公开(公告)号：EP1817108A2

公开(公告)日：2007-08-15

申请号：EP05798767.9

申请日：2005-10-12

申请人： BASF AKTIENGESELLSCHAFT

发明人： DECKERT, Petra ,  BASSLER, Peter ,  BARTSCH, Michael ,  HADERLEIN, Gerd ,  LUYKEN, Hermann ,  SCHEIDEL, Jens ,  PFAB, Peter ,  AECHTNER, Tobias ,  SIEGEL, Wolfgang

IPC分类号： B01J38/56

CPC分类号： B01J31/4053 ,  B01D11/0434 ,  B01J31/1845 ,  B01J31/185 ,  B01J31/24 ,  B01J31/403 ,  B01J2231/323 ,  B01J2531/847 ,  C07C253/10 ,  C07C253/32 ,  Y02P20/584 ,  C07C255/04

摘要： The invention relates to a method for the extractive separation of homogeneously dissolved catalysts from a reaction product from a hydrocyanation of unsaturated mononitriles to dinitriles, by extraction with a carbon material (K), characterised in that a) a non-polar aprotic liquid (F) is added to the reaction product to give a stream (I) and b) the stream (I) is extracted with a carbon material (K) at a temperature (T), to give a stream (II), containing the carbon material (K), enriched with the catalyst and a stream (III), stripped of catalyst.

公开(公告)号：EP1868975A2

公开(公告)日：2007-12-26

申请号：EP06725582.8

申请日：2006-04-05

申请人： BASF AKTIENGESELLSCHAFT

发明人： BARTSCH, Michael ,  HADERLEIN, Gerd ,  AECHTNER, Tobias ,  SCHEIDEL, Jens ,  DIENES, Christian ,  TEMPEL, Alexandre ,  HOFRICHTER, Thorsten ,  WEINLE, Werner

IPC分类号： C07C37/11

CPC分类号： C07C37/11 ,  C07C39/15

摘要： The invention relates to a method for producing biphenols of general formula (I) by reacting monophenols of general formula (II), wherein the radicals R1, R2 and R3 independently represent hydrogen, alkyl, aryl or arylalkyl, with 1 - 10 C-atoms, in the presence of an oxidation agent in a reactor. Said method is characterised in that a) the reactor does not contain any stationary integrated components which act as a current agitator, b) a maximum of 0,6 mol of oxidation agents are used per mol of monophenol, and c) the oxidation agent is added in a continuous or discontinuous manner in a plurality of portions within a time span of between 10 min - 24 hours, whereby the amount of oxidation agent which is added per time unit is not constant over the entire tine span, but is varied.

公开(公告)号：EP1713816B1

公开(公告)日：2007-08-01

申请号：EP05701205.6

申请日：2005-01-27

申请人： BASF Aktiengesellschaft

发明人： SCHEIDEL, Jens ,  JUNGKAMP, Tim ,  BARTSCH, Michael ,  HADERLEIN, Gerd ,  BAUMANN, Robert ,  LUYKEN, Hermann ,  DECKERT, Petra ,  PFAB, Peter ,  SIEGEL, Wolfgang ,  AECHTNER, Tobias

IPC分类号： C07F9/00

CPC分类号： C07C253/34 ,  C07C255/04

摘要： The invention relates to a method for the extractive separation of nickel(0) complexes and phosphorus-containing ligands and/or free phosphorus-containing ligands from a reaction discharge of a hydrocyanation of unsaturated mononitries to dinitriles, by means of a hydrocarbon, the hydrocarbon and the reaction discharge being separated into two phases at a temperature T (in °C). The invention is characterised in that the content of nickel(0) complexes and phosphorus-containing ligands and/or free phosphorus-containing ligands in the reaction discharge of the hydrocyanation is at least y wt. %, depending on the temperature T, and a maximum of 60 wt. % independently of the temperature T. The numerical value of the minimum content y is indicated by the equation y = 0,5 T + 20, T being a dimensionless numerical value.

