公开(公告)号：EP2716663A4

公开(公告)日：2014-06-18

申请号：EP12794087

申请日：2012-05-11

Applicant: ASAHI KASEI CHEMICALS CORP

Inventor： ARAKI YOSHIFUMI ,  SASAYA EIJI ,  SHIBUYA KENTA

IPC: C08C19/02 ,  C08F4/48 ,  C08F212/02 ,  C08F236/04

CPC classification number: C08F236/10 ,  C08C19/02 ,  C08F212/08 ,  C08F4/48

公开(公告)号：EP2913348A4

公开(公告)日：2015-10-14

申请号：EP13848476

申请日：2013-10-22

Applicant: ASAHI KASEI CHEMICALS CORP

Inventor： ARAKI YOSHIFUMI ,  SASAYA EIJI ,  NITTA KATSUNORI

IPC: C08F8/04 ,  B01J31/02 ,  B01J31/12 ,  B01J31/14 ,  B01J31/22 ,  B01J37/04

CPC classification number: B01J31/2295 ,  B01J31/0204 ,  B01J31/0237 ,  B01J31/06 ,  B01J31/122 ,  B01J31/143 ,  B01J31/22 ,  B01J31/2282 ,  B01J31/2291 ,  B01J2231/645 ,  B01J2531/46

公开(公告)号：EP2947101A4

公开(公告)日：2016-01-20

申请号：EP14740721

申请日：2014-01-08

Applicant: ASAHI KASEI CHEMICALS CORP

Inventor： ARAKI YOSHIFUMI ,  SASAYA EIJI ,  SUZUKI TAKUYA

IPC: C08F6/06 ,  C08F2/06 ,  C08F36/04 ,  C08F236/10 ,  C08F297/04 ,  C08L9/00

CPC classification number: C08F236/10 ,  C08C2/00 ,  C08C19/02 ,  C08F6/06 ,  C08F36/04 ,  C08F297/04 ,  C08L9/00 ,  C08F2/06

公开(公告)号：EP2898950A4

公开(公告)日：2015-09-02

申请号：EP13839238

申请日：2013-09-12

Applicant: ASAHI KASEI CHEMICALS CORP

Inventor： ARAKI YOSHIFUMI ,  SASAYA EIJI ,  NITTA KATSUNORI

IPC: B01J31/22 ,  B01J31/02 ,  B01J31/12 ,  B01J31/14 ,  C07F7/28 ,  C08F8/04

CPC classification number: B01J31/2295 ,  B01J31/0204 ,  B01J31/0209 ,  B01J31/0237 ,  B01J31/122 ,  B01J31/143 ,  B01J31/22 ,  B01J2231/60 ,  B01J2231/64 ,  B01J2531/46 ,  C07F7/28 ,  C07F17/00 ,  C08C19/02 ,  C08F8/04 ,  C08F299/02 ,  C08F297/04

Abstract: A catalyst composition for hydrogenation including (A) to (D), in which a mass ratio ((C)/(A)) is 0.1 to 4.0 and a mass ratio ((D)/(A)) is 0.01 to 1.00, (A): a titanocene compound represented by formula (1), (wherein R 5 and R 6 are any group selected from hydrogen, a hydrocarbon group having 1 to 12 carbon atoms, an aryloxy group, an alkoxy group, a halogen group, and a carbonyl group. R 1 and R 2 are any group selected from the group consisting of hydrogen and a hydrocarbon group having 1 to 12 carbon atoms, and R 1 and R 2 are not all hydrogen atoms or all a hydrocarbon group having 1 to 12 carbon atoms), (B): a reductant formed from a compound containing an element selected from the elements Li, Na, K, Mg, Zn, Al, and Ca, (C): an unsaturated compound having a molecular weight of 400 or less, and (D): a polar compound.

Abstract translation: 用于氢化含（A）至（D），其中质量比（（C）/（A））为0.1〜4.0，以质量比的催化剂组合物（（D）/（A））是0时01至1:00， （A）：由式表示的二茂钛化合物（1），（worin R 5和R 6是选自氢任何基团，具有1至12个碳原子至芳氧基，上烷氧基的烃基，卤素基团， 和羰基。R 1和R 2的任何基团选自氢和具有1至12个碳原子的烃基中选择的，并且R 1和R 2不都是氢原子，或所有具有1到的烃基的 12个碳原子），（B）：从含有选自元素锂，钠，钾，镁，锌，铝，和Ca，（C）选择的元素的化合物形成的还原剂：在不饱和化合物具有400的分子量 或更小，和（D）：极性化合物。

公开(公告)号：EP2898949A4

公开(公告)日：2015-07-29

申请号：EP13838783

申请日：2013-09-12

Applicant: ASAHI KASEI CHEMICALS CORP

Inventor： ARAKI YOSHIFUMI ,  SASAYA EIJI ,  NITTA KATSUNORI

IPC: B01J31/22 ,  B01J31/02 ,  B01J31/06 ,  B01J31/12 ,  B01J31/14 ,  C07C5/03 ,  C07F7/28 ,  C08C19/02 ,  C08F8/04 ,  C08F297/04

CPC classification number: B01J31/2295 ,  B01J31/0204 ,  B01J31/0209 ,  B01J31/0237 ,  B01J31/06 ,  B01J31/12 ,  B01J31/143 ,  B01J2231/645 ,  B01J2531/46 ,  C08C19/02 ,  C08F8/04 ,  C08F297/06 ,  C08F297/04

Abstract: A catalyst composition for hydrogenation including (A) to (D), in which a mass ratio (D) / (A) is 0.01 to 2.00. (A): a titanocene compound represented by following formula (1), (wherein R 5 and R 6 are selected from the group consisting of hydrogen, a hydrocarbon group having 1 to 12 carbon atoms, an aryloxy group, an alkoxy group, a halogen group, and a carbonyl group, and R 1 and R 2 are selected from hydrogen and a hydrocarbon group having 1 to 12 carbon atoms) (B): a compound containing an element selected from Li, Na, K, Mg, Zn, Al, and Ca, (C): an unsaturated polymer having a fraction of an olefinic unsaturated double bond content of side chains based on a total olefinic unsaturated double bond content of 0.25 to 1.0, and (D): a polar compound.