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1.
公开(公告)号:EP3861143A1
公开(公告)日:2021-08-11
申请号:EP19818023.4
申请日:2019-12-09
Applicant: TFL Ledertechnik GmbH
Inventor: FENNEN, Jens , AMPUERO, Rodolfo , SCHULTE-GAUCZINSKI, Nina , MEJIAS, Lorenzo
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公开(公告)号:EP1694874A1
公开(公告)日:2006-08-30
申请号:EP04791169.8
申请日:2004-10-07
Applicant: TFL Ledertechnik GmbH
Inventor: LAUTON, Alain , HERRMANN, Wolfgang , FENNEN, Jens , GABAGNOU, Catherine
IPC: C14C3/16
CPC classification number: C14C3/16
Abstract: Compositions comprising a) 5 to 50% by weight of an aliphatic dialdehyde having 2 to 10 carbon atoms; b) 2.5 to 20% by weight of at least one reductive saccharide having a dextrose equivalent of 10 to 100; c) 2.5 to 20% by weight of at least one water-soluble, optionally monoetherified polyoxaalkylene glycol having a molecular weight of more than 100 and not more than 2000; and d) 90 to 10% by weight of water, 0.05 to 0.19 mole of the components b) and c) being added per mole of the component a), outstandingly suitable for the pretanning of pelts and subsequent production of leathers free of heavy metals.
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3.
公开(公告)号:EP3440227A1
公开(公告)日:2019-02-13
申请号:EP17715042.2
申请日:2017-03-29
Applicant: TFL Ledertechnik GmbH
Inventor: GABAGNOU, Catherine , SCHULTE, Nina , HERTA, Grigore Daniel , FENNEN, Jens
IPC: C14C3/16
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公开(公告)号:EP1322813B1
公开(公告)日:2013-10-23
申请号:EP01962972.4
申请日:2001-08-27
Applicant: TFL Ledertechnik GmbH
Inventor: MCHUGH, Jon, Louis , FENNEN, Jens , PAGE, Campbell,Thomas
CPC classification number: C14C9/02 , D06P1/0032 , D06P1/008 , D06P1/645 , D06P1/65112 , D06P1/65131 , D06P1/673 , D06P3/32
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公开(公告)号:EP1831405B1
公开(公告)日:2009-03-11
申请号:EP05850465.5
申请日:2005-12-16
Applicant: TFL Ledertechnik GmbH
Inventor: LAUTON, Alain , DIREK, Aykut
IPC: C14C3/20 , C14C3/28 , C07C317/22
Abstract: Process for the treatment of wetwhite, wetblue or vegetable pretanned leather, characterized in that - for the purpose of said treatment - a composition containing a) 1 - 95% by weight of a product of the reaction of a phenol and a sulphonating agent, the molar ratio (phenol):(SO3) being (1 ):(1.1-2.2), b) 1 - 95% by weight of a product of the reaction of a naphthalenesulphonic acid and formaldehyde, and c) 5 - 50% by weight c1) of a formaldehyde condensate of a dihydroxydiarylsulphonic acid with aryl- or (hydroxy)arylsulphonic acid and/or c2) of a urea/formaldehyde condensate of a phenol and phenolsulphonic acid, the sum of the components a), b), c1) and/or c2) being 100% by weight, is added in the form of an aqueous solution to the aqueous liquor, and, if adjusted to a concentration of 50%, is added to the liquor in an amount of 1 - 20% by weight, based on the shaved weight of the hides or skins as the substrate, is added to the liquor after the first tanning and before the subsequent treatment, which includes one or more of the steps retanning, dyeing and fatliquoring, and without a neutralizing step and without a liquor change; and the leathers obtained by this process or obtained using said composition.
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公开(公告)号:EP1954840A1
公开(公告)日:2008-08-13
申请号:EP06830144.9
申请日:2006-11-27
Applicant: TFL Ledertechnik GmbH
Inventor: STRIJBOS, Leonardus
IPC: C14C9/00
CPC classification number: C14C9/00
Abstract: D-Isoascorbic acid or one of its salts, as such or as a constituent of a liquid or solid formulation, is an effective agent for reducing the amount of Cr(VI) compounds in leathers tanned with Cr(III) salts by treatment of the leather in an aqueous liquor after tanning or finishing or of a commodity article with an aqueous solution.
