摘要:
In a process for producing phenol and cyclohexanone, a feed comprising cyclohexylbenzene is oxidized to produce an oxidation reaction product comprising cyclohexyl-1-phenyl-1-hydroperoxide. At least a portion of the oxidation reaction product is then cleaved to produce a cleavage reaction product comprising phenol, cyclohexanone, and at least one contaminant. At least a portion of the cleavage reaction product is contacted with an acidic material to convert at least a portion of the at least one contaminant to a converted contaminant and thereby produce a modified reaction product. The oxidation reaction product may have at least 50 wt% of cyclohexylbenzene, no greater than 80 wt% of cyclohexyl-1-phenyl-1-hydroperoxide, and 0.1 wt% to 10 wt% of another hydroperoxide.
摘要:
A novel small pore (metallo)aluminophosphate molecular sieve is disclosed. The as-synthesized material has an X-ray diffraction pattern including the lines listed in Table 1 and is produced in the presence of fluoride ions and 4-dimethylaminopyridine as structure directing agent. The silicoaluminophosphate material has methanol conversion activity and n-hexane cracking activity.
摘要:
A process for cracking a hydrocarbon feedstock containing salt and/or particulate matter, wherein said hydrocarbon feedstock containing salt and/or particulate matter is heated, then separated into a vapor phase and a liquid phase by flashing in a flash separation vessel, separating and cracking the vapor phase which comprises less than about 98% of the hydrocarbon feedstock containing salt and/or particulate matter, and recovering cracked product. The salt and/or particulate matter are removed in the liquid bottoms stream from the flash separation vessel. The liquid phase could then be sold as bunker C fuel oil or fed to a refinery catalytic cracker or coker unit without desalting.
摘要:
This invention is directed to processes of making polymer in the presence of a hydrofluorocarbon or perfluorocarbon and recovering the polymer. The processes provided enable polymerization processes to be practiced with minimal fouling in the reaction system, and to the recovery of the hydrofluorocarbon and other hydrocarbons such as hydrocarbons for reuse in the process or hydrocarbon by-products from the polymerization process. The invention is particularly beneficial in the production of ethylene based polymers using Ziegler Natta catalyst systems.
摘要:
This invention relates to a process of polymerizing ethylene in a reactor comprising contacting a catalyst system comprising a supported chromium catalyst and an aluminum alkyl cocatalyst, where the catalyst and cocatalyst are contacted by cofeeding the catalyst and cocatalyst to the reactor or feeding the catalyst and cocatalyst separately to the reactor, where the catalyst and cocatalyst are not contacted prior to the step of feeding or cofeeding, with ethylene, and from 0 to 50 mole % of one or more comonomers, where the polymerization occurs at a temperature between 50 and 120°C, and the molar ratio of aluminum from the cocatalyst to the chromium in the supported chromium catalyst is 30:1 or more.
摘要:
This invention relates to a continuous process to produce a branched olefin polymer comprising: 1) selecting a first catalyst component capable of producing a polymer having an Mw of 100,000 or less and a crystallinity of 20% or less under selected polymerization conditions; 2) selecting a second catalyst component capable of producing polymer having an Mw of 100,000 or less and a crystallinity of 20% (preferably 40% or more) or more at the selected polymerization conditions; 3) contacting a catalyst component, one or more activators and one or more C2 to C40 olefins in a first reaction zone, at a temperature of greater than 70°C, and at a residence time of 120 minutes or less; and 4) transferring the contents of the first reaction zone to a second reaction zone and further contacting the contents with a catalyst component, an activator and or one or more C2 to C40 olefins, at a temperature of greater than 70°C, and at a residence time of 120 minutes or less; and 5) optionally, transferring the contents of the second reaction zone to a third reaction zone and further contacting the contents with a catalyst compound, an activator and or one or more C2 to C40 olefins, at a temperature of greater than 70°C, and at a residence time of 120 minutes or less; and 6) recovering a branched olefin polymer comprising at least 50 o mole % of one or more C3 to C40 olefins, where the first catalyst component is present in at least one reaction zone and the second catalyst component is present in a second reaction zone and where in at least one reaction zone the C2 to C40 olefin is a C3 to C40 alpha-olefin.
摘要:
The present invention relates to radiation resistant plasticized polyolefin compositions comprising a polyolefin and a non-functionalized hydrocarbon plasticizer.
摘要:
Stretch films are disclosed, the films having at least one layer formed of or including a polyethylene copolymer and having a natural draw ratio of at least 250%, a tensile stress at the natural draw ratio of at least 22 MPa, and a tensile stress at second yield of at least 12 MPa. In some embodiments, the polyethylene copolymer can have a CDBI of at least 70%, a melt index 12.16 of from 0.1 to 15 g/10 min., a density of from 0.910 to 0.940 g/cm3, a melt index ratio 121.6/12.16 of from 30 to 80, and an Mw/Mn ratio of from 2.5 to 5.5. The stretch films are particularly useful in bundling and packaging applications.
摘要:
The invention is directed to a method for preparing microporous aluminophosphate or silicoaluminophosphate molecular sieves having the CHA framework type, the process comprising the steps of (a) forming a reaction mixture comprising a source of aluminum, a source of phosphorus, optionally a source of silicon, at least one source of fluoride ions and at least one template containing one or more N,N-dimethylamino moieties, (b), inducing crystallization of aluminophosphate and/or silicoaluminophosphate molecular sieve from the reaction mixture, and (c) recovering aluminophosphate and/or silicoaluminophosphate molecular sieve from the reaction mixture. The invention also relates to the molecular sieves obtained by this method and to molecular sieve catalyst compositions containing these molecular sieves.