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1.发明公开LIGANDEN FÜR PNICOGENCHELATKOMPLEXE MIT EINEM METALL DER VIII. NEBENGRUPPE UND VERWENDUNG DER KOMPLEXE ALS KATALYSATOREN FÜR HYDROFORMYLIERUNG, CARBNONYLIERUNG, HYDROCYANIERUNG ODER HYDRIERUNG 有权FOR pnicogen螯合配体与八边GROUP而复杂的催化剂的氢甲酰化反应，羰基化，氰化或在氢化使用的金属
公开(公告)号：EP1383777A1
公开(公告)日：2004-01-28
申请号：EP02761895.8
申请日：2002-03-28
CPC分类号： C07F15/065 , B01J31/186 , B01J31/187 , B01J31/28 , B01J2231/321 , B01J2231/323 , B01J2231/645 , B01J2531/80 , B01J2531/821 , B01J2531/822 , B01J2531/827 , B01J2531/845 , C07C29/141 , C07C29/16 , C07C45/50 , C07C45/505 , C07F9/5721 , C07F9/5728 , C07F9/65522 , C07F9/65586 , C07F9/65842 , C07F9/65848 , C07F9/6596 , C07F15/004 , C07F15/0053 , C07F15/0066 , C07C31/125 , C07C47/02
摘要： Pnicogen chelate compounds which have two pnicogen-containing groups joined to one another via a xanthene-like or triptycene-like molecular skeleton and in which at least one pyrrole group is covalently bound via its nitrogen atom to each pnicogen atom form complexes with metals of transition group VIII which are useful as catalysts for the hydroformylation of olefins.
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公开(公告)号：EP1296993A1
公开(公告)日：2003-04-02
申请号：EP01949463.2
申请日：2001-07-04
CPC分类号： C08F110/02 , C07F15/006 , C07F15/04 , C08F10/00 , C08F4/80 , C08F2500/03 , C08F4/7016
摘要： The invention relates to metallic compounds of general formula (I), where M is either Ni or Pd in the +II oxidation state; a method for the polymerisation or co-polymerisation of olefins with said ionic metallic compounds; supported catalysts for the polymerisation and co-polymerisation of olefins, containing one or more of the ionic metallic compounds; method for production of said ionic metallic compounds and said supported catalysts and method for the polymerisation or co-polymerisation of olefins using said supported catalysts.
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公开(公告)号：EP0710260B1
公开(公告)日：1997-03-05
申请号：EP94921651.9
申请日：1994-07-16
发明人： LIPPERT, Ferdinand , HÖHN, Arthur , HOFMANN, Peter
IPC分类号： C08G67/02
CPC分类号： B01J31/2409 , B01J31/24 , B01J2231/10 , B01J2531/80 , B01J2531/824 , C08G67/02
摘要： Catalyst systems suitable for preparing polyketones consist of: (a) a compound of a metal of the 8th sub-group of the periodic system; (b) a protonic acid and a Lewis acid; and (c) a biphosphine having general formula (I), in which R?1 and R3¿ stand for cycloaliphatic or branched aliphatic residues and R?2 and R4¿ also stand for such residues or for non-branched aliphatic residues, whereas the C atoms in the residues R1-R4 may be substituted by heteroatoms.
