摘要:
The invention concerns the use as biocides of polymers which contain the following incorporated by polymerization: (a) between 0.1 and 100 mol % vinyl amine units or ethylene imine units; (b) between 0 and 99.9 mol % units of at least one monomer selected from the group comprising open-chain N-vinyl carboxylic acid amides, vinyl formiate, vinyl acetate, vinyl propionate, vinyl alcohol, C1 to C6 alkyl vinyl ether, monoethylenically unsaturated C3 to C8 carboxylic acids, their esters, nitriles, amides and anhydrides, N-vinyl urea, N-vinyl imidazoles and N-vinyl imidazolines; and (c) between 0 and 5 mol % units of monomers having at least two ethylenically unsaturated double bonds. The total of (a), (b) and (c) in mol % is always 100.
摘要:
The disclosure concerns a method of producing water-soluble condensates and addition products containing amino groups and possessing enhanced de-watering and retention properties in paper production. Between 5 and 95 wt % of the condensates or addition products are removed as a permeate from solutions of water-soluble condensates or addition products containing amino groups by ultrafiltration through membranes and the condensates or addition products containing amino groups are if necessary isolated more efficiently from the retentate. The high-molecular polymer components contained in the residue are used as retention, de-watering and fixing agents in paper production, as promotors in gluing paper with alkyl diketenes, as flocculents for sewage sludges, as adhesives in the production of composite films, as additives to hair and skin conditioners and as an agent for immobilising anionic active substances.
摘要:
The invention concerns a shell-type catalyst comprising a metallic carrier material and a catalytically active layer which adheres firmly thereto, which contains elements of the alkali, alkaline earth and/or lanthanide group of the periodic system of elements and which can be obtained by physical or chemical vapour deposition on the carrier material. The invention further concerns the use of shell-type catalysts and a process for preparing aziridines by the catalytic intramolecular splitting off of water in the gaseous phase from compounds of formula (I), in which R?1, R2, R3, R4 and R5¿, independently of one another, signify H or C¿1? - C4 alkyl and R?5¿ additionally stands for cyclohexyl, phenyl, benzyl, C¿1? - C8 hydroxyalkyl or C1 - C8 aminoalkyl.
摘要:
A process is disclosed for producing finely divided, water-insoluble aziridine polymers by polymerisation of aziridines, preferably ethylene imine, in the presence of cross-linking agents which contain at least two functional groups in at least one ether. Also disclosed are modified, water-insoluble aziridine polymers obtained by reacting finely divided, water-insoluble, cross-linked aziridine polymers in an aqueous medium with carbon bisulphide or formaldehyde and a nucleophilic agent from the group of the alkaline metal cyanides, primary amines, secondary amines, alkaline metal sulphites and alkaline metal phosphites. The invention also relates to the use of the modified and non-modified, finely divided, water-insoluble polymers for immobilising active substances, as absorbing agent for aldehydes, ketones and acids and for removing heavy metal ions from waste water.
摘要:
A process is disclosed for producing finely divided, water-insoluble aziridine polymers by polymerisation of aziridines, preferably ethylene imine, in the presence of cross-linking agents which contain at least two functional groups in at least one ether. Also disclosed are modified, water-insoluble aziridine polymers obtained by reacting finely divided, water-insoluble, cross-linked aziridine polymers in an aqueous medium with carbon bisulphide or formaldehyde and a nucleophilic agent from the group of the alkaline metal cyanides, primary amines, secondary amines, alkaline metal sulphites and alkaline metal phosphites. The invention also relates to the use of the modified and non-modified, finely divided, water-insoluble polymers for immobilising active substances, as absorbing agent for aldehydes, ketones and acids and for removing heavy metal ions from waste water.
摘要:
The invention concerns the use as biocides of polymers which contain the following incorporated by polymerization: (a) between 0.1 and 100 mol % vinyl amine units or ethylene imine units; (b) between 0 and 99.9 mol % units of at least one monomer selected from the group comprising open-chain N-vinyl carboxylic acid amides, vinyl formiate, vinyl acetate, vinyl propionate, vinyl alcohol, C1 to C6 alkyl vinyl ether, monoethylenically unsaturated C3 to C8 carboxylic acids, their esters, nitriles, amides and anhydrides, N-vinyl urea, N-vinyl imidazoles and N-vinyl imidazolines; and (c) between 0 and 5 mol % units of monomers having at least two ethylenically unsaturated double bonds. The total of (a), (b) and (c) in mol % is always 100.
摘要:
The invention relates to a method for producing paper, paperboard and cardboard by dehydrating paper material containing interfering substances in the presence of fixing agents. Reaction products are used as fixing agents. Said products are obtained by reacting polymers, containing amino and/or ammonium groups, from the group of: polymers containing vinyl amino units, polyalkylene polyamines, polyamidoamines, polyamidoamines grafted with ethylene imine and optionally cross-linked, polydiallydldimethylammoniumchlorides; polymers containing dialkylaminoalkylacrylamide-units or dialkylaminoalkylmethacrylamide units and polyallylamines and dicyandiamide-formaldehyde-condensates, with reactive sizing agents for paper with a polymer/reactive sizing agent weight ratio of 15,000 : 1 to 1 : 1. The invention also relates to reaction products thus obtained and to their use as fixing agents for water soluble and water insoluble interfering substances in the production of paper, paperboard and cardboard from paper materials containing interfering substances.