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公开(公告)号:EP1144462A1
公开(公告)日:2001-10-17
申请号:EP99965543.4
申请日:1999-12-22
发明人: BREMSER, Wolfgang , STRICKMANN, Frank , BENDIX, Maximilian , PAULUS, Wolfgang , RAETHER, Roman, Benedikt , CHRISTIE, David
IPC分类号: C08F2/38 , C09D4/00 , C08F293/00 , C09D153/00
CPC分类号: C09D151/06 , C08F291/00 , C08F293/005 , C09D133/062 , C09D153/00 , C08L2666/02 , C08L2666/24
摘要: The invention relates to a coating agent, containing at least one conversion product (A) and at least one suitable additive (C), (A) being produced according to a method comprising the following step (i): (iv) reacting a reaction mixture comprising at least one radically convertible monomer in radical conditions, (a) in the presence of at least one radical initiator and a compound (I) of formula (II) wherein R1 to R4 each represent, independently of each other, hydrogen, an unsubstituted or substituted alkyl radical, cycloalkyl radical or aralkyl radical or an unsubstituted or a substituted aromatic hydrocarbon radical, on the condition that at least two of R1 to R4 represent an unsubstituted or a substituted aromatic hydrocarbon radical, in an aqueous phase.
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公开(公告)号:EP1141033B1
公开(公告)日:2004-10-06
申请号:EP99964585.6
申请日:1999-12-16
发明人: BREMSER, Wolfgang , STRICKMANN, Frank , BENDIX, Maximilian , PAULUS, Wolfgang , RAETHER, Roman, Benedikt , CHRISTIE, David
IPC分类号: C08F2/38 , C08F220/18 , C08F220/10 , C08F293/00
CPC分类号: C08F212/32 , C08F293/00 , C08F293/005
摘要: A method for producing a reaction product (A) comprising the following step (i): (iv) a reaction mixture comprising at least one radically reactable monomer (a) is reacted in radical conditions in the presence of at least one radical initiator and a compound of formula (I), wherein R1-R4 represent independently from each other hydrogen, a respectively unsubstituted or substituted alkyl radical, a cycloalkyl radical, an aralkyl radical, an unsubstituted or substituted aromatic hydrocarbon radical, under the proviso that at least two from R1-R4 represent an unsubstituted or substituted aromatic hydrocarbon radical.
摘要翻译: 一种生产反应产物(A)的方法,包括以下步骤(i):(iv)包含至少一种可自由基反应的单体(a)的反应混合物在自由基条件下在至少一种自由基引发剂和 式(I)化合物,其中R1-R4彼此独立地表示氢,分别为未取代或取代的烷基,环烷基,芳烷基,未取代或取代的芳族烃基,条件是至少两个 R1-R4代表未取代或取代的芳族烃基。
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公开(公告)号:EP1144462B1
公开(公告)日:2004-08-11
申请号:EP99965543.4
申请日:1999-12-22
发明人: BREMSER, Wolfgang , STRICKMANN, Frank , BENDIX, Maximilian , PAULUS, Wolfgang , RAETHER, Roman, Benedikt , CHRISTIE, David
IPC分类号: C08F2/38 , C09D4/00 , C08F293/00 , C09D153/00
CPC分类号: C09D151/06 , C08F291/00 , C08F293/005 , C09D133/062 , C09D153/00 , C08L2666/02 , C08L2666/24
摘要: The invention relates to a coating agent, containing at least one conversion product (A) and at least one suitable additive (C), (A) being produced according to a method comprising the following step (i): (iv) reacting a reaction mixture comprising at least one radically convertible monomer in radical conditions, (a) in the presence of at least one radical initiator and a compound (I) of formula (II) wherein R1 to R4 each represent, independently of each other, hydrogen, an unsubstituted or substituted alkyl radical, cycloalkyl radical or aralkyl radical or an unsubstituted or a substituted aromatic hydrocarbon radical, on the condition that at least two of R1 to R4 represent an unsubstituted or a substituted aromatic hydrocarbon radical, in an aqueous phase.
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公开(公告)号:EP1141033A1
公开(公告)日:2001-10-10
申请号:EP99964585.6
申请日:1999-12-16
发明人: BREMSER, Wolfgang , STRICKMANN, Frank , BENDIX, Maximilian , PAULUS, Wolfgang , RAETHER, Roman, Benedikt , CHRISTIE, David
IPC分类号: C08F2/38 , C08F220/18 , C08F220/10 , C08F293/00
CPC分类号: C08F212/32 , C08F293/00 , C08F293/005
摘要: A method for producing a reaction product (A) comprising the following step (i): (iv) a reaction mixture comprising at least one radically reactable monomer (a) is reacted in radical conditions in the presence of at least one radical initiator and a compound of formula (I), wherein R1-R4 represent independently from each other hydrogen, a respectively unsubstituted or substituted alkyl radical, a cycloalkyl radical, an aralkyl radical, an unsubstituted or substituted aromatic hydrocarbon radical, under the proviso that at least two from R1-R4 represent an unsubstituted or substituted aromatic hydrocarbon radical.
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公开(公告)号:EP1368437B1
公开(公告)日:2006-10-25
申请号:EP02700225.2
申请日:2002-02-12
CPC分类号: C09D4/00 , C08F2438/02 , C08K5/3435 , C08F220/00 , C08F222/00 , C08F236/00 , C08F212/00
摘要: The invention relates to coating compositions that contain stable adducts that generate initiator radicals at higher temperatures. The invention further relates to a method for producing the same and to the use of said coating compositions. The stable adducts are used to initiate polymerization of ethylenically unsaturated monomers.
