摘要:
A battery electrode comprises an electrically conductive substrate having an electrochemically active electrode composition supported thereupon. The composition includes an active material capable of reversibly alloying with lithium, which material shows a volume change upon such reversible alloying. The composition includes a buffering agent which accommodates the volume change in the active material and minimizes mechanical strain in the composition. The active composition may further include materials such as carbon. The active material may comprise silicon, aluminum, antimony, antimony oxides, bismuth, bismuth oxides, tin, tin oxides, chromium, chromium oxides, tungsten, and tungsten oxides or lithium alloys of the foregoing. The buffering agent may comprise a metal or a metal oxide or lithium alloys of the foregoing. Also disclosed are batteries which incorporate these electrodes, methods for the fabrication of the electrodes and methods for the fabrication and operation of the batteries.
摘要:
A composite material having utility as a cathode material for a lithium ion battery includes a first component which is a metal phosphate and a second component which is a metal nitride, a metal oxynitride, or a mixture of the two. The second component is coated on, or dispersed through the bulk of, the first component. The metal phosphate may be a lithiated metal phosphate and may be based upon one or more transition metals. Also disclosed is a method for preparing the material as well as electrodes fabricated from the material and lithium ion cells which include such electrodes.
摘要:
A multiphase composite material having utility as an electrochemical electrode or catalyst includes a first active phase which is an amorphous, electrochemically active material; and a second, stabilizer phase which includes one or more of: metals, carbon, ceramics, and intermetallic compounds. The stabilizer phase is configured as a plurality of spaced apart regions having the active phase disposed therebetween. The active phase may comprise one or more of: Sn, Sb, Bi, Pb, Ag, In, Si, Ge, and Al. The stabilizer phase may include one or more of: Fe, Zr, Ti, and C. Also disclosed are electrodes and batteries which include the material as well
摘要:
High surface area electrodes for use in electrical and electrochemical energy storage and conversion devices comprise conductive transition metal nitrides, carbides, borides or combinations thereof where the metal is molybdenum or tungsten. Disclosed is a method of manufacturing such electrodes by forming or depositing a layer of metal oxide, then exposing the metal oxide layer at elevated temperature to a source of nitrogen, carbon or boron in a chemically reducing environment to form the desired metal nitride, carbide or boride film. Also disclosed is an ultracapacitor comprised of the new high surface area electrodes having a specific capacitance of 100 mF/cm2 and an energy density of 100 mJ/cm3 with improved conductivity and chemical stability when compared to currently available electrodes.
摘要:
A catalyst comprises an electrically conductive ceramic substrate having at least one noble metal supported thereupon. The substrate may be a transition metal based ceramic such as a carbide, nitride, boride, or silicide of a transition metal, and the noble metal may comprise a mixture of noble metals. The substrate may comprise a high surface area ceramic. Also disclosed are fuel cells incorporating the catalysts.
摘要:
A non-oxide, transition metal-based ceramic material has the general formula AyM2Zx, wherein A is a group IA element, M is a transition metal and Z is selected from the group consisting of N, C, B, Si, and combinations thereof, and wherein x ≤ 2 and y ≤ 6-x. In these materials, the group IA element occupies interstitial sites in the metallic lattice, and may be readily inserted into or released therefrom. The materials may be used as catalysts and as electrodes. Also disclosed herein are methods for the fabrication of the mates.
摘要:
A catalyst comprises an electrically conductive ceramic substrate having at least one noble metal supported thereupon. The substrate may be a transition metal based ceramic such as a carbide, nitride, boride, or silicide of a transition metal, and the noble metal may comprise a mixture of noble metals. The substrate may comprise a high surface area ceramic. Also disclosed are fuel cells incorporating the catalysts.
摘要:
A transition metal based ceramic material having the general formula: LiαM1-βTβNxOδ, wherein M is a transition metal, T is a dopant metal, and wherein x is greater than 0 and less than or equal to 1, δ is 0, or less than or equal to 4; α is less than or equal to 3-x, and β is less than 1 is disclosed. The ceramic material has utility as a cathode material for rechargeable lithium batteries.
摘要:
High surface area electrodes for use in electrical and electrochemical energy storage and conversion devices comprise conductive transition metal nitrides, carbides, borides or combinations thereof where the metal is molybdenum or tungsten. Disclosed is a method of manufacturing such electrodes by forming or depositing a layer of metal oxide, then exposing the metal oxide layer at elevated temperature to a source of nitrogen, carbon or boron in a chemically reducing environment to form the desired metal nitride, carbide or boride film. Also disclosed is an ultracapacitor comprised of the new high surface area electrodes having a specific capacitance of 100 mF/cm2 and an energy density of 100 mJ/cm3 with improved conductivity and chemical stability when compared to currently available electrodes.