摘要:
A superabsorbent material with enhanced odour control and control of bacterial growth comprises a non-acidic, alkali-neutralising compound selected from acid anhydrides, lactides, lactones and hydrolysable esters, especially cyclic acid anhydrides, lactides and lactones of η- or δ-carboxylic acids. The superabsorbent material can be used in hygiene products such as diapers.
摘要:
A process for oxidising cellulose, in which a nitroxyl compound such as TEMPO is oxidised using an oxidising agent in the presence of a complex of a transition metal such as Mn, Fe, Cu, and a complexing agent such as a polyamine, or an oxidative enzyme, and the resulting nitrosonium ion is used to selectively oxidise the cellulose 6-hydroxy-methylene groups to carbaldehyde groups and carboxylic acid groups.
摘要:
The invention pertains to a process for producing oxidised cellulose having a high molecular weight, by pre-treating cellulose in a non-alkaline solvent for cellulose so as to lower its crystallinity, and then oxidising it using an oxidising system predominantly oxidising the 6-hydroxymethyl groups or the 2,3-dihydroxyethylene groups to carbaldehyde and/or carboxyl groups. The oxidising agent is preferably a nitroxyl compound or periodate, and the product is useful as a water absorbent.
摘要:
A superabsorbent article of the invention having improved odour control and microbial control, comprises a liquid-impervious back layer, a liquid-absorbing intermediate layer containing a partially neutralised, acidic hydrophilic polymer, especially a surface-crosslinked polyacrylate, and a liquid-pervious, non-absorbing top layer, and is characterised by comprising an alkali-neutralising agent which is evenly distributed in said absorbing intermediate layer.
摘要:
Carbohydrates having primary hydroxyl groups, such as starch and cellulose, can be selectively oxidised to carboxylic carbohydrates by oxidation with molecular oxygen, using a nitrogen oxide such as a nitrite salt, as a catalyst. The reaction is advantageously carried out in a dehydrating solvent such as concentrated phosphoric acid.
摘要:
The invention pertains to a process for the regeneration and recovery of periodate from a spent iodate solution, by reacting the iodate with at least an equimolar amount of hypohalite, and carrying out the recovery in the presence of a water-miscible organic solvent or potassium ions or divalent metal (especially calcium) ions. The regenerated periodate is especially suitable for oxidising carbohydrates to dialdehyde carbohydrates.
摘要:
The present invention relates to a cellulose-containing fibrous material, wherein hydroxy groups were oxidized at the C(6) of glucose units of the cellulose into aldehyde and/or carboxy groups, a paper or nonwoven (product) made therefrom, in particular tissue (products) and a process for their manufacture. The paper or nonwoven (products) of the invention display excellent strength properties.
摘要:
A process for oxidising cellulose, in which a nitroxyl compound such as TEMPO is oxidised using an oxidising agent in the presence of a complex of a transition metal such as Mn, Fe, Cu, and a complexing agent such as a polyamine, or an oxidative enzyme, and the resulting nitrosonium ion is used to selectively oxidise the cellulose 6-hydroxy-methylene groups to carbaldehyde groups and carboxylic acid groups.