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    PROCESS FOR THE CATALYTIC DEHYDROGENATION OF ALKANES TO ALKENES WITH SIMULTANEOUS COMBUSTION OF HYDROGEN
    5.
    发明公开
    PROCESS FOR THE CATALYTIC DEHYDROGENATION OF ALKANES TO ALKENES WITH SIMULTANEOUS COMBUSTION OF HYDROGEN 失效
    同时燃烧氢气将烷烃催化脱氢制氢的方法

    公开(公告)号：EP0832055A1

    公开(公告)日：1998-04-01

    申请号：EP95920511.0

    申请日：1995-05-17

    申请人： MOBIL OIL CORPORATION

    发明人： AGASKAR, Pradyot, Adwaitanand ,  GRASSELLI, Robert, Karl ,  MICHAELS, James, Nathaniel ,  REISCHMAN, Paul, Thomas ,  STERN, David, Lawrence ,  TSIKOYIANNIS, John, George

    IPC分类号： C07C5

    CPC分类号： C07C5/3335 ,  C07C5/3337 ,  C07C5/42 ,  C07C2529/44 ,  C07C11/02

    摘要： There is provided a process for the net catalytic oxidative dehydrogenation of alkanes to produce alkenes. The process involves simultaneous equilibrium dehydrogenation of alkanes to alkenes and combustion of the hydrogen formed to drive the equilibrium dehydrogenation reaction further to the product alkenes. In the present reaction, the alkane feed is dehydrogenated over an equilibrium dehydrogenation catalyst in a first reactor, and the effluent from the first reactor is then passed into a second reactor containing a reducible metal oxide which serves to selectively combust hydrogen in an oxidation/reduction (REDOX) reaction. This particular mode of operation is termed a separate reactor, REDOX mode.

    摘要翻译： 提供了用于烷烃净催化氧化脱氢生产烯烃的方法。 该方法包括将烷烃同时平衡脱氢成烯烃和形成的氢的燃烧，以进一步驱使产物烯烃进行平衡脱氢反应。 在本反应中，烷烃原料在第一反应器中通过平衡脱氢催化剂脱氢，然后来自第一反应器的流出物通入含有可还原金属氧化物的第二反应器中，所述可还原金属氧化物用于选择性氧化氧化/还原 （REDOX）反应。 这种特定的操作模式被称为单独的反应器，即REDOX模式。

    Process for dehydrogenating hydrocarbons and oxygenated hydrocarbons
    6.
    发明公开
    Process for dehydrogenating hydrocarbons and oxygenated hydrocarbons 失效
    一种用于烃和含氧烃的脱氢方法。

    公开(公告)号：EP0543535A1

    公开(公告)日：1993-05-26

    申请号：EP92310109.1

    申请日：1992-11-04

    申请人： BP Chemicals Limited

    发明人： Cooper, Jeremy Bernard, BP Chemicals Limited ,  Frost, Jonathon Charles, The British Petroleum ,  Partington, Stephen Roy, The British Petroleum

    IPC分类号： C07C5/42 ,  C07C27/10 ,  C01F17/00

    CPC分类号： C07C45/002 ,  B01J23/66 ,  B01J23/96 ,  B01J37/03 ,  C07C5/324 ,  C07C5/3335 ,  C07C5/42 ,  C07C2523/10 ,  C07C2523/52 ,  C07C2523/66 ,  Y02P20/52 ,  Y02P20/584 ,  C07C11/04

    摘要： A continuous process for the dehydrogenation of a hydrocarbon and/or oxygenated hydrocarbon feed, comprising contacting the hydrocarbon and/or oxygenated hydrocarbon feed with a dehydrogenation catalyst at elevated temperature in a reaction zone characterised in that the catalyst is capable of retaining hydrogen and (a) is contacted with a feed to form a dehydrogenated product and hydrogen, at least some of the hydrogen formed being adsorbed by the catalyst and/or reacting therewith to reduce at least part of the catalyst; (b) the dehydrogenated product and any unadsorbed/unreacted hydrogen is removed from the reaction zone; (c) at least some of the adsorbed hydrogen is removed from the catalyst and/or at least some of the reduced catalyst is oxidised; and (d) reusing the catalyst from step (c) in step (a).

    摘要翻译： 用于脱氢的连续方法的烃和/或含氧烃进料，其包括在反应区中在升高的温度下接触的烃和/或含氧烃进料与脱氢催化剂DASS的催化剂是能够保持氢和（一个 ）与进料接触，以形成脱氢产物和氢气，至少一些氢气的形成吸附在催化剂和/或起反应那里与降低催化剂的至少一部分; （B）的脱氢产物和任何未吸附的/未反应的氢气从反应区除去 （C）中的至少一些吸附的氢被从催化剂去除和/或至少一些所述还原的催化剂被氧化; 和（d）从重复使用步骤（c）在步骤中的催化剂（a）中。

    Process of oxidizing aliphatic hydrocarbons in the presence of a solid heterogeneous catalyst and catalyst
    7.
    发明公开
    Process of oxidizing aliphatic hydrocarbons in the presence of a solid heterogeneous catalyst and catalyst 失效
    Verfahren zur Oxydation aliphatischer Kohlenwasserstoffe mit einem Molybdat-Katalysator。

    公开(公告)号：EP0409355A1

    公开(公告)日：1991-01-23

    申请号：EP90201980.1

    申请日：1990-07-19

    申请人： THE DOW CHEMICAL COMPANY

    发明人： Khazai, Bijan ,  Vrieland, Edwin G. ,  Murchison, Graig B.

    IPC分类号： C07C5/48 ,  C07C11/167 ,  B01J23/28 ,  B01J32/00

    CPC分类号： C07C5/42 ,  B01J23/28 ,  B01J37/0018 ,  C03C14/004 ,  C03C2214/04 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2521/10 ,  C07C2523/04 ,  C07C2523/28 ,  C07C11/167

    摘要： A process for the production of olefins and diolefins, such as 1,3-butadiene, comprising contacting an aliphatic hydrocarbon, such as butane, with a heterogeneous catalyst composition containing reactive oxygen under reaction conditions such that a more highly unsaturated aliphatic hydrocarbon is selectively formed in a high productivity. The catalyst is a composition comprising a catalyst component of magnesia, an oxide of molybdenum, a Group IA metal oxide promoter, and optionally vanadium oxide. In a preferred embodiment, the catalyst composition also comprises a support component of magnesium and alumina and/or magnesium aluminate spinel. The present catalyst has high surface area and high attrition resistance.

    摘要翻译： 一种生产烯烃和二烯烃如1,3-丁二烯的方法，包括在反应条件下使脂族烃如丁烷与含有活性氧的非均相催化剂组合物接触，使得选择性地形成更高度不饱和的脂族烃 在高生产率。 催化剂是包含氧化镁的催化剂组分，钼的氧化物，第IA族金属氧化物促进剂和任选的氧化钒的组合物。 在优选的实施方案中，催化剂组合物还包含镁和氧化铝和/或铝酸镁尖晶石的载体组分。 本催化剂具有高表面积和高耐磨性。