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公开(公告)号：EP1501879A1
公开(公告)日：2005-02-02
申请号：EP03720470.8
申请日：2003-04-15
CPC分类号： C08F297/04 , C07F5/062 , C08F4/54 , C08F36/04 , C08L53/02 , C08F4/52 , C08F4/48 , C08L2666/02
摘要： The invention relates to an initiator composition and method for anionic polymerisation, comprising at least one alkali metal hydride, selected from LiH, NaH and KH and at least one organoaluminium compound. The invention further relates to a method for anionic polymerisation of styrol or dienyl monomers using said initiator composition.
摘要翻译： 本发明涉及用于阴离子聚合的引发剂组合物和方法，其包含至少一种选自LiH，NaH和KH的碱金属氢化物和至少一种有机铝化合物。 本发明进一步涉及使用所述引发剂组合物使苯乙烯或二烯基单体阴离子聚合的方法。
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公开(公告)号：EP1054912B1
公开(公告)日：2003-12-17
申请号：EP99910197.5
申请日：1999-02-05
发明人： SCHADE, Christian , FISCHER, Wolfgang , GAUSEPOHL, Hermann , KLOSTERMANN, Rainer , WARZELHAN, Volker , FONTANILLE, Michel , DEFFIEUX, Alain , DESBOIS, Philippe
IPC分类号： C08F12/04
CPC分类号： C08F12/04 , C08F236/10 , C08F4/52
摘要： The invention relates to a method for homopolymerization of vinyl-aromatic monomers or copolymerization of vinyl-aromatic monomers or dienes in the presence of at least one alkali metal organyl, at least one magnesium organyl and at least one aluminum organyl. The invention also relates to an initiator composition for implementing the inventive method.
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3.发明授权
公开(公告)号：EP1054908B1
公开(公告)日：2003-04-23
申请号：EP99910198.3
申请日：1999-02-05
发明人： SCHADE, Christian , FISCHER, Wolfgang , GAUSEPOHL, Hermann , JÜNGLING, Stephan , WARZELHAN, Volker , FONTANILLE, Michel , DEFFIEUX, Alain , DESBOIS, Philippe
CPC分类号： C08F4/46
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公开(公告)号：EP0918805B2
公开(公告)日：2007-08-22
申请号：EP97941943.9
申请日：1997-08-18
发明人： FISCHER, Wolfgang , GAUSEPOHL, Hermann , KNOLL, Konrad , LÄTSCH, Stefan , LOTH, Wolfgang , SCHADE, Christian , WARZELHAN, Volker , FONTANILLE, Michel , DEFFIEUX, Alain , DESBOIS, Philippe
CPC分类号： C08F297/04 , C08F4/44 , C08F4/50 , C08F12/04 , C08F12/08 , C08F36/04 , C08F279/02 , C08F4/46 , C08F4/54 , C08F4/52 , C08F4/48 , C08F212/08
摘要： A continuous anionic polymerisation or copolymerisation process of styrene or diene monomers with alkali metal alkyl as polymerisation initiator is carried out in the presence of a metal alkyl or aryl of an at least bivalent element as reaction speed regulator, preferably in non-isotherm conditions and without a back admixture in a pipe or pipe bundle reactor. A metal alkyl or aryl A of formula R1M1 and a metal alkyl or aryl B of formula R2nM2 in a molar ratio between B and A from 0.1:1 to 500:1 are used. In the formulas, M1 is Li, Na or K; R1 is hydrogen, C¿1?-C20-alkyl or C6-C20-aryl or C7-C20-alkyl-substituted aryl; M?2¿ is an n-valent element of groups 2a, 2b or 3a of the periodic table of elements; and R2 is hydrogen, halogen, C¿1?-C20-alkyl or C6-C20-alkyl. Also disclosed is a special initiator for the anionic polymerisation which does not contain any Lewis bases.
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公开(公告)号：EP1629026A1
公开(公告)日：2006-03-01
申请号：EP04731892.8
申请日：2004-05-10
IPC分类号： C08G65/12
CPC分类号： C08G65/12
摘要： The invention relates to a method for producing homopolymers from oxiranes or copolymers from oxiranes and comonomers, by anionic polymerisation in the presence of an alkali metal compound and an aluminium organyl. The method is characterised in that no crown ether or cryptand is used during the polymerisation process.
