PROCESS FOR THE MANUFACTURE OF TETRAFLUOROOLEFINS
    4.
    发明公开
    PROCESS FOR THE MANUFACTURE OF TETRAFLUOROOLEFINS 审中-公开
    生产四氟乙烯的方法

    公开(公告)号:EP2558432A4

    公开(公告)日:2013-10-09

    申请号:EP11769341

    申请日:2011-04-08

    申请人: ARKEMA INC

    IPC分类号: C07C17/08

    摘要: A method for producing a tetrafluoroolefin, such as 2,3,3,3-tetrafluoropropene (HFO-1234yf), comprises contacting 1,1,1,2-tetrachloro-2-fluoropropane (HCFC-241bb) with or without a catalyst under conditions effective to convert the 1,1,1,2-tetrachloro-2-fluoropropane (HCFC-241bb) to the tetrafluoroolefin, optionally, via an intermediate. The conversion may be a one-step fluorination or a two-step fluorination and dehydrochlorination process. The 1,1,1,2-tetrachloro-2-fluoropropane (HCFC-241bb) may also be obtained by dehydrochlorinating 1,2,3-trichloropropane (HCC-260da) to form 2,3-dichloropropene (HCO-1250xf); fluorinating 2,3-dichloropropene (HCO-1250xf) to form 1,2-dichloro-2-fluoropropane (HCFC-261bb); and chlorinating 1,2-dichloro-2-fluoropropane (HCFC-261bb) to form 1,1,1,2-tetrachloro-2-fluoropropane (HCFC-241bb).

    METHOD OF SELECTING REFRIGERANT-LUBRICANT COMBINATIONS
    10.
    发明公开
    METHOD OF SELECTING REFRIGERANT-LUBRICANT COMBINATIONS 审中-公开
    VERFAHREN ZUR AUSWAHL VONKÜHL-UND SCHMIERKOMBINATIONEN

    公开(公告)号:EP2519599A4

    公开(公告)日:2017-05-03

    申请号:EP10841562

    申请日:2010-12-20

    申请人: ARKEMA INC

    IPC分类号: C09K5/00

    摘要: The present invention provides methods for selecting refrigerant and lubricant combinations for use in heat transfer cycle systems and provides methods for operating said heat transfer systems. More particularly, the invention provides methods to select lubricant and refrigerant combinations for a heat transfer cycle system wherein at the lower temperatures of the heat transfer cycle the refrigerant and lubricant are miscible and at the upper temperatures of the heat transfer cycle the refrigerant and lubricant are phase separated and such that the density phase inversion temperature of the combination is below the upper operating temperature of the heat transfer cycle.

    摘要翻译: 本发明提供了用于选择用于传热循环系统的制冷剂和润滑剂组合的方法,并且提供了用于操作所述传热系统的方法。 更具体地说,本发明提供了选择用于传热循环系统的润滑剂和制冷剂组合的方法,其中在传热循环的较低温度下,制冷剂和润滑剂是可混溶的,并且在传热循环的较高温度下,制冷剂和润滑剂是 相分离并且使得该组合的密度相转化温度低于传热循环的上操作温度。