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1.发明公开
公开(公告)号：EP1713777A1
公开(公告)日：2006-10-25
申请号：EP05700915.1
申请日：2005-01-14
发明人： KÖNEMANN, Martin , MÜLLEN, Klaus , REUTHER, Erik
IPC分类号： C07D221/14 , C07D221/18
CPC分类号： C07D221/14 , C07D221/18 , C07D471/06
摘要： The invention relates to a method for producing terrylen-3,4:11,12-tetracarboxylic acid diimids of general formula (I), wherein R and R' are independently hydrogen, possibly substituted C1-C30-alkyl, C5-C8-cycloalkyl, aryl or hetaryl consisting in a) reacting a diboran (II) in the presence an aprotic organic solvent, a transition metal-based catalyst and a base with a1) a 9-brom-perylen-3,4-dicarboxyl acid imid (IIIa) or a2) a naphthalene-1,8-dicarboxylic-acid imid (IIIb), b1) in submitting a formed 9-(dioxaborolan-2-yl)perylene-3,4-dicarboxylic acid imid (IVa) in the presence of an organic solvent preferably mixed with water, a transition metal-based catalyst and a base to a Suzuki-coupling reaction with a naphthalene-1,8-dicarboxylic carbon imid (IIIb) or b2) a submitting a formed 4-(dioxaborolan-2-yl)naphthalene-1,8-dicarboxylic acid imid (IVb) in the presence of an organic solvent preferably mixed with water, a transition metal-based catalyst and a base to a Suzuki-coupling reaction with a 9-brom-perylen-3,4-dicarbon acid imid (IIIa) and c)in transforming a formed 9-(4-naphthalene-1,8-dicarboxylic acid imid) perylene-3,4-dicarboxylic acid imid (V) into the terrylen-3,4:11,12-tetracarbon acid di-imid base (I) by cyclodehydration in an organic reaction medium exhibiting hydroxy and amino functions and containing a substantially insoluble base.
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2.发明公开DURCH CYCLISCHE AMINOGRUPPEN SUBSTITUIERTE RYLENTETRACARBONS[UREDIIMIDE 审中-公开通过循环氨基取代RYLENTETRACARBONS [UREDIIMIDE
公开(公告)号：EP1819678A1
公开(公告)日：2007-08-22
申请号：EP05810887.9
申请日：2005-11-26
发明人： KÖNEMANN, Martin , QU, Jianqiang , MÜLLEN, Klaus
IPC分类号： C07D221/18 , C09B5/62
CPC分类号： C09B5/62
摘要： The invention relates to rylene tetracarboxylic acid diimides of general formula (I). The invention also relates to the production of said rylene tetracarboxylic acid diimides and to the use thereof for colouring organic and inorganic materials, in particular lacquers, printing inks and plastic materials, as a dispersing auxiliary agent and pigment additive for organic pigments, for producing aqueous polymer dispersions which can be absorbed in the close infrared area of the electromagnetic spectrum, in the production of markings and inscriptions which absorb infrared light and which are invisible to the human eye and as infrared absorbers for heat management.
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公开(公告)号：EP1532210A1
公开(公告)日：2005-05-25
申请号：EP03797212.2
申请日：2003-07-25
发明人： KRIEGER, Matthias , BÖHM, Arno , SIGGEL, Lorenz , BECKER, Stefan , MÜLLEN, Klaus , KOHL, Christopher
IPC分类号： C09B57/08
CPC分类号： C09B5/62
摘要： Disclosed are rylene dyes of general formula (I), in which R represents hydrogen, optionally substituted C1-C30 alkyl, C5-C8 cycloalkyl, aryl, or hetaryl, R' represents bromine, cyano, -NR32, optionally substituted aryloxy, arylthio, hetaryloxy, or hetarylthio, optionally substituted C3-C18 alk-1-inyl, X and Y both represent hydrogen or jointly represent a radical of formula (Ia), n represents 2, 3, 4, or additionally 1 if X and Y represent a radical of formula (Ia), n' represents 1 to 4, and m represents 0 to 6.
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4.发明授权VERFAHREN ZUR HERSTELLUNG FARBSTOFFENTHALTENDER, WÄSSRIGER POLYMERISATDISPERSIONEN 有权VERFAHREN ZUR HERSTELLUNG FARBSTOFFENTHALTENDER，WÄSSRIGERPOLYMERISATDISPERSIONEN
公开(公告)号：EP1054907B1
公开(公告)日：2004-04-14
申请号：EP99906122.9
申请日：1999-01-13
发明人： MATHAUER, Klemens , BÖHM, Arno , MÄCHTLE, Walter , ROSSMANITH, Peter , KIELHORN-BAYER, Sabine , MÜLLEN, Klaus , ROHR, Ulrike , RAULFS, Friedrich-Wilhelm , SCHLÖSSER, Ulrike , SCHROF, Wolfgang , HANCIOGULLARI, Harutyun , SIEMENSMEYER, Karl , DELAVIER, Paul , SENS, Rüdiger , FREUND, Torsten , IKEDA, Takahiro , WAKEBE, Takanori
IPC分类号： C08F2/44 , C08F2/22 , C09D11/00 , C07C271/12 , C07C69/54 , C07D221/18 , C07D471/06 , C09D5/02 , C09D5/03 , D21H19/00
CPC分类号： C08F2/32 , C08F2/44 , C08K3/00 , C09B69/102
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5.发明公开
公开(公告)号：EP1054913A2
公开(公告)日：2000-11-29
申请号：EP99910218.9
申请日：1999-02-11
发明人： RAETHER, Roman, Benedikt , PAULUS, Wolfgang , BRAUN, Frank , MÜLLEN, Klaus , KLAPPER, Markus , STEENBOCK, Marco
IPC分类号： C08F26/00 , C08F293/00 , A61K35/16
CPC分类号： C08F26/10 , C08F26/02 , C08F293/005
摘要： The invention relates to a method for the production of polymers from N-vinyl compounds, characterized in that vinyl compounds are polymerized in the presence of radicals of general formula (I), wherein Q stands for NR2 or S and T stands for CR3R4 or S and R?1, R2, R3 and R4¿ can be identical to or different from each other and independently stand for hydrogen, C¿1?- to C20-alkyl or C6- to C18-aryl.
