-
1.发明授权VERFAHREN ZUR HERSTELLUNG VON 3-PENTENSÄUREESTERN DURCH CARBONYLIERUNG VON ALKOXYBUTENEN 失效受理并alkoxybutenes的羰基化制备3-戊
公开(公告)号：EP0815070B1
公开(公告)日：2000-06-14
申请号：EP96908048.0
申请日：1996-03-15
CPC分类号： C07C67/37 , C07C69/533
摘要： The invention concerns the production of 3-pentenic acid esters by carbonylation of alkoxybutenes in the presence of a catalyst and a solvent at high temperature and pressure: at least one C1-C10 alkoxybutene, in which the alkoxy group is in the allyl position relative to the double bond, is converted with carbon monoxide at a temperature in the 60-140 °C range and a carbon monoxide partial pressure in the 3-30 MPa range, in the presence of a palladium-based catalyst.
-
公开(公告)号：EP0827516A1
公开(公告)日：1998-03-11
申请号：EP96919746.0
申请日：1996-05-09
摘要： Polymers are obtained by polymerising olefinically unsaturated monomers in the presence of a catalyst system that contains as active elements (a) a salt of a metal of group VIIIB of the periodic system; (b) one or several compounds selected in the group of protonic acids and Lewis acids; (c) a chelated compound having the general formula (I) R?1R2E1-Z-E2R3R4¿, in which the substituents and indexes have the following meanings: E1, E2 stand for an element of group VA of the periodic system; Z stands for a bridging structural unit made of one, two or three substructural units of elements of groups IVA, VA, VIA of the periodic system; R1 to R4 stand for substituents selected in the group of C¿1?-C20 organic carbon and C3-C30 organic silicium residues that may contain one or several elements of groups IVA, VA, VIA and VIIA of the periodic system.
-
公开(公告)号：EP0810988A1
公开(公告)日：1997-12-10
申请号：EP96904071.0
申请日：1996-02-13
摘要： A methyl formiate continuous production process is disclosed. Carbon monoxide and methanol are reacted under an increased pressure and at a high temperature in the presence of an alkaline metal methylate. The reaction is carried out under a pressure from 210 to 250 bar in the presence of 0.05 to 0.2 % by weight of an alkaline metal methylate in relation to the methanol used.
-
公开(公告)号：EP0827515A1
公开(公告)日：1998-03-11
申请号：EP96914188.0
申请日：1996-05-09
摘要： Polymers are obtained by polymerising olefinically unsaturated monomers in the presence of a metal complex having the general formula (I), in which the substituents and indexes have the following meanings: M is a metal of group VIIIB of the periodic table of elements; E1, E2 stand for an element of group VA of the periodic table of elements; Z is a bridging structural unit made of one, two or three substructural units of elements of groups IVA, VA, VIA of the periodic table of elements; R1 to R4 stand for substituents selected in the group that consists of C¿1?-C20 organic carbon residues and C3-C30 organic silicium residues which may contain one or several elements of groups IVA, VA, VIA and VIIA of the periodic table of elements; L?1, L2¿ stand for formally charged or neutral ligands; X stands for monovalent or polyvalent anions; p equals 0, 1 or 2; m, n equal 0, 1 or 2, whereas p = m x n.
摘要翻译： 聚合物通过在具有通式（I）的金属配合物存在下聚合烯属不饱和单体而获得，其中取代基和指数具有以下含义：M是元素周期表中VIIIB族的金属; E1，E2代表元素周期表中的VA族元素; Z是由元素周期表第IVA，VA，VIA族元素的一个，两个或三个子结构单元构成的桥联结构单元; R1至R4表示选自由C1-C20有机碳残基和C3-C30有机硅残基组成的组中的取代基，所述有机硅残基可含有一种或多种元素周期表中的IVA，VA，VIA和VIIA族 要素; L 1，L 2'代表正式带电荷或中性配体; X代表单价或多价阴离子; p等于0,1或2; m，n等于0,1或2，而p = m×n。
-
公开(公告)号：EP0710260B1
公开(公告)日：1997-03-05
申请号：EP94921651.9
申请日：1994-07-16
发明人： LIPPERT, Ferdinand , HÖHN, Arthur , HOFMANN, Peter
IPC分类号： C08G67/02
CPC分类号： B01J31/2409 , B01J31/24 , B01J2231/10 , B01J2531/80 , B01J2531/824 , C08G67/02
摘要： Catalyst systems suitable for preparing polyketones consist of: (a) a compound of a metal of the 8th sub-group of the periodic system; (b) a protonic acid and a Lewis acid; and (c) a biphosphine having general formula (I), in which R?1 and R3¿ stand for cycloaliphatic or branched aliphatic residues and R?2 and R4¿ also stand for such residues or for non-branched aliphatic residues, whereas the C atoms in the residues R1-R4 may be substituted by heteroatoms.
