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公开(公告)号:EP0610861B1
公开(公告)日:1997-05-28
申请号:EP94101831.9
申请日:1994-02-07
发明人: Osawa, Ryoko, c/o Asahi Glass Company Ltd. , Maekawa, Takashige, c/o Asahi Glass Company Ltd. , Momii, Tatsuo, c/o Asahi Glass Company Ltd. , Kamata, Satoshi, c/o Asahi Glass Company Ltd.
IPC分类号: C07C49/84 , C07C49/83 , C07C49/835 , C07C69/712 , C07C69/708 , C07C69/63 , C08K5/13 , C08L27/12
CPC分类号: C08K5/132 , C07C49/84 , C07C69/63 , C07C69/708 , F05C2201/0433 , F05C2203/0813 , C08L27/12
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公开(公告)号:EP0610861A1
公开(公告)日:1994-08-17
申请号:EP94101831.9
申请日:1994-02-07
发明人: Osawa, Ryoko, c/o Asahi Glass Company Ltd. , Maekawa, Takashige, c/o Asahi Glass Company Ltd. , Momii, Tatsuo, c/o Asahi Glass Company Ltd. , Kamata, Satoshi, c/o Asahi Glass Company Ltd.
IPC分类号: C07C49/84 , C07C49/83 , C07C49/835 , C07C69/712 , C07C69/708 , C07C69/63 , C08K5/13 , C08L27/12
CPC分类号: C08K5/132 , C07C49/84 , C07C69/63 , C07C69/708 , F05C2201/0433 , F05C2203/0813 , C08L27/12
摘要: A fluorine-containing benzophenone derivative of the formula (1), (2) or (3):
Φ¹ (-X¹-Q¹-R f ¹) n (1)
Φ²-X²-Q²-R f ²-Q³-X³-Φ³ (2)
Φ⁴-X⁴-Q f -X⁵-Φ⁵ (3)
wherein Φ¹ is a 2-hydroxybenzophenone structure of the formula ka-1:
(wherein Y is a hydrogen atom or a hydroxyl group, each of k and m indicates the number of bond sites, k is an integer of from 0 to 3, and m is an integer of from 0 to 3, provided that 1≦(k+m)≦4 ), n corresponds to (k+m) and is an integer of from 1 to 4, each of Φ², Φ³, Φ⁴ and Φ⁵ is a 2-hydroxybenzophenone structure of the formula ka-1 wherein (k+m) is 1, each of X¹, X², X³, X⁴ and X⁵ is a single bond or an oxygen atom, Q¹ is a single bond or a bivalent linking group having a carbon atom directly bonded to X¹, each of Q² and Q³ is a single bond or a bivalent linking group, R f ¹ is a monovalent polyfluorohydrocarbon group having from 2 to 22 carbon atoms, in which some of the carbon atoms may be substituted by ether oxygen atoms, R f ² is a bivalent polyfluorohydrocarbon group having from 2 to 22 carbon atoms, in which some of the carbon atoms may be substituted by ether oxygen atoms, and Q f is a bivalent linking group having at least one Q⁴-R f ¹ (wherein Q⁴ is a bivalent linking group, and R f ¹ is as defined above).摘要翻译: 式(1),(2)或(3)的含氟二苯甲酮衍生物:PHI 1(-X 1 -Q 1 -R f 1)n(1> PHI 2) -X 2 -Q 2 -R f 2 -Q 3 -X 3 - PH 3(2)PH 4 - -X 4 -Q f-X 5 - PHI 5其中PHI 1是式ka-1的2-羟基二苯甲酮结构:
(其中Y是氢原子或羟基,k和m各自表示键的数目 位置,k为0〜3的整数,m为0〜3的整数,条件是1(k + m)= 4),n对应于(k + m)且为 1〜4的整数,PHI 2,PHI 3,PHI 4和PHI 5各自为式ka-1的2-羟基二苯甲酮结构,其中(k + m)为1, X 1,X 2,X 3,X 4和X 5中的每一个为单键或氧原子,Q 1为单键或具有 与X 1直接键合的碳原子,Q 2和Q 3各自为单键或二价连接基团,Rf 1为具有2至22个碳原子的一价多氟烃基,其中 一些ca R原子可以被醚氧原子取代,Rf 2是具有2至22个碳原子的二价多氟烃基,其中一些碳原子可以被醚氧原子取代,Qf是二价连接基团,其具有 至少一个Q 4 -R f 1(其中Q 4是二价连接基团,Rf 1定义如上)。
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