PIPERAZINVERBINDUNGEN MIT HERBIZIDER WIRKUNG

    公开(公告)号:EP2054394A2

    公开(公告)日:2009-05-06

    申请号:EP08760876.6

    申请日:2008-06-11

    申请人: Basf Se

    IPC分类号: C07D241/08 A01N43/60

    CPC分类号: C07D241/08 A01N43/60

    摘要: The invention relates to piperazine compounds of the following defined general formula (I) and to their use as herbicides. The invention also relates to crop protection agents and to a method for combating undesired plant growth. In formula (I): R1 is selected from halogen, cyano, nitro, Z-C(=O)-R12, phenyl and a 5- or 6-membered heterocyclic group that has 1, 2, 3 or 4 heteroatoms, selected from O, N and S as ring atoms, wherein phenyl and the heterocyclic group are unsubstituted or have 1, 2, 3 or 4 substituents R1a; Z stands for a covalent bond or a CH2 group; R12 represents hydrogen, C1-C6 alkyl, C3-C6 cycloalkyl, C2-C6 alkenyl, C5-C6 cycloalkenyl, C2-C6 alkynyl and similar; R2 represents hydrogen, halogen, nitro, cyano, C1-C4 alkyl, C1-C4 haloalkyl, C2- C4 alkenyl, C1-C4 alkoxy, C1-C4 haloalkoxy, benzyl or a group S(O) nR21, wherein R21 stands for C1-C4 alkyl or C1-C4 haloalkyl and n stands for 0, 1 or 2; R3 represents hydrogen or halogen; R4 represents C1-C4 alkyl, C3- C4 alkenyl or C3-C4 alkynyl; R5 represents hydrogen, C1-C4 alkyl, C3-C4 alkenyl, C3-C4 alkynyl or a group (=O)R51, wherein R51 stands for hydrogen, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy or C1-C4 haloalkoxy; R6 stands for C1-C4 alkyl, C1-C4 hydroxy alkyl or C1-C4 haloalkyl; R7, R8 stand, independently of one another, for hydrogen, OH, C1-C4 alkoxy, C1-C4 haloalkyoxy, C1-C4 alkyl or C1-C4 haloalkyl; R9, R10 are selected, independently of one another, from hydrogen, halogen, CN, NO2, C1-C4 alkyl, C1-C4 haloalkyl, C2-C4 alkenyl, C1-C4 alkoxy and C1-C4 haloalkoxy; and R11 represents hydrogen or C1-C4 alkyl. The invention also relates to the agriculturally suitable salts of said compounds.

    摘要翻译: 本发明涉及下面定义的通式(I)的哌嗪化合物和它们作为除草剂的用途。 本发明还涉及作物保护剂和防治不希望的植物生长的方法。 在式(I)中,R 1选自卤素,氰基,硝基,ZC(= O)-R 12,苯基和具有1,2,3或4个选自O,O或S的杂原子的5-或6-元杂环基团。 N和S作为环原子,其中苯基和杂环基团未被取代或具有1,2,3或4个取代基R 1a; Z代表共价键或CH2基团; R 12代表氢,C 1 -C 6烷基,C 3 -C 6环烷基,C 2 -C 6烯基,C 5 -C 6环烯基,C 2 -C 6炔基等; R2表示氢,卤素,硝基,氰基,C1-C4烷基,C1-C4卤代烷基,C2-C4链烯基,C1-C4烷氧基,C1-C4卤代烷氧基,苄基或S(O)nR21基团, -C4烷基或C1-C4卤代烷基,n代表0,1或2; R3代表氢或卤素; R 4代表C 1 -C 4烷基,C 3 -C 4烯基或C 3 -C 4炔基; R 5代表氢,C 1 -C 4烷基,C 3 -C 4烯基,C 3 -C 4炔基或基团(= O)R 51,其中R 51代表氢,C 1 -C 4烷基,C 1 -C 4卤代烷基, C4卤代烷氧基; R6代表C1-C4烷基,C1-C4羟烷基或C1-C4卤代烷基; R 7,R 8彼此独立地代表氢,OH,C 1 -C 4烷氧基,C 1 -C 4卤代烷氧基,C 1 -C 4烷基或C 1 -C 4卤代烷基; R9,R10彼此独立地选自氢,卤素,CN,NO2,C1-C4烷基,C1-C4卤代烷基,C2-C4链烯基,C1-C4烷氧基和C1-C4卤代烷氧基; 并且R 11代表氢或C 1 -C 4烷基。 本发明还涉及所述化合物的农业上合适的盐。

    SYNERGISTICALLY ACTING HERBICIDAL MIXTURES
    4.
    发明授权
    SYNERGISTICALLY ACTING HERBICIDAL MIXTURES 有权
    协同除草剂混合使用

