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1.发明授权VERFAHREN ZUR ISOMERISIERUNG VON CIS-2-PENTENNITRIL ZU TRANS-3-PENTENNITRIL 有权方法CIS 2戊烯腈反式-3-戊烯腈的异构化
公开(公告)号：EP1622862B1
公开(公告)日：2011-07-13
申请号：EP04727882.5
申请日：2004-04-16
Applicant: BASF SE
Inventor： BARTSCH, Michael , BAUMANN, Robert , HADERLEIN, Gerd , FLORES, Miguel Angel , JUNGKAMP, Tim , LUYKEN, Hermann , SCHEIDEL, Jens , SIEGEL, Wolfgang , KUNSMANN-KEITEL, Dagmar, Pascale
IPC: C07C253/30 , C07C255/07
CPC classification number: C07C253/30 , C07C255/07
Abstract: The invention relates to a method for the isomerization of 2-pentenenitrile to form trans-3-pentenenitrile in the presence of aluminium oxide as a catalyst. The invention is characterised in that the BET surface of the aluminium oxide is at least 50 m2/g.
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2.发明授权STERISCH ANSPRUCHSVOLLE CHELATPHOSPHINITPHOSPHITLIGANDEN, KATALYSATOR, UMFASSEND WENIGSTENS EINEN NICKEL(0)KOMPLEX STABILISIERT DURCH DIESEN LIGANDEN SOWIE EIN VERFAHREN ZUR HERSTELLUNG VON NITRILEN 有权大件CHELATPHOSPHINITPHOSPHITLIGANDEN，催化剂，含有稳定化通过一种用于制造NITRILES这些配体和方法至少一种镍（0）络合物
公开(公告)号：EP1682559B1
公开(公告)日：2009-12-30
申请号：EP04790949.4
申请日：2004-10-28
Applicant: BASF SE
Inventor： BARTSCH, Michael , BAUMANN, Robert , HADERLEIN, Gerd , FLORES, Miguel Angel , JUNGKAMP, Tim , LUYKEN, Hermann , SCHEIDEL, Jens , SIEGEL, Wolfgang
CPC classification number: B01J31/1885 , B01J31/185 , B01J31/1875 , B01J2231/323 , B01J2231/52 , B01J2531/847 , C07C253/10 , C07C253/30 , C07F9/4875 , C07F9/65744 , C07C255/07 , C07C255/09
Abstract: The invention relates to phosphinite phosphites I of formula 1, 2, 3, 4, 5 or 6 and mixtures thereof, wherein R1, R2, R4 independently represent an alkyl or alkylene group with 1 to 8 carbon atoms, provided that at least one of the groups R1, R2, R4 is different from H; R5 to R22 independently represent H, an alkyl or alkylene group with 1 to 8 carbon atoms; R3 is H, methyl or ethyl; X is F, Cl or CF3, if n = 1 or 2 and X is H, if n = 0.
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