剂存在下反应生产亚乙基胺的方法，其中在用氢处理之前催化剂的催化活性物质含有铝，铜，镍和钴的含氧化合物和 在珠状或棒状的情况下，棒状催化剂体在每种情况下具有小于3mm的直径，在片状具有<3mm的高度的情况下，并且在所有其他几何形状的情况下具有相同的 直径L = 1 / a'<0.70mm，其中a'是每体积单位的外表面积（mms2 / mmp3），其中：a'= Ap / Vp，其中Ap是催化剂颗粒的外表面积 mms2），Vp是催化剂颗粒（mmp3）的体积。

公开(公告)号：EP1943201B1

公开(公告)日：2013-09-18

申请号：EP06807664.5

申请日：2006-10-30

申请人： BASF SE

发明人： KIESSLICH, Frank ,  CRONE, Sven ,  MACHHAMMER, Otto ,  VAN LAAR, Frederik ,  SCHWAB, Ekkehard ,  SCHINDLER, Götz-Peter

IPC分类号： C07C2/84 ,  C07C15/00

CPC分类号： B01J29/46 ,  C01B3/50 ,  C01B2203/048 ,  C01B2203/0495 ,  C01C3/0212 ,  C07C2/84 ,  C07C2529/06 ,  C07C2529/48 ,  Y02P20/13 ,  C07C15/00

公开(公告)号：EP1943201A2

公开(公告)日：2008-07-16

申请号：EP06807664.5

申请日：2006-10-30

申请人： BASF SE

发明人： KIESSLICH, Frank ,  CRONE, Sven ,  MACHHAMMER, Otto ,  VAN LAAR, Frederik ,  SCHWAB, Ekkehard ,  SCHINDLER, Götz-Peter

IPC分类号： C07C2/84 ,  C07C15/00

CPC分类号： B01J29/46 ,  C01B3/50 ,  C01B2203/048 ,  C01B2203/0495 ,  C01C3/0212 ,  C07C2/84 ,  C07C2529/06 ,  C07C2529/48 ,  Y02P20/13 ,  C07C15/00

摘要： The invention relates to a method for producing aromatic hydrocarbons from a C1-C4 alkane or a mixture of C1-C4 alkanes. Said method is characterized in that: a) an educt flow A containing a C1-C4 alkane or a mixture of C1-C4 alkanes is brought in contact with a catalyst, and some of the C1-C4 alkane or some of the mixture of C1-C4 alkanes is reacted to aromatic hydrocarbon/s, b) the product flow B resulting from step (a) is separated into a low-boiling flow C containing the main portion of the hydrogen and the non-reacted C1-C4 alkane or mixture of C1-C4 alkanes, and a high-boiling flow D or several high-boiling flows D' containing the main portion of the obtained aromatic hydrocarbon, and c) the low-boiling flow C is fed to another process consuming C1-C4 alkane, the hydrogen contained in the low-boiling flow C being optionally eliminated beforehand.