-
6.发明授权
公开(公告)号：EP0827516B1
公开(公告)日：2001-04-11
申请号：EP96919746.6
申请日：1996-05-09
-
7.发明授权
公开(公告)号：EP0827515B1
公开(公告)日：2000-08-30
申请号：EP96914188.6
申请日：1996-05-09
摘要： Polymers are obtained by polymerising olefinically unsaturated monomers in the presence of a metal complex having the general formula (I), in which the substituents and indexes have the following meanings: M is a metal of group VIIIB of the periodic table of elements; E1, E2 stand for an element of group VA of the periodic table of elements; Z is a bridging structural unit made of one, two or three substructural units of elements of groups IVA, VA, VIA of the periodic table of elements; R1 to R4 stand for substituents selected in the group that consists of C¿1?-C20 organic carbon residues and C3-C30 organic silicium residues which may contain one or several elements of groups IVA, VA, VIA and VIIA of the periodic table of elements; L?1, L2¿ stand for formally charged or neutral ligands; X stands for monovalent or polyvalent anions; p equals 0, 1 or 2; m, n equal 0, 1 or 2, whereas p = m x n.
-
8.发明公开GEMISCHE AUS ALKYLIERTEN METHYLOLIERTEN 4,5-DIHYDROXY-IMIDAZOLIDIN-2-ONEN 失效烷基化的混合物羟甲基-4,5-二羟基咪唑烷-2-酮
公开(公告)号：EP0948488A1
公开(公告)日：1999-10-13
申请号：EP97954477.0
申请日：1997-12-30
发明人： HOIS, Pia , LIPPERT, Ferdinand , REICHERT, Jürgen
CPC分类号： D06M13/432 , C07D233/40 , D06M2101/06
摘要： A process is disclosed for preparing mixtures of mixed-alkylated methylolated 4,5-dihydroxy-imidazolidin-2-ones by reacting methylolated 4,5-dihydroxy-imidazolidin-2-one (DMDHEU) with a monovalent C1-5-alcohol and a polyol selected in the group which comprises ethylene glycol, diethylene glycol, 1,2- and 1,3-propylene glycol, 1,2-, 1,3- and 1,4-butylene glycol, glycerin and polyethylene glycols of formula HO(CH2CH2O)nH, in which 3≤n≤20. The monovalent C1-5-alcohol and the polyol are used in an amount of 0.1 to 2.0 molar equivalents each, with respect to DMDHEU, and the reaction is carried out at temperatures from 20 °C to 70 °C at a pH value from 1 to 2.5, the pH value being set at 4 to 8 after the reaction.
-
公开(公告)号：EP0810988B1
公开(公告)日：1999-10-13
申请号：EP96904071.6
申请日：1996-02-13
摘要： A methyl formiate continuous production process is disclosed. Carbon monoxide and methanol are reacted under an increased pressure and at a high temperature in the presence of an alkaline metal methylate. The reaction is carried out under a pressure from 210 to 250 bar in the presence of 0.05 to 0.2 % by weight of an alkaline metal methylate in relation to the methanol used.
-
10.发明公开
公开(公告)号：EP0970034A1
公开(公告)日：2000-01-12
申请号：EP98906940.6
申请日：1998-02-09
CPC分类号： B01J31/0239 , B01J31/0234 , B01J31/0244 , B01J31/0267 , B01J31/20 , B01J31/2234 , B01J2231/321 , B01J2531/821 , B01J2531/847 , C07C51/14 , C07C67/38 , C07C53/122 , C07C69/24
摘要： The invention relates to a method for producing carboxylic acids or their esters from olefins and carbon monoxide in the presence of water or alcohols at temperatures of between 100 and 270 °C and pressure of between 30 and 100 bar. Said method is characterized in that as halogen-free catalyst system it uses a mixture of a) nickel or a nickel compound; b) at least one of the metals of a group including chromium, molybdenum, wolfram, rhenium, ruthenium, osmium, rhodium, iridium, palladium, platinum, silver and gold, or a compound of these metals; c) at least one non-metallic compound from the group of tertiary or quaternary nitrogen, phosphorus or arsenic compounds and nitrogen-containing heterocyclic compounds.
-
-
-
-
-
-
-
-
-
搜索结果
15 条记录 (耗时 0.011 秒)
