公开(公告)号：EP2892879B1

公开(公告)日：2020-07-22

申请号：EP13835855.1

申请日：2013-09-04

申请人： Goussev, Dmitri ,  Spasyuk, Denis ,  Smith, Samantha

发明人： Goussev, Dmitri ,  Spasyuk, Denis ,  Smith, Samantha

IPC分类号： C07C323/25 ,  B01J31/22 ,  C01B3/02 ,  C07C209/30 ,  C07C209/44 ,  C07C29/132 ,  C07C5/03 ,  B01J31/18 ,  B01J31/20 ,  B01J31/24 ,  C01B3/04 ,  C01B3/26 ,  C07C29/147 ,  C07C67/00 ,  C07C41/18 ,  C07C45/00 ,  C07F15/00 ,  C07C209/52 ,  C07C5/08

公开(公告)号：EP2892879A4

公开(公告)日：2016-04-20

申请号：EP13835855

申请日：2013-09-04

申请人： GOUSSEV DMITRI ,  SPASYUK DENIS ,  SMITH SAMANTHA

发明人： GOUSSEV DMITRI ,  SPASYUK DENIS ,  SMITH SAMANTHA

IPC分类号： C07C323/25 ,  B01J31/18 ,  B01J31/20 ,  B01J31/22 ,  B01J31/24 ,  C01B3/02 ,  C01B3/04 ,  C01B3/26 ,  C07C5/03 ,  C07C5/08 ,  C07C29/132 ,  C07C29/147 ,  C07C41/18 ,  C07C45/00 ,  C07C67/00 ,  C07C209/30 ,  C07C209/44 ,  C07C209/52 ,  C07F15/00

CPC分类号： C07C67/40 ,  B01J31/1805 ,  B01J31/1895 ,  B01J31/20 ,  B01J31/22 ,  B01J31/226 ,  B01J31/2295 ,  B01J31/2404 ,  B01J2231/641 ,  B01J2231/643 ,  B01J2231/645 ,  B01J2231/70 ,  B01J2231/763 ,  B01J2531/0238 ,  B01J2531/821 ,  B01J2531/825 ,  C01B3/02 ,  C01B3/04 ,  C01B3/26 ,  C01B2203/0277 ,  C01B2203/1064 ,  C07C5/03 ,  C07C5/08 ,  C07C29/147 ,  C07C41/18 ,  C07C45/002 ,  C07C67/00 ,  C07C209/52 ,  C07C323/25 ,  C07C2531/22 ,  C07C2531/24 ,  C07F15/0026 ,  C07F15/0046 ,  C07F15/0053 ,  Y02E60/364 ,  C07C211/45 ,  C07C9/06 ,  C07C9/15 ,  C07C15/073 ,  C07C47/06

摘要： The present application discloses novel amino-sulfide metal catalysts for organic chemical syntheses including hydrogenation (reduction) of unsaturated compounds or dehydrogenation of substrates. The range of hydrogenation substrate compounds includes esters, lactones, oils and fats, resulting in alcohols, diols, and triols as reaction products. The catalysts of current application can be used to catalyze a hydrogenation reaction under solvent free conditions. The present catalysts also allow the hydrogenation to proceed without added base, and it can be used in place of the conventional reduction methods employing hydrides of the main-group elements. Furthermore, the catalysts of the present application can catalyze a dehydrogenation reaction under homogenous and/or acceptorless conditions. As such, the catalysts provided herein can be useful in substantially reducing cost and improving the environmental profile of manufacturing processes for a variety of chemicals.

公开(公告)号：EP2892879A1

公开(公告)日：2015-07-15

申请号：EP13835855.1

申请日：2013-09-04

申请人： Goussev, Dmitri ,  Spasyuk, Denis ,  Smith, Samantha

发明人： Goussev, Dmitri ,  Spasyuk, Denis ,  Smith, Samantha

IPC分类号： C07C323/25 ,  B01J31/22 ,  C01B3/02 ,  C07C209/30 ,  C07C209/44 ,  C07C29/132 ,  C07C5/03

CPC分类号： C07C67/40 ,  B01J31/1805 ,  B01J31/1895 ,  B01J31/20 ,  B01J31/22 ,  B01J31/226 ,  B01J31/2295 ,  B01J31/2404 ,  B01J2231/641 ,  B01J2231/643 ,  B01J2231/645 ,  B01J2231/70 ,  B01J2231/763 ,  B01J2531/0238 ,  B01J2531/821 ,  B01J2531/825 ,  C01B3/02 ,  C01B3/04 ,  C01B3/26 ,  C01B2203/0277 ,  C01B2203/1064 ,  C07C5/03 ,  C07C5/08 ,  C07C29/147 ,  C07C41/18 ,  C07C45/002 ,  C07C67/00 ,  C07C209/52 ,  C07C323/25 ,  C07C2531/22 ,  C07C2531/24 ,  C07F15/0026 ,  C07F15/0046 ,  C07F15/0053 ,  Y02E60/364 ,  C07C211/45 ,  C07C9/06 ,  C07C9/15 ,  C07C15/073 ,  C07C47/06

摘要： The present application discloses novel amino-sulfide metal catalysts for organic chemical syntheses including hydrogenation (reduction) of unsaturated compounds or dehydrogenation of substrates. The range of hydrogenation substrate compounds includes esters, lactones, oils and fats, resulting in alcohols, diols, and triols as reaction products. The catalysts of current application can be used to catalyze a hydrogenation reaction under solvent free conditions. The present catalysts also allow the hydrogenation to proceed without added base, and it can be used in place of the conventional reduction methods employing hydrides of the main-group elements. Furthermore, the catalysts of the present application can catalyze a dehydrogenation reaction under homogenous and/or acceptorless conditions. As such, the catalysts provided herein can be useful in substantially reducing cost and improving the environmental profile of manufacturing processes for a variety of chemicals.

摘要翻译： 本申请公开了用于有机化学合成的新型氨基硫化物金属催化剂，包括不饱和化合物的氢化（还原）或底物脱氢。 氢化底物化合物的范围包括酯，内酯，油和脂肪，产生醇，二醇和三醇作为反应产物。 目前应用的催化剂可用于在无溶剂条件下催化氢化反应。 本催化剂还允许氢化进行而不添加碱，并且可以用代替采用主要组分的氢化物的常规还原方法。 此外，本申请的催化剂可以在均匀和/或无接受条件下催化脱氢反应。 因此，本文提供的催化剂可用于显着降低成本并改善各种化学品的制造方法的环境特征。