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公开(公告)号:EP1322813A1
公开(公告)日:2003-07-02
申请号:EP01962972.4
申请日:2001-08-27
Applicant: TFL Ledertechnik GmbH
Inventor: MCHUGH, Jon, Louis , FENNEN, Jens , PAGE, Campbell,Thomas
CPC classification number: C14C9/02 , D06P1/0032 , D06P1/008 , D06P1/645 , D06P1/65112 , D06P1/65131 , D06P1/673 , D06P3/32
Abstract: Tanned leather is (a) pretreated in an aqueous and alkaline medium either with ammonia, primary amines or a mixture of ammonia and primary amines and then with a polyfunctional organic compound containing at least one aldehyde group as a functional group, or (b) in an aqueous and acidic medium with a polyfunctional organic compound and then ammonia, primary amines or a mixture of ammonia and primary amines, and (c) then dyed in an aqueous and alkaline medium with a water-soluble dye containing at least one functional group which is capable of reacting with one of the functional groups of the organic compound, forming a covalent bond. A tanned and dyed leather is obtainable with a high colour intensity, outstanding wet fastness and excellent grain tightness, wherein the dye is permanently and covalently bonded to the leather via a bridging group, preferably in the region of the surface, and the bridging group is essentially bonded to the leather via -N=CH- groups.
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公开(公告)号:EP4008691A1
公开(公告)日:2022-06-08
申请号:EP20211257.9
申请日:2020-12-02
Applicant: TFL Ledertechnik GmbH
Inventor: Rabe, Volker , Boll, Matthias
IPC: C02F9/00 , C14C3/06 , C14C3/32 , C02F1/28 , C02F1/52 , C02F1/66 , C02F101/22 , C02F103/24
Abstract: Die vorliegende Erfindung betrifft die Entfernung von gelösten Cr(III)-verbindungen aus verbrauchten Gerbflotten durch ein Verfahren umfassend die Schritte:
a) Zugabe von Aktivkohle zu mindestens einer Cr(III)-haltigen gebrauchten Gerbflotte,
b) Erhöhung des pH der Mischung aus Schritt a) unter Durchmischung auf einen Wert von 5.5 bis 9.0 zur Ausfällung des Cr(III) unter Bildung eines Cr(III)-Niederschlag-Aktivkohle-Gemenges und
c) Abtrennung des Cr(III)-Niederschlag-Aktivkohle-Gemenges.-
9.
公开(公告)号:EP3561081A1
公开(公告)日:2019-10-30
申请号:EP19167730.1
申请日:2017-03-29
Applicant: TFL Ledertechnik GmbH
Inventor: Gabagnou, Catherine , Schulte-Gauczinski, Nina , Herta, Grigore Daniel , Fennen, Jens
IPC: C14C3/16
Abstract: Die Erfindung betrifft eine Zusammensetzung enthaltend ein Acetal eines aldehydischen Gerbstoffs zum Gerben von Häuten und/oder Fellen sowie ein Verfahren zur Gerbung von Häuten und/oder Fellen zur Herstellung von Leder, wobei ein Acetal eines aldehydischen Gerbstoffes verwendet wird. Durch Absenken des pH-Wertes kann der aldehydische Gerbstoff freigesetzt werden, wodurch ein Gerbungsschritt eingeleitet wird. Die erfindungsgemäße Zusammensetzung und das erfindungsgemäße Verfahren zeichnen sich durch eine geringere Toxizität gegenüber konventionellen Zusammensetzungen und Gerbungsverfahren aus, die auf aldehydischen Gerbstoffen beruhen. Ferner ist eine verbesserte Penetration der Gerbstoffe in tiefere Schichten der Haut und/oder des Felles möglich, so dass eine besonders homogene Gerbung erreicht wird.
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公开(公告)号:EP3024950A1
公开(公告)日:2016-06-01
申请号:EP14744532.4
申请日:2014-07-25
Applicant: TFL Ledertechnik GmbH
Inventor: FENNEN, Jens , KIENTZ, Eric , DÖPPERT, Florian , SCHULTE, Nina
CPC classification number: C14C3/28 , C14C3/10 , C14C3/14 , C14C3/20 , C14C3/22 , C14C9/02 , C14C11/006 , D06P3/00 , C09D175/04 , C08L75/08
Abstract: The present invention is directed to a process for retanning leather comprising the steps of: a) providing tanned or pre-tanned leather b) treating the tanned leather of step a) with a composition comprising hollow microspheres, preferably as an aqueous composition, the hollow microspheres have a true density of from 0.01 to 0.10 g/cm 3 (25°C) and/or a bulk density of the dry powder of 0.005 to 0.06 g/cm 3 (25°C), c) drying, whereby the temperature of the leather during drying does not exceed 75 °C.as well as to leather obtained by said process.
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