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    POLYESTER HYDROGELS
    7.
    发明公开
    POLYESTER HYDROGELS 有权
    聚酯水凝胶

    公开(公告)号：EP3083753A1

    公开(公告)日：2016-10-26

    申请号：EP14825292.7

    申请日：2014-12-17

    申请人： BASF SE

    发明人： YAMAMOTO, Motonori ,  WISSEMEIER, Alexander ,  WEIGELT, Wolfgang ,  KELLER, Harald ,  SEUFERT, Michael ,  FERNANDEZ RAMIREZ, Gimmy Alex ,  SANZ-GOMEZ, Jorge ,  WIEDEMANN, Alexandra

    IPC分类号： C08G63/676 ,  C08L67/06 ,  C08G63/52

    CPC分类号： C08G63/6888 ,  B01J20/262 ,  C05G3/04 ,  C08G63/52 ,  C08G63/676 ,  C08G63/916 ,  C08G2210/00 ,  C08G2310/00 ,  C09K17/18

    摘要： The present invention relates to a polyester comprising units derived from monomers A, B and C, wherein the group of monomers A consists of (a1) monomers A1, or (a2) monomers A1 and monomers A2, with monomers A1 and monomers A2 being present in a molar ratio of at least 31:69, preferably at least 4:1, wherein the monomers A1 are selected from the group consisting of aromatic sulfonated dicarboxylic acid based monomers of general formulae (I), (II), (III) and (IV), and wherein the monomers A2 are selected from the group consisting of non-sulfonated aromatic dicarboxylic acid based monomers of general formulae (V), (VI) and (VII); and wherein the group of monomers B consists of (b1) monomers B1, or (b2) monomers B1 and monomers B2, with monomers B1 and monomers B2 being present in a molar ratio of at least 1:9, preferably at least 4:1, wherein the monomers B1 are selected from the group consisting of unsaturated dicarboxylic acid based monomers of general formula (VIII), and wherein the monomers B2 are selected from the group consisting of saturated dicarboxylic acid based monomers of general formula (IX); and wherein the group of monomers C consists of (c1) monomers C1, (c2) monomers C2, or (c3) monomers C1 and C2, wherein the monomers C1 are selected from the group consisting of ethylene glycol based monomers of general formula (X), and wherein the monomers C2 are selected from the group consisting of propylene glycol based monomers of general formula (XI), and wherein the molar ratio of the units derived from the group of monomers A to the units derived from the group of monomers B is from 9:1 to 1:2.4, and wherein the molar ratio of the units derived from the groups of monomers A and B to the units derived from the group of monomers C is from 1.3:1 to 1:1.3. The polyester of the invention is preferably cross-linked.

    摘要翻译： 本发明涉及包含衍生自单体A，B和C的单元的聚酯，其中单体A的组由单体A1或（a2）单体A1和单体A2组成，单体A1和单体A2存在 摩尔比为至少31:69，优选至少4:1，其中单体A1选自通式（I），（II），（III）和（II）的芳族磺化二羧酸基单体和 （IV），并且其中单体A2选自通式（V），（VI）和（VII）的非磺化芳族二羧酸基单体; 并且其中单体组B由（b1）单体B1或（b2）单体B1和单体B2组成，其中单体B1和单体B2以至少1:9，优选至少4:1的摩尔比存在 其中单体B1选自通式（VIII）的不饱和二羧酸基单体，并且其中单体B2选自通式（IX）的基于饱和二羧酸的单体; 并且其中单体组C由（c1）单体C1，（c2）单体C2或（c3）单体C1和C2组成，其中单体C1选自通式（X）的基于乙二醇的单体 ），并且其中单体C2选自通式（XI）的基于丙二醇的单体，并且其中衍生自单体A的单元的单元与衍生自单体B的单元的单元的摩尔比 为9:1至1:2.4，并且其中衍生自单体A和B的基团的单元与衍生自单体C的基团的单元的摩尔比为1.3:1至1:1.3。 本发明的聚酯优选交联。