摘要:
To provide an ethylene/tetrafluoroethylene copolymer which is excellent in heat resistance and flexibility. An ethylene/tetrafluoroethylene copolymer comprising repeating units (A) based on tetrafluoroethylene and repeating units (B) based on ethylene in a ratio of repeating units (A)/repeating units (B) = 66/34 to 75/25 (molar ratio) and as an optional component, repeating units (C) based on a monomer represented by CH 2 =CX(CF 2 ) n Y (wherein each of X and Y which are independent of each other is a hydrogen atom or a fluorine atom, and n is from 2 to 8) in an amount of from 0 to 1 mol% based on the total number of moles of the repeating units (A) based on tetrafluoroethylene and the repeating units (B) based on ethylene, and having a volume flow rate measured at 297°C of from 4 to 1,000 mm 3 /sec and an elastic modulus of at most 500 MPa.
摘要:
To provide a fluorinated elastomer from which it is possible to produce a crosslinked article excellent in cold resistance and excellent in mechanical strength; a fluorinated elastomer composition containing said elastomer; and a fluorinated elastomer crosslinked article obtained by molding and crosslinking said composition. The fluorinated elastomer comprises units (A) based on vinylidene fluoride and units (B) based on a perfluorovinyl ether represented by CF 2 =CF-O-R f , and has iodine atoms at main chain terminals, wherein the molar ratio [(A)/(B)] of units (A) to units (B) is from 88/12 to 50/50. In the formula, R f is a C 1-20 perfluoroalkyl group having a branched structure, or a C 2-20 perfluoroalkyl group having a branched structure and also having an etheric oxygen atom between carbon atoms.
摘要:
Provided is a fluororesin laminate in which a fluorinated copolymer layer is firmly adhered to a vinyl chloride type copolymer layer, and its production process. A fluororesin laminate comprising a layer (I) containing a fluorinated copolymer (1) having a crystallization temperature of from 100 to 220°C, a layer (II) made of an epoxy group-containing ethylene type copolymer or its composition (2) and a layer (III) made of a vinyl chloride type copolymer or its composition (3), which layers are sequentially laminated.
摘要:
To provide a fluorinated elastomer composition which is excellent in flexibility, heat resistance and flame retardance, and a molded product, cross-linked product and covered electric wire, using such a fluorinated elastomer composition. A fluorinated elastomer composition comprising a tetrafluoroethylene/propylene copolymer (a), an ethylene/tetrafluoroethylene copolymer (b), an ethylene copolymer (c) containing epoxy groups and a flame retardant (d), wherein the mass ratio [(a)/(b)] of (a) to (b) is from 70/30 to 40/60, the mass ratio [(b)/(c)] of (b) to (c) is from 100/0.1 to 100/10, and the content of (d) is from 0.1 to 30 parts by mass per 100 parts by mass of the total content of (a), (b) and (c).
摘要:
To provide a copolymer capable of producing a molded article excellent in strength at a high temperature. A copolymer comprising ethylene units, tetrafluoroethylene units and other monomer units, wherein to the sum of ethylene units and tetrafluoroethylene units, the ethylene units are from 49 to 40 mol% and the tetrafluoroethylene units are from 51 to 60 mol%; to all units in the copolymer, other monomer units are from 2.6 to 6.0 mol%; the melting point is at least 230°C; and the melt flow rate is from 1 to 15 g/10 min.
摘要:
To provide a fluorinated elastomer composition which is excellent in flexibility, heat resistance and flame retardance, and a molded product, cross-linked product and covered electric wire, using such a fluorinated elastomer composition. A fluorinated elastomer composition comprising a tetrafluoroethylene/propylene copolymer (a), an ethylene/tetrafluoroethylene copolymer (b), an ethylene copolymer (c) containing epoxy groups and a flame retardant (d), wherein the mass ratio [(a)/(b)] of (a) to (b) is from 70/30 to 40/60, the mass ratio [(b)/(c)] of (b) to (c) is from 100/0.1 to 100/10, and the content of (d) is from 0.1 to 30 parts by mass per 100 parts by mass of the total content of (a), (b) and (c).
摘要:
To provide an effective process for producing a fluorinated polymer excellent in adhesion, by using a polymerization medium having a low ozone layer destruction potential. A process for producing a fluorinated polymer, which comprises polymerizing a monomer mixture comprising a fluorinated monomer and a polar functional group-containing monomer (excluding one having a fluorine atom) in a polymerization medium, wherein the polymerization medium contains a medium compound represented by CmH 2m+1-x F x -O-C n H 2n+1-y F y (wherein m is an integer of from 1 to 6, n is an integer of from 1 to 6, x is from 0 to (2m+1), y is from 0 to 2n, and (x+y) is at least 1), and wherein a solution obtained by dissolving the polar functional group-containing monomer in the polymerization medium is continuously or intermittently added to a polymerization reaction system.
摘要:
To provide a fluorinated elastomer composition which is excellent in heat discoloration resistance and moldability, and a molded product, cross-linked product and covered electric wire, using such a fluorinated elastomer composition. A fluorinated elastomer composition comprising a fluorinated rubber (a) and a fluorinated copolymer (b), wherein the fluorinated copolymer (b) has units (A) derived from tetrafluoroethylene and units (B) derived from ethylene in a molar ratio [(A)/(B)] of the units (A) to the units (B) of from 25/75 to 80/20; the fluorinated copolymer (b) has a crystallization temperature of from 100 to 210°C and a melt flow rate of from 0.1 to 1,000 g/10 min.; and the mass ratio [(a)/(b)] of the fluorinated rubber (a) to the fluorinated copolymer (b) is from 80/20 to 20/80.