摘要:
Provided are a polypropylene resin composition comprising a polypropylene resin (A), a specific fiber (B), an organic flame retardant (C) and a polytetrafluoroethylene resin (D) each in a specific amount, and a molded article obtained by molding the composition.
摘要:
A polar-group-containing olefin copolymer which comprises 99.999 to 80 mol% of structural units derived from at least one of ethylene and ±-olefin having 3 to 20 carbon atoms and 20 to 0.001 mol% of structural units derived from at least one polar-group-containing monomer which contains an epoxy group and is represented by the following structural formula (I) or following structural formula (II), the polar-group-containing olefin copolymer being a random copolymer obtained by copolymerization in the presence of a transition metal catalyst and having a linear molecular structure.
摘要:
Provided are a metallocene complex that facilitates copolymerization of olefin monomers including propylene at a higher uptake rate of comonomers, i.e., ethylene and ±-olefin, manufacture of a rubber component having a higher molecular weight, and manufacture of homopolypropylene having a higher melting point through homopolymerization of propylene, compared to traditional metallocene catalysts, and a method of olefin polymerization in the presence of such a metallocene complex. Also provided are, for example, a metallocene complex represented by general formula [I] (e.g., a metallocene complex having a substituent at position 6 of one or each indenyl ring and an optionally substituted furyl or thienyl group at position 2 of one or each indenyl ring), an olefin polymerization catalyst containing the metallocene complex, and a method of olefin polymerization involving olefin polymerization or copolymerization in the presence of the olefin polymerization catalyst.
摘要:
An object is to develop a method for stably producing a propylene-based polymer together with inhibiting generation of an aggregated polymer, reducing a generation amount of fine powder, and thereby enhancing production efficiency. The present invention relates to a method for producing a propylene-based polymer, comprising polymerizing propylene or propylene and an ±-olefin except propylene in the presence of a catalyst using a horizontal polymerization reactor equipped with a stirrer rotating around a horizontal axis in the inside of the reactor by a continuous vapor-phase polymerization method in which heat of reaction is removed by heat of vaporization of liquefied propylene, wherein the reactor can set a plurality of area sections different in temperature in a horizontal axis direction in the inside of the reactor and at least one of the following requirements (A) and (B) is satisfied: requirement (A): temperature difference ”T1 (°C) (= TÉ - T±) between temperature (T±) of an area section including an upstream end of the reactor and temperature (TÉ) of an area section including a downstream end thereof is 0.1 to 20°C; requirement (B): temperature difference ”T2 (°C) (= Tx - Tz) between temperature (Tx) of an area section including a catalyst feed part and dew point (Tz) of mix gas in the reactor is 0 to 5°C.
摘要:
A process for producing an olefin polymer through olefin polymerization in the presence of a metallocene transition metal catalyst, while preventing polymer deposition on the reactor wall and preventing the generation of a sheet-form polymer, massive polymer, etc. to stably conduct the polymerization operation over long. The process is characterized by polymerizing an olefin in the presence of [A] a metallocene transition metal catalyst and [B] an organoaluminum compound represented by the general formula R1n Al(OR2)3-n (wherein R1 represents C¿1-20? alkyl, aryl, hydrogen, or halogeno; R?2¿ represents C¿1-20? alkyl or aryl; and n is a number satisfying 0≤n∫3) under such conditions that the temperature of the polymerizer wall, tw (°C), and the polymerization temperature, tr (°C), satisfy the following relationship 1: 0.5