摘要翻译： 本发明涉及由环氧乙烷或环氧乙烷与共聚单体的共聚物通过在碱金属化合物和铝有机物存在下的阴离子聚合生产均聚物的方法。 该方法的特征在于在聚合过程中不使用冠醚或穴状配体。
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公开(公告)号：EP1597291A1
公开(公告)日：2005-11-23
申请号：EP04705764.1
申请日：2004-01-28
发明人： DESBOIS, Philippe , ISHAQUE, Michael , SCHADE, Christian , DEFFIEUX, Alain , CARLOTTI, Stéphane
IPC分类号： C08F12/08
CPC分类号： C08F4/56 , C08F4/463 , C08F4/52 , C08F112/12 , C08F212/08 , C08F297/04 , C08L9/06 , C08L25/10 , C08L53/02 , C08L2666/24
摘要： The invention relates to a method for the production of homopolymers made of α-methylstyrene, or copolymers made of α-methylstyrene and comonomers, by anionic polymerisation in the presence of an initiator composition. The invention is characterised in that the initiator composition contains potassium hydride and at least one aluminium organyl.
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公开(公告)号：EP1056790A1
公开(公告)日：2000-12-06
申请号：EP99908853.7
申请日：1999-02-05
发明人： SCHADE, Christian , FISCHER, Wolfgang , GAUSEPOHL, Hermann , KNOLL, Konrad , WARZELHAN, Volker , FONTANILLE, Michel , DEFFIEUX, Alain , DESBOIS, Philippe
摘要： The invention relates to a method for homopolymerization of vinyl-aromatic monomers or copolymerization of vinyl-aromatic monomers and dienes in the presence of at least one alkali metal compound and at least one compound of an element from Group 3a of the periodic table, wherein the compounds contain, in relation to the sum of molar equivalence of the alkali metal and the elements from Group 3a: a) 0.1 to 3.9 molar equivalents of oxygen, sulfur, nitrogen or phosphorus and b) 0.1 to 3.9 molar equivalents of an organyl ligand.
摘要翻译： 本发明涉及在至少一种碱金属化合物和至少一种周期表第3a族元素的化合物存在下乙烯基芳族单体的均聚或乙烯基芳族单体和二烯的共聚的方法， 相对于碱金属和来自第3a族的元素的摩尔当量之和，化合物含有：a）0.1至3.9摩尔当量的氧，硫，氮或磷，和b）0.1至3.9摩尔当量的有机配体。
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公开(公告)号：EP1682603B1
公开(公告)日：2007-02-21
申请号：EP04791091.4
申请日：2004-10-30
IPC分类号： C08G65/00
CPC分类号： C08G65/2642 , C08G65/10 , C08G65/105 , C08G65/12
摘要： The invention relates to a method for producing homopolymers from oxirans, or copolymers from oxirans and comonomers by anionic polymerisation. Said method is characterised in that the polymerisation takes place in the presence of a quaternary ammonium and/or phosphonium compound and a mononuclear aluminium organyl.
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公开(公告)号：EP1597291B1
公开(公告)日：2006-10-04
申请号：EP04705764.1
申请日：2004-01-28
发明人： DESBOIS, Philippe , ISHAQUE, Michael , SCHADE, Christian , DEFFIEUX, Alain , CARLOTTI, Stéphane
IPC分类号： C08F12/08
CPC分类号： C08F4/56 , C08F4/463 , C08F4/52 , C08F112/12 , C08F212/08 , C08F297/04 , C08L9/06 , C08L25/10 , C08L53/02 , C08L2666/24
摘要： The invention relates to a method for the production of homopolymers made of α-methylstyrene, or copolymers made of α-methylstyrene and comonomers, by anionic polymerisation in the presence of an initiator composition. The invention is characterised in that the initiator composition contains potassium hydride and at least one aluminium organyl.
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公开(公告)号：EP1629026B1
公开(公告)日：2006-09-06
申请号：EP04731892.8
申请日：2004-05-10
IPC分类号： C08G65/12
CPC分类号： C08G65/12
摘要： The invention relates to a method for producing homopolymers from oxiranes or copolymers from oxiranes and comonomers, by anionic polymerisation in the presence of an alkali metal compound and an aluminium organyl. The method is characterised in that no crown ether or cryptand is used during the polymerisation process.
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