    公开(公告)号:EP1526774B1

    公开(公告)日:2008-05-21

    申请号:EP03771085.2

    申请日:2003-07-24

    申请人: BASF SE

    IPC分类号: A01N43/80

    摘要: A synergistic herbicidal mixture comprising A) at least one 3-heterocyclyl-substituted benzoyl derivative of the formula (I) see paper versionin which the variables have the following meanings: R1, R3 are halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, alkylsulfinyl or alkylsulfonyl; R2 is a optionally substituted heterocyclic radical selected from the group: isoxazol-3-yl, isoxazol-4-yl, isoxazol-5-yl, 4,5-dihydroisoxazol-3-yl, 4,5-di-hydroisoxazol-4-yl and 4,5-dihydroisoxazol-5-yl;R4 is hydrogen, halogen or alkyl; R5 is alkyl; R6 is hydrogen or alkyl; or one of its environmentally compatible salts; and B) at least the compound of formula (IIa) see paper versionor one of its environmentally compatible salts; and, if desired, orthe compound of formula (IIb) see paper versionor one of its environmentally compatible salts; in a synergistically effective amount; and, if desired, C) at least one further herbicidal compound; in a synergistically effective amount. Compositions comprising these mixtures, processes for the preparation of these compositions, and their use for controlling un-desired plants.

    NICHT-WÄSSRIGE WIRKSTOFFKONZENTRATE MIT HERBIZIDER WIRKUNG
    6.
    发明公开
    NICHT-WÄSSRIGE WIRKSTOFFKONZENTRATE MIT HERBIZIDER WIRKUNG 有权
    非含水活性精矿具有除草活性

    公开(公告)号:EP2048946A2

    公开(公告)日:2009-04-22

    申请号:EP07788222.3

    申请日:2007-08-03

    申请人: BASF SE

    摘要: The present invention relates to active ingredient concentrates having an herbicidal effect, comprising: a) 10 to 100 g/L of at least one 4-benzoyl-substituted pyrazol compound of the formula (I), wherein R1, R3 independently of each other stand for hydrogen, halogen, hethyl, halogen methyl, methoxy, halogen methoxy, methylthio, methyl sulfinyl, or methyl sulfonyl; R2 stands for a 5-membered heterocyclic residue, which is unsubstituted, or carries 1, 2, 3, or 4 substituents, which are selected from halogen, C1-C6-alkyl, C1-C4-akoxy, C1-C4-halogen alkyl, C1-C4-halogen alkoxy, and C1-C4-alkylthio; R4 stands for hydrogen, halogen, or methyl; R5 stands for C1-C6-alkyl, C3-C6-cycloalkyl, or C3-C6-cycloalkylmethyl; and R6 stands for hydrogen, or C1-C4-Alkyl; or one of its salts used in agriculture, b) 200 to 700 g/L 2-chlorine-N-(2,4-dimethyl-3-thienyl)-N-(2-methoxy-1-methylethyl)-acetamide, and 25 c) 10 to 200 g/L of at least a surface-active substance S, which is selected from a mixture of at least one anionic surface-active compound, and at least one non-ionic surface-active compound, wherein the components a), b), and c) are dissolved in an organic solvent mixture, which comprises at least 95 wt.-%, based on the solvent mixture, of d1) at least one aprotic polar organic solvent, which has a miscibility with water at 25°C and 1 bar of at least 50 g/l, and d2) at least one organic solvent, which has a solubility in water at 25°C and 1 bar of less than 5 g/l.