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4.发明授权VERBINDUNGEN DES PHOSPHORS, ARSENS UND DES ANTIMONS BASIEREND AUF DIARYLANELLIERTEN BICYCLO[2.2.N]-GRUNDKÖRPERN UND DIESE ENTHALTENDE KATALYSATOREN 有权基于DIARYLANELLIERTEN双环[2.2.n]-GRUNDKÖRPERN和含有催化剂的磷，砷和锑的化合物
公开(公告)号：EP1257361B1
公开(公告)日：2003-11-26
申请号：EP01907517.5
申请日：2001-02-09
IPC分类号： B01J31/18 , B01J31/22 , B01J31/24 , C07C13/44 , C07C13/64 , C07C13/68 , C07C2/50 , C07B37/12 , C07C45/50 , C07C253/10 , C07C51/14
CPC分类号： C07F9/65746 , B01J31/1658 , B01J31/185 , B01J31/1865 , B01J31/1875 , B01J31/2457 , B01J2231/12 , B01J2231/20 , B01J2231/321 , B01J2231/323 , B01J2231/543 , B01J2231/645 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/828 , B01J2531/845 , B01J2531/847 , C07C45/50 , C07C253/10 , C07F9/46 , C07F9/5027 , C07F9/6561 , C07F9/65719 , C07C47/02 , C07C255/04
摘要： The present invention relates to phosphor, arsenic and antimony compounds based upon diaryl-anellated bicyclo`2.2.n! parent substances. The invention also relates to a method for producing the same and a catalyst which comprises at least one complex of a metal pertaining to the VIII. subgroup, whereby said complex has such a compound as the ligand. The invention further relates to the use of said catalysts for hydroformylation, hydrocyanation, carbonylation, hydrogenation, olefin oligomerisation, olefin polymerisation and metathesis.
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公开(公告)号：EP0827520A1
公开(公告)日：1998-03-11
申请号：EP96919739.0
申请日：1996-05-09
发明人： LIPPERT, Ferdinand , HÖHN, Arthur , HOFMANN, Peter
CPC分类号： C08G67/02
摘要： Metal complexes having general formula (I) are useful to copolymerise carbon monoxide with olefinically unsaturated compounds. In said formula, the substituents and indexes have the following meanings: M is a metal of group VIIB of the periodic table of elements; E1, E2 stand for an element of group VA of the periodic table of elements; Z stands for a structural unit with a bridging atom selected among the elements of groups IVA, VA or VIA of the periodic table of elements; R1 to R4 stand for substituents selected in the group that consists of C¿1?-C20 organic carbon residues and C3-C30 organic silicium residues and at least one of these four residues is a non-aromatic residue; L?1, L2¿ stand for formally charged or neutral ligands; X stand for monovalent or polyvalent anions; p equals 0, 1 or 2; m, n equal 0, 1 or 2, whereas p = m x n.
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公开(公告)号：EP0827519A1
公开(公告)日：1998-03-11
申请号：EP96914190.0
申请日：1996-05-09
发明人： LIPPERT, Ferdinand , HÖHN, Arthur , HOFMANN, Peter
IPC分类号： C08G67
CPC分类号： C08G67/02
摘要： The invention concerns copolymers of carbon monoxide with olefinically unsaturated compounds, obtainable by polymerisation of the monomers in the presence of a metal complex of general formula (I) in which the substituents and indices have the following meanings: M is a group VIIIB metal; E1, E2 are a group VA element; Z is a structural unit with a bridging atom selected from among the group IVA, VA or VIA elements; R1-R4 are substituents selected from the group comprising C¿1?-C20 carbon-organic and C3-C30 silicon-organic rests, at least one of the four rests beins a non-aromatic rest; L?1, L2¿ are formally charged or neutral ligands; X stands for formally mono- or polyvalent anions; p is 0, 1 or 2, m and n are 0, 1 or 2, and p = m x n.
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公开(公告)号：EP0710260A1
公开(公告)日：1996-05-08
申请号：EP94921651.0
申请日：1994-07-16
发明人： LIPPERT, Ferdinand , HÖHN, Arthur , HOFMANN, Peter
CPC分类号： B01J31/2409 , B01J31/24 , B01J2231/10 , B01J2531/80 , B01J2531/824 , C08G67/02
摘要： Catalyst systems suitable for preparing polyketones consist of: (a) a compound of a metal of the 8th sub-group of the periodic system; (b) a protonic acid and a Lewis acid; and (c) a biphosphine having general formula (I), in which R and R stand for cycloaliphatic or branched aliphatic residues and R and R also stand for such residues or for non-branched aliphatic residues, whereas the C atoms in the residues R -R may be substituted by heteroatoms.
