摘要:
The invention concerns ion liquids derived from the reaction of at least a halogenated or oxyhalogenated Lewis acid based on titanium, niobium, tantalum, tin or antimony with an organic salt of formula X+A- wherein A- is a halide or hexafluoroantimoniate anion and X+ a quaternary ammonium, quaternary phosphonium or ternary sulphonium cation. Said liquids are in particular useful for liquid phase HF fluorination of saturated or unsaturated compounds with C-CI bonds.
摘要:
The invention concerns the use of an acid selected among the C2-C4 percarboxylic acids for decontaminating materials soiled by organophosphorous and/or organosulphurous compounds. The percarboxylic acid is in particular in the form of an anhydrous or substantially anhydrous organic solution of said percarboxylic acid, such as is obtained by reacting an aqueous hydrogen peroxide solution with the corresponding carboxylic acid miscible in water, in the presence of a catalyst and an organic solvent optionally the one whereby water has been continuously eliminated from the reaction medium by azeotropic distillation.