CYCLOHEXYLBENZENE HYDROPEROXIDE COMPOSITIONS
    1.
    发明公开
    CYCLOHEXYLBENZENE HYDROPEROXIDE COMPOSITIONS 审中-公开
    CYCLOHEXYLBENZOL-HYDROPEROXID-ZUSAMMENSETZUNGEN

    公开(公告)号:EP2616435A1

    公开(公告)日:2013-07-24

    申请号:EP11751724.3

    申请日:2011-08-16

    IPC分类号: C07C409/14 C07C13/28

    摘要: In a process for producing phenol and cyclohexanone, a feed comprising cyclohexylbenzene is oxidized to produce an oxidation reaction product comprising cyclohexyl-1-phenyl-1-hydroperoxide. At least a portion of the oxidation reaction product is then cleaved to produce a cleavage reaction product comprising phenol, cyclohexanone, and at least one contaminant. At least a portion of the cleavage reaction product is contacted with an acidic material to convert at least a portion of the at least one contaminant to a converted contaminant and thereby produce a modified reaction product. The oxidation reaction product may have at least 50 wt% of cyclohexylbenzene, no greater than 80 wt% of cyclohexyl-1-phenyl-1-hydroperoxide, and 0.1 wt% to 10 wt% of another hydroperoxide.

    摘要翻译: 在生产苯酚和环己酮的方法中,将包含环己基苯的进料氧化以产生包含环己基-1-苯基-1-氢过氧化物的氧化反应产物。 然后将至少一部分氧化反应产物切割以产生包含苯酚,环己酮和至少一种污染物的裂解反应产物。 裂解反应产物的至少一部分与酸性物质接触以将至少一部分至少一种污染物转化为转化的污染物,从而产生改性的反应产物。 氧化反应产物可以具有至少50重量%的环己基苯,不大于80重量%的环己基-1-苯基-1-氢过氧化物和0.1重量%至10重量%的其它氢过氧化物。