    PIPERAZINVERBINDUNGEN MIT HERBIZIDER WIRKUNG

    公开(公告)号:EP2054395A2

    公开(公告)日:2009-05-06

    申请号:EP08760877.4

    申请日:2008-06-11

    申请人: Basf Se

    摘要: The invention relates to piperazine compounds of the following defined general formula (I) and to their use as herbicides. The invention also relates to crop protection agents and to a method for combating undesired plant growth. In formula (I), the variables are defined as follows: R1 is selected from halogen, cyano, nitro, Z-C(=O)-R11, phenyl and a 5- or 6-membered heterocyclic group that has 1, 2, 3 or 4 heteroatoms, selected from O, N and S as ring atoms, wherein phenyl and the heterocyclic group are unsubstituted or have 1, 2, 3 or 4 substituents R1a; Z stands for a covalent bond or a CH2 group; R11 represents hydrogen, C1-C6 alkyl, C3-C6 cycloalkyl, C2-C6 alkenyl, C5-C6 cycloalkenyl, C2-C6 alkynyl and similar; R2 represents hydrogen, halogen, nitro, cyano, C1-C4 alkyl, C1-C4 haloalkyl, C2- C4 alkenyl, C1-C4 alkoxy, C1-C4 haloalkoxy, benzyl or a group S(O) nR21, wherein R21 stands for C1-C4 alkyl or C1-C4 haloalkyl and n stands for 0, 1 or 2; R3 represents hydrogen or halogen; R4 represents C1-C4 alkyl, C3- C4 alkenyl or C3-C4 alkynyl; R5 represents hydrogen, C1-C4 alkyl, C3-C4 alkenyl, C3-C4 alkynyl or a group (=O)R51, wherein R51 stands for hydrogen, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy or C1-C4 haloalkoxy; R6 stands for C1-C4 alkyl, C1-C4 hydroxy alkyl or C1-C4 haloalkyl; R7, R8 stand, independently of one another, for hydrogen, OH, C1-C4 alkoxy, C1-C4 haloalkyoxy, C1-C4 alkyl or C1-C4 haloalkyl; R9, R10 are selected, independently of one another, from hydrogen, halogen, CN, NO2, C1-C4 alkyl, C1-C4 haloalkyl, C2-C4 alkenyl, C1-C4 alkoxy and C1-C4 haloalkoxy.

    摘要翻译: 本发明涉及下面定义的通式(I)的哌嗪化合物和它们作为除草剂的用途。 本发明还涉及作物保护剂和防治不希望的植物生长的方法。 在式(I)中,变量定义如下:R 1选自卤素,氰基,硝基,ZC(= O)-R 11,苯基和具有1,2,3或4个碳原子的5-或6-元杂环基团 4个选自O,N和S的杂原子作为环原子,其中苯基和杂环基未被取代或具有1,2,3或4个取代基R 1a; Z代表共价键或CH2基团; R 11代表氢,C 1 -C 6烷基,C 3 -C 6环烷基,C 2 -C 6烯基,C 5 -C 6环烯基,C 2 -C 6炔基等; R2表示氢,卤素,硝基,氰基,C1-C4烷基,C1-C4卤代烷基,C2-C4链烯基,C1-C4烷氧基,C1-C4卤代烷氧基,苄基或S(O)nR21基团, -C4烷基或C1-C4卤代烷基,n代表0,1或2; R3代表氢或卤素; R 4代表C 1 -C 4烷基,C 3 -C 4烯基或C 3 -C 4炔基; R 5代表氢,C 1 -C 4烷基,C 3 -C 4烯基,C 3 -C 4炔基或基团(= O)R 51,其中R 51代表氢,C 1 -C 4烷基,C 1 -C 4卤代烷基, C4卤代烷氧基; R6代表C1-C4烷基,C1-C4羟烷基或C1-C4卤代烷基; R 7,R 8彼此独立地代表氢,OH,C 1 -C 4烷氧基,C 1 -C 4卤代烷氧基,C 1 -C 4烷基或C 1 -C 4卤代烷基; R 9,R 10彼此独立地选自氢,卤素,CN,NO 2,C 1 -C 4烷基,C 1 -C 4卤代烷基,C 2 -C 4烯基,C 1 -C 4烷氧基和C 1 -C 4卤代烷氧基。

    SYNERGISTICALLY ACTING HERBICIDAL MIXTURES
    9.
    发明授权
    SYNERGISTICALLY ACTING HERBICIDAL MIXTURES 有权
    协同组合物除草剂

    公开(公告)号:EP1526773B1

    公开(公告)日:2008-12-17

    申请号:EP03765083.5

    申请日:2003-07-22

    申请人: BASF SE

    IPC分类号: A01N43/80

    CPC分类号: A01N43/80 A01N2300/00

    摘要: A synergistic herbicidal mixture comprising: A) at least one 3-heterocyclyl-substituted benzoyl derivative of the formula (I) in which the variables have the following meanings: R1, R3 are halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, alkylsulfinyl or alkylsulfonyl; R2 is a optionally substituted heterocyclic radical selected from the group: isoxazol-3-yl, isoxazol-4-yl, isoxazol-5-yl, 4,5-dihydroisoxazol-3-yl, 4,5-dihydroisoxazol-4-yl and 4,5-dihydroisoxazol-5-yl; R4 is hydrogen, halogen or alkyl; R5 is alkyl; R6 is hydrogen or alkyl; or one of its environmentally compatible salts; and B) two herbicides selected from the group including imazapyr, imazaquin, imazamethabenz-methyl, imazamox, imazapic and imazethapyr; or one of its environmentally compatible salts; and, if desired, C) at least one further herbicidal compound; in a synergistically effective amount. Compositions comprising these mixtures, processes for the preparation of these compositions, and their use for controlling undesired plants