摘要:
Synthetic hydrotalcites of the general formula [M2+1-xM3+x(OH) 21 x+ [An x/n. 11H20]x where M2+ is a divalent cation, M3+ is a trivalent cation and A°- is an organic anion selected from straight chain carboxylates of C16-CI8 acids, carboxylates of aromatic acids, carboxylates of acrylic acid, unsaturated carboxylates of methacrylic acid, unsaturated carboxylates of vinylacetic acid and C2 and higher organic acids containing heteroatoms such as nitrogen, phosphorous, sulfur and halogens are disclosed, along with methods of synthesis and uses.
摘要:
A process for the reduction of methylbenzofuran (MBF) impurities in phenol obtained from the decomposition product of cumene hydroperoxide requires treating the phenol to reduce the level of acetol, contacting the phenol containing a low level of acetol with an acid resin at sufficient temperature and residence time to reduce the level of MBF by conversion to higher boiling compounds, then distilling the phenol to separate phenol from higher boiling compounds. The phenol may be treated in known ways, such as by treatment with an amine, to reduce the level of acetol. The phenol containing a low level of acetol is contacted with a strong acid resin to reduce the level of MBF.
摘要:
A method is provided for the efficient, low cost removal of acetol from a phenol stream. The method results in removal of substantially all of the acetol from the phenol stream without the formation of substantial amounts of additional methylbenzofuran. The method also avoids the use of expensive reagents and capital intensive distillation equipment.
摘要:
A paintable impact copolymer composition is produced by in-reactor blending of a xylene insoluble polypropylene fraction and a xylene soluble ethylene-propylene rubber (EPR) fraction. The composition comprises from about 5 wt. % to about 50 wt.% a xylene-soluble portion and from about 50 wt. % to about 95 wt. % a xyleneinsoluble portion. The ratio of the weight average molecular weight of said xylenesoluble portion to that of said xylene-insoluble portion is from about 0.5 to about 1.8. The intrinsic viscosity of said xylene-soluble portion is from about 0.5 to about 7.0 dL/g. The xylene-soluble portion comprises from about 30 to about 70 mole percent ethylene units.
摘要:
Polypropylene resin compositions are provided that are useful in the production of biaxially oriented polypropylene films (BOPPs). The resins of the present invention are blends of high crystalline (low solubles) polypropylene homopolymer and an ethylene/propylene random copolymer (RCP). These blends can be used to replace standard high solubles BOPP grade polypropylene homopolymers. In addition, the use of high crystalline polypropylene homopolymers in the blends imparts improved stiffness to the finished films while maintaining good processability of the blends.
摘要:
A process for removing methylbenzofuran from phenol comprissing: - treating the phenol stream to reduce the level of acetol, - passing the phenol stream through a fixed bed of strong acid aromatic sulfonic acid resin, - distilling the phenol.
摘要:
Alkanes are converted to alkenes by contacting an alkane with an oxidizing agent and a heteropolyacid supported on a polyoxometallate salt. Also disclosed are catalyst compositions of heteropolyacids supported on polyoxometallate salts and methods of preparing these catalyst compositions.
摘要:
A method of manufacturing an improved clarity, low haze, low melt flow rate homopolymer polypropylene and thermoformed parts therefrom using an additive package such that the additive package alone provides the improved qualities, and process adjustments at the thermoforming stage are not required. The additive package does not contain a phosphite antioxidant, and the homopolymer polypropylene is either virgin material or virgin material mixed with at least 25 percent reground homopolymer polypropylene of the improved formulation described herein and combined with the improved clarity additive package.