摘要:
A poly(oxyalkylene) polymer and a metal salt of a carboxylic acid, sulfonic acid, or alkylsulfate, in combination are useful as a polymer processing additive synergist. Polymer processing additive compositions, homogeneously catalyzed olefin compositions, and other extrudable polymer compositions including a poly(oxyalkylene) polymer and a metal salt of a carboxylic acid, sulfonic acid, or alkylsulfate are disclosed. Methods of reducing melt defects during the extrusion of a thermoplastic polymer, which may be a homogeneously catalyzed polyolefin, are also disclosed.
摘要:
Described herein is a melt-processible polymer composition comprising: a non-fluorinated melt-processible polymer; and a fluoropolymer derived from the polymerization of a monomer and a sulfinate-containing molecule, wherein the sulfinate-containing molecule is selected from the group consisting of: (a) CX1X3═CX2—(R)p—CZ1Z2—SO2M Formula (I) (b) Formula (II); and (c) combinations thereof, wherein X1, X2, and X3 are each independently selected from H, F, Cl, a C1 to C4 alkyl group, and a C1 to C4 fluorinated alkyl group; R is a linking group; Z1 and Z2 are independently selected from F, CF3, and a perfluoroalkyl group; R1 and R2 are end-groups; p is 0 or 1; m is at least 2; and M is a cation.
摘要:
A polymer composition includes a non-fluorinated, thermoplastic polymer and a minor amount of a fluoropolymer combined with the non-fluorinated polymer. A polymer processing additive composition that includes a fluoropolymer and a polymer processing additive synergist is also disclosed. The fluoropolymer includes diads represented by formula —CF2-CF(R)—CH(R′)—CF(R″)— in a range from about 23 mole percent to about 50 mole percent. Each R is independently —CF3, —Rf, or —ORf, each R′ and R″ are independently H, F, CF3, or —Rf, and each Rf is independently a perfluoroalkyl group having from 1 to 12 carbon atoms and optionally interrupted by one or more —O— groups. A method of reducing melt defects during the extrusion of a polymer is also disclosed.
摘要:
A polymer composition includes a non-fluorinated, thermoplastic polymer and a minor amount of a fluoropolymer combined with the non-fluorinated polymer. A polymer processing additive composition that includes a fluoropolymer and a polymer processing additive synergist is also disclosed. The fluoropolymer includes diads represented by formula —CF2-CF(R)—CH(R′)—CF(R″)— in a range from about 23 mole percent to about 50 mole percent. Each R is independently —CF3, —Rf, or —ORf, each R′ and R″ are independently H, F, CF3, or —Rf, and each Rf is independently a perfluoroalkyl group having from 1 to 12 carbon atoms and optionally interrupted by one or more —O— groups. A method of reducing melt defects during the extrusion of a polymer is also disclosed.
摘要:
A poly(oxyalkylene) polymer having a weight average molecular weight of at least 50,000 grams per mole and a metal salt of a carboxylic acid, sulfonic acid, or alkylsulfate, in combination are useful as a polymer processing additive. In some embodiments, the polymer processing additive further includes a poly(oxyalkylene) polymer having a weight average molecular weight of up to 20,000 grams per mole Polymer processing additive compositions and thermoplastic, for example, polyolefm, compositions including a poly(oxyalkylene) polymer and a metal salt of a carboxylic acid, sulfonic acid, or alkylsulfate are disclosed. Methods of reducing melt defects during the extrusion of a thermoplastic polymer, which may be a homogeneously catalyzed polyolefin, are also disclosed.
摘要:
A composition includes a first amorphous fluoropolymer having a first Mooney viscosity ML 1+10 @ 121°C less than 60 and a second amorphous fluoropolymer having a second Mooney viscosity ML 1+10 @ 121°C greater than 80. The composition further includes at least one of a non-fluorinated, thermoplastic polymer as a major component of the composition or a polymer processing additive synergist. A method of reducing melt defects during the extrusion of a polymer is also provided. Use of a combination of the first and second amorphous fluoropolymers as a polymer processing additive is also provided.