摘要:
This application relates to synthetic fuels and to a method of running compression ignition engines into which the fuels are injected or inducted. The fuels comprise mixtures of (A) at least one alcohol with an average molecular weight of less than 160 and (B) at least one further organic compound having a spontaneous ignition temperature of less than 450°C. Suitable alcohols (component (A)) include methanol, ethanol, propa- nols, isopropanol, butanol. The further organic compound or compounds (component (B)) may be selected from a wide range of compounds including alcohols, ethers, aldehydes for example acetaldehyde, compounds containing one or more nitrate groups and one or more ether linkages for example 2-ethoxyethyl nitrate, and nitrogen-containing organic compounds including azo compounds, tetrazines, nitroso compounds, nitro compounds, certain nitrate compounds and hyponitrites.
摘要:
This application relates to synthetic fuels and to a method of running compression ignition engines into which the fuels are injected or inducted. The fuels comprise mixtures of (A) at least one alcohol with an average molecular weight of less than 160 and (B) at least one further organic compound having a spontaneous ignition temperature of less than 450°C. Suitable alcohols (component (A)) include methanol, ethanol, propa- nols, isopropanol, butanol. The further organic compound or compounds (component (B)) may be selected from a wide range of compounds including alcohols, ethers, aldehydes for example acetaldehyde, compounds containing one or more nitrate groups and one or more ether linkages for example 2-ethoxyethyl nitrate, and nitrogen-containing organic compounds including azo compounds, tetrazines, nitroso compounds, nitro compounds, certain nitrate compounds and hyponitrites.
摘要:
The invention concerns a composition of matter comprising a mixture of (A) at least one alcohol with an average molecular weight of less than 160 and (B) at least one organic compound of formula wherein x = an integer greater than 3, and wherein the molecular weight (or average molecular weight) of the compound(s) is between 260 and 480. The composition may be used as a fuel for compression ignition engines.
摘要:
The invention concerns a composition of matter comprising a mixture of (A) at least one alcohol with an average molecular weight of less than 160 and (B) at least one organic compound of formula wherein x = an integer greater than 3, and wherein the molecular weight (or average molecular weight) of the compound(s) is between 260 and 480. The composition may be used as a fuel for compression ignition engines.
摘要:
The invention concerns a process for the preparation of nitric acid esters of organic hydroxy compounds by reacting an organic hydroxy compound with nitric acid in the presence of sulphuric acid and in a solvent, followed by separating off the spent acid, substantially neutralizing the residual acidity of the organic solution, and removing solvent to leave the organic nitrate. From 95% to 220% of the stoichiometric requirement of nitric acid for complete nitration is used. The mole ratio of water to sulphuric acid at the end ofthe reaction is from 0,2:1 to 2,5:1. From 200 to 2000 ml of solvent per mole of hydroxy group is present. Yields of at least 92% are obtained. The invention is particularly suitable for the preparation of alkyl nitrates, alkylene or polyalkylene glycol, monoalkyl ether mononitrates, alkylene or polyalkylene glycol dinitrates, diol nitrates, nitrates containing homocyclic or heterocyclic rings, or nitrates derived from polyols.
摘要:
The invention concerns a process for the preparation of nitric acid esters of organic hydroxy compounds by reacting an organic hydroxy compound with nitric acid in the presence of sulphuric acid and in a solvent, followed by separating off the spent acid, substantially neutralizing the residual acidity of the organic solution, and removing solvent to leave the organic nitrate. From 95% to 220% of the stoichiometric requirement of nitric acid for complete nitration is used. The mole ratio of water to sulphuric acid at the end ofthe reaction is from 0,2:1 to 2,5:1. From 200 to 2000 ml of solvent per mole of hydroxy group is present. Yields of at least 92% are obtained. The invention is particularly suitable for the preparation of alkyl nitrates, alkylene or polyalkylene glycol, monoalkyl ether mononitrates, alkylene or polyalkylene glycol dinitrates, diol nitrates, nitrates containing homocyclic or heterocyclic rings, or nitrates derived from polyols.