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8.发明授权LIGANDEN FÜR PNICOGENCHELATKOMPLEXE MIT EINEM METALL DER VIII. NEBENGRUPPE UND VERWENDUNG DER KOMPLEXE ALS KATALYSATOREN FÜR HYDROFORMYLIERUNG, CARBONYLIERUNG, HYDROCYANIERUNG ODER HYDRIERUNG 有权FOR pnicogen螯合配体与八边GROUP而复杂的催化剂的氢甲酰化反应，羰基化，氰化或在氢化使用的金属
公开(公告)号：EP1383777B1
公开(公告)日：2005-11-16
申请号：EP02761895.8
申请日：2002-03-28
CPC分类号： C07F15/065 , B01J31/186 , B01J31/187 , B01J31/28 , B01J2231/321 , B01J2231/323 , B01J2231/645 , B01J2531/80 , B01J2531/821 , B01J2531/822 , B01J2531/827 , B01J2531/845 , C07C29/141 , C07C29/16 , C07C45/50 , C07C45/505 , C07F9/5721 , C07F9/5728 , C07F9/65522 , C07F9/65586 , C07F9/65842 , C07F9/65848 , C07F9/6596 , C07F15/004 , C07F15/0053 , C07F15/0066 , C07C31/125 , C07C47/02
摘要： Pnicogen chelate compounds which have two pnicogen-containing groups joined to one another via a xanthene-like or triptycene-like molecular skeleton and in which at least one pyrrole group is covalently bound via its nitrogen atom to each pnicogen atom form complexes with metals of transition group VIII which are useful as catalysts for the hydroformylation of olefins.
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公开(公告)号：EP1296993B1
公开(公告)日：2005-01-26
申请号：EP01949463.2
申请日：2001-07-04
CPC分类号： C08F110/02 , C07F15/006 , C07F15/04 , C08F10/00 , C08F4/80 , C08F2500/03 , C08F4/7016
摘要： The invention relates to metallic compounds of general formula (I), where M is either Ni or Pd in the +II oxidation state; a method for the polymerisation or co-polymerisation of olefins with said ionic metallic compounds; supported catalysts for the polymerisation and co-polymerisation of olefins, containing one or more of the ionic metallic compounds; method for production of said ionic metallic compounds and said supported catalysts and method for the polymerisation or co-polymerisation of olefins using said supported catalysts.
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10.发明授权VERFAHREN ZUR HYDROFORMYLIERUNG, VERBRÜCKTE VERBINDUNGEN DES PHOSPHORS, ARSENS UND DES ANTIMONS UND KATALYSATOR, UMFASSEND EINEN KOMPLEX DIESER VERBRÜCKTEN VERBINDUNGEN 有权加氢甲酰化方法，其包括这样的配合物的磷，砷和锑和催化剂的桥路连接桥接化合物的
公开(公告)号：EP1280811B1
公开(公告)日：2004-10-13
申请号：EP01931693.4
申请日：2001-05-11
发明人： AHLERS, Wolfgang , PACIELLO, Rocco , RÖPER, Michael , HOFMANN, Peter , TENSFELDT, Markus , GOETHLICH, Alexander
IPC分类号： C07F9/00
CPC分类号： B01J31/1845 , B01J31/1865 , B01J31/24 , B01J31/2414 , B01J31/2457 , B01J2531/821 , B01J2531/822 , B01J2531/845 , C07C17/263 , C07C17/2632 , C07C17/35 , C07C45/30 , C07C45/50 , C07C45/676 , C07C49/697 , C07F15/004 , C07F15/0053 , C07F15/0066 , C07F15/008 , C07F15/0093 , C07F15/065 , C07C25/18 , C07C25/22 , C07C47/02
摘要： The invention relates to a method for the hydroformylation of ethylenically unsaturated compounds. According to said method, at least one complex of a metal of subgroup VIII with at least one ligand containing two triaryl groups, each triaryl group having a radical containing phosphor, arsenic or antimony and one aryl radical of the two triaryl groups being bonded to a non-aromatic 3- to 8-membered carbocyclic or heterocyclic bridging group with a single bond, respectively; is used as the hydroformylation catalyst
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