公开(公告)号：EP1799697A1

公开(公告)日：2007-06-27

申请号：EP05796041.1

申请日：2005-09-30

申请人： BASF Aktiengesellschaft

发明人： BARTSCH, Michael ,  BAUMANN, Robert ,  HADERLEIN, Gerd ,  AECHTNER, Tobias ,  SCHEIDEL, Jens ,  LUYKEN, Hermann ,  PFAB, Peter ,  SIEGEL, Wolfgang ,  WEISKOPF, Verena

IPC分类号： C07F9/6574 ,  B01D11/00

CPC分类号： B01D11/0492 ,  C07F9/025 ,  C07F9/145

摘要： The invention relates to a method for purifying chelate ligands containing phosphorus by extraction by means of polar extraction agents.

公开(公告)号：EP1716105A1

公开(公告)日：2006-11-02

申请号：EP05707029.4

申请日：2005-01-27

申请人： BASF Aktiengesellschaft

发明人： JUNGKAMP, Tim ,  BAUMANN, Robert ,  BARTSCH, Michael ,  HADERLEIN, Gerd ,  LUYKEN, Hermann ,  SCHEIDEL, Jens ,  AECHTNER, Tobias ,  PFAB, Peter ,  DECKERT, Petra ,  BASSLER, Peter ,  SIEGEL, Wolfgang

IPC分类号： C07C253/10 ,  C07C255/07

CPC分类号： C07C253/30 ,  C07C253/10 ,  Y02P20/582 ,  C07C255/07

摘要： The invention relates to a method for producing 3-pentenenitrile, characterised by the following steps: (a) isomerisation of an educt stream containing 2-methyl-3-butenenitrile on at least one dissolved or dispersed isomerisation catalyst to form a stream (1), which contains the isomerisation catalyst(s), 2-methyl-3-butenenitrile, 3-pentenenitrile and (Z)-2-methyl-2-butenenitrile; (b) distillation of the stream (1) to obtain a stream (2) as the overhead product, which contains 2-methyl-3-butenenitrile, 3-pentenenitrile and (Z)-2-methyl-2-butenenitrile and a stream (3) as the bottom product, which contains the isomerisation catalyst(s); (c) distillation of the stream (2) to obtain a stream (4) as the overhead product, which is enriched with (Z)-2-methyl-2-butenenitrile in comparison to stream (2), (in relation to the sum of all pentenenitriles in stream (2)) and a stream (5) as the bottom product, which is enriched with 3-pentenenitrile and 2-methyl-3-butenenitrile in comparison to stream (2), (in relation to the sum of all pentenenitriles in stream (2); (d) distillation of stream (5) to obtain a stream (6) as the bottom product, which contains 3-pentenenitrile and a stream (7) as the head product, which contains 2-methyl-3-butenenitrile.

公开(公告)号：EP1713816A1

公开(公告)日：2006-10-25

申请号：EP05701205.6

申请日：2005-01-27

申请人： BASF Aktiengesellschaft

发明人： SCHEIDEL, Jens ,  JUNGKAMP, Tim ,  BARTSCH, Michael ,  HADERLEIN, Gerd ,  BAUMANN, Robert ,  LUYKEN, Hermann ,  DECKERT, Petra ,  PFAB, Peter ,  SIEGEL, Wolfgang ,  AECHTNER, Tobias

IPC分类号： C07F9/00

CPC分类号： C07C253/34 ,  C07C255/04

摘要： The invention relates to a method for the extractive separation of nickel(0) complexes and phosphorus-containing ligands and/or free phosphorus-containing ligands from a reaction discharge of a hydrocyanation of unsaturated mononitries to dinitriles, by means of a hydrocarbon, the hydrocarbon and the reaction discharge being separated into two phases at a temperature T (in °C). The invention is characterised in that the content of nickel(0) complexes and phosphorus-containing ligands and/or free phosphorus-containing ligands in the reaction discharge of the hydrocyanation is at least y wt. %, depending on the temperature T, and a maximum of 60 wt. % independently of the temperature T. The numerical value of the minimum content y is indicated by the equation y = 0,5 T + 20, T being a dimensionless numerical value.