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公开(公告)号:EP1252203B1
公开(公告)日:2004-03-17
申请号:EP00985177.5
申请日:2000-12-15
发明人: RAETHER, Roman, Benedikt , MODERY, Bernd , BRAUN, Frank , BRINKMANN-RENGEL, Susanne , CHRISTIE, David , HAREMZA, Sylke
IPC分类号: C08F12/32
CPC分类号: C08F12/32
摘要: The invention relates to a method for producing a conversion product (A), which comprises the following steps: (i) reacting, under radical conditions, a reaction mixture containing at least one radically convertible monomer (a) in the presence of at least one radical initiator and one compound of formula (I), wherein R1 to R4, independent of one another, represent hydrogen, a non-substituted or substituted alkyl radical, cycloalkyl radical, aralkyl radical, a non-substituted or substituted aromatic hydrocarbon radical with the provision that at least two of the radicals R1 to R4 represent a non-substituted or substituted aromatic hydrocarbon radical, or the radicals R and R or R and R , in pairs, represent a substituted or non-substituted aromatic hydrocarbon radical with 6 to 18 C atoms and a functional group which, in conjunction with the C-C double bond in general formula (I), comprises a multiple bond between a C atom and a heteroatom, whereby during the reaction, the reaction mixture consists of 10 or less wt. % water.
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公开(公告)号:EP1294843A1
公开(公告)日:2003-03-26
申请号:EP01947356.0
申请日:2001-06-11
IPC分类号: C11D3/37
CPC分类号: C11D3/3749 , C11D3/0021 , C11D3/3776
摘要: The invention relates to a washing active preparation containing a water-soluble or water-dispersible block copolymer which can be produced by controlled radical polymerisation, to a method for producing a washing active preparation of this type and to the use of water-soluble or water-dispersible block copolymers produced by controlled radical polymerisation for producing washing active preparations.
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公开(公告)号:EP1368437A1
公开(公告)日:2003-12-10
申请号:EP02700225.2
申请日:2002-02-12
CPC分类号: C09D4/00 , C08F2438/02 , C08K5/3435 , C08F220/00 , C08F222/00 , C08F236/00 , C08F212/00
摘要: The invention relates to coating compositions that contain stable adducts that generate initiator radicals at higher temperatures. The invention further relates to a method for producing the same and to the use of said coating compositions. The stable adducts are used to initiate polymerization of ethylenically unsaturated monomers.
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公开(公告)号:EP1294775A1
公开(公告)日:2003-03-26
申请号:EP01960308.3
申请日:2001-06-13
IPC分类号: C08F2/38 , C08F293/00
CPC分类号: C08F212/32 , C08F246/00
摘要: The invention relates to a method for the production of a reaction product (A), comprising the following steps: reaction of a reaction mixture under radical conditions, said mixture comprising at least one monomer (a) capable of undergoing radical reactions, in the presence of at least one compound of formula (I), or in the presence of at least one compound of formula (II), where R1 to R4 independently and R11 and R12 = H, methyl, or a radical-stabilising and/or sterically-hindered group, from unsubstituted or substituted, linear or branched alkyl with two or more C atoms, cycloalkyl, an alcohol, ether, polyether, amino, or aralkyl group, a substituted or unsubstituted aromatic, heterocyclic or olefinic hydrocarbon, a halogen atom, a substituted or unsubstituted, linear or branched alkenyl or alkinyl group, or other homologous functional groups, with the proviso that at least two of the groups R1 to R4 are a radical-stabilising and/or a sterically-hindered group and the following compounds are excluded as compounds of formula (I): diphenylethylene, dinaphthylethylene, 4,4'-vinylidenebis(N,N'-dimethylaniline), 4,4'- vinylidenebis(aminobenzene), cis- and trans-stilbene and mixtures of two or more of the above.
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公开(公告)号:EP1252203A2
公开(公告)日:2002-10-30
申请号:EP00985177.5
申请日:2000-12-15
发明人: RAETHER, Roman, Benedikt , MODERY, Bernd , BRAUN, Frank , BRINKMANN-RENGEL, Susanne , CHRISTIE, David , HAREMZA, Sylke
IPC分类号: C08F12/32
CPC分类号: C08F12/32
摘要: The invention relates to a method for producing a conversion product (A), which comprises the following steps: (i) reacting, under radical conditions, a reaction mixture containing at least one radically convertible monomer (a) in the presence of at least one radical initiator and one compound of formula (I), wherein R1 to R4, independent of one another, represent hydrogen, a non-substituted or substituted alkyl radical, cycloalkyl radical, aralkyl radical, a non-substituted or substituted aromatic hydrocarbon radical with the provision that at least two of the radicals R1 to R4 represent a non-substituted or substituted aromatic hydrocarbon radical, or the radicals R?1 and R2 or R3 and R4¿, in pairs, represent a substituted or non-substituted aromatic hydrocarbon radical with 6 to 18 C atoms and a functional group which, in conjunction with the C-C double bond in general formula (I), comprises a multiple bond between a C atom and a heteroatom, whereby during the reaction, the reaction mixture consists of 10 or less wt. % water.
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