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6.发明公开VERFAHREN ZUR HERSTELLUNG VON TERRYLEN-3,4:11,12-TETRACARBONSÄUREDIIMIDEN DURCH DIREKTSYNTHESE 有权用于生产涤纶-3,4：11,12-四甲通过直接合成
公开(公告)号：EP1711469A1
公开(公告)日：2006-10-18
申请号：EP05700962.3
申请日：2005-01-15
发明人： KÖNEMANN, Martin , BÖHM, Arno , HELFER, Willi , ROMEIS, Jürgen , QU, Jianqiang , MÜLLEN, Klaus
IPC分类号： C07D221/18
CPC分类号： C07D221/18 , C07D221/14 , C07D471/06
摘要： The invention relates to a method for the production of terylene-3,4:11,12-tetracarboxydiimides (I) in which the variables have the following meanings: R, R' independently = H, optionally substituted alkyl or cycloalkyl, aryl or heteroaryl, R1 = H or alkyl; R2 = H, alkyl, optionally substituted aryl or heteroaryl, whereby a perylene-3,4-dicarboxyimide (II) is reacted with a naphthalene-1,8-dicarboxyimide (III), where X = H, bromine or chlorine, in the presence of a base-stable, high boiling organic solvent and an alkali or alkaline earth metal base.
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公开(公告)号：EP1373214A1
公开(公告)日：2004-01-02
申请号：EP02716770.9
申请日：2002-02-14
发明人： KRIEGER, Matthias , BÖHM, Arno , REUTHER, Erik , MÜLLEN, Klaus
IPC分类号： C07D221/18 , C07D491/06 , C09B3/14 , C09B3/18 , C09B3/20
CPC分类号： C07D491/06 , C07D221/18 , C07D471/06 , C09B5/62
摘要： The invention relates to rylene derivatives of the general formula (I), in which: R represents hydrogen or optionally substituted C1-C30 alkyl, aryl or heteroaryl; R1 represents hydrogen or bromine; R2 represents hydrogen or C¿1?-C6 alkyl; R?3¿ represents hydrogen, C¿1?-C18 alkyl or optionally substituted aryl or heteroaryl; and n represents 2 or 3.
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8.发明授权
公开(公告)号：EP1054913B1
公开(公告)日：2003-04-23
申请号：EP99910218.9
申请日：1999-02-11
发明人： RAETHER, Roman, Benedikt , PAULUS, Wolfgang , BRAUN, Frank , MÜLLEN, Klaus , KLAPPER, Markus , STEENBOCK, Marco
IPC分类号： C08F26/00 , C08F293/00 , A61K35/16
CPC分类号： C08F26/10 , C08F26/02 , C08F293/005
摘要： The invention relates to a method for the production of polymers from N-vinyl compounds, characterized in that vinyl compounds are polymerized in the presence of radicals of general formula (I), wherein Q stands for NR or S and T stands for CR R or S and R , R , R and R can be identical to or different from each other and independently stand for hydrogen, C1- to C20-alkyl or C6- to C18-aryl.
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公开(公告)号：EP1086154A1
公开(公告)日：2001-03-28
申请号：EP99924953.5
申请日：1999-05-12
发明人： STORK, Martin , MÜLLEN, Klaus , KLAPPER, Markus , KOCH, Matthias , GREGORIUS, Heike , RIEF, Ursula , KRISTEN, Marc, Oliver
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/6592 , C08F210/00 , Y10S526/943 , C08F4/027 , C08F4/65916
摘要： The invention relates to a method for producing a carrier-borne catalyst which method comprises the following steps: (1) preparation of a copolymer with comonomer units containing leaving groups; (2) polymerisation-analogue reaction with a possibly substituted cyclopentadienyl compound; and (3) reaction of the copolymer obtained in (2) with a mono-Cp-metallocene compound.
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公开(公告)号：EP0804507B1
公开(公告)日：1999-04-28
申请号：EP96900944.8
申请日：1996-01-12
发明人： MÜLLEN, Klaus , QUANTE, Heribert , BÖHM, Arno
IPC分类号： C09B5/62 , C07D221/18
CPC分类号： C07D221/18 , C09B5/62
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