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    PIPERAZINVERBINDUNGEN MIT HERBIZIDER WIRKUNG
    7.
    发明公开
    PIPERAZINVERBINDUNGEN MIT HERBIZIDER WIRKUNG 审中-公开

    公开(公告)号：EP2054395A2

    公开(公告)日：2009-05-06

    申请号：EP08760877.4

    申请日：2008-06-11

    申请人： Basf Se

    发明人： HUPE, Eike ,  SEITZ, Thomas ,  WITSCHEL, Matthias ,  SONG, Dschun ,  MOBERG, William Karl ,  PARRA RAPADO, Liliana ,  STELZER, Frank ,  VESCOVI, Andrea ,  NEWTON, Trevor William ,  REINHARD, Robert ,  SIEVERNICH, Bernd ,  GROSSMANN, Klaus ,  EHRHARDT, Thomas ,  RACK, Michael ,  KIBLER, Elmar

    IPC分类号： C07D241/08 ,  C07D403/10 ,  C07D407/10 ,  C07D409/10 ,  C07D413/10 ,  C07D417/10 ,  A61K31/495

    CPC分类号： C07D241/08 ,  C07D403/10 ,  C07D407/10 ,  C07D409/10 ,  C07D413/10 ,  C07D417/10

    摘要： The invention relates to piperazine compounds of the following defined general formula (I) and to their use as herbicides. The invention also relates to crop protection agents and to a method for combating undesired plant growth. In formula (I), the variables are defined as follows: R1 is selected from halogen, cyano, nitro, Z-C(=O)-R11, phenyl and a 5- or 6-membered heterocyclic group that has 1, 2, 3 or 4 heteroatoms, selected from O, N and S as ring atoms, wherein phenyl and the heterocyclic group are unsubstituted or have 1, 2, 3 or 4 substituents R1a; Z stands for a covalent bond or a CH2 group; R11 represents hydrogen, C1-C6 alkyl, C3-C6 cycloalkyl, C2-C6 alkenyl, C5-C6 cycloalkenyl, C2-C6 alkynyl and similar; R2 represents hydrogen, halogen, nitro, cyano, C1-C4 alkyl, C1-C4 haloalkyl, C2- C4 alkenyl, C1-C4 alkoxy, C1-C4 haloalkoxy, benzyl or a group S(O) nR21, wherein R21 stands for C1-C4 alkyl or C1-C4 haloalkyl and n stands for 0, 1 or 2; R3 represents hydrogen or halogen; R4 represents C1-C4 alkyl, C3- C4 alkenyl or C3-C4 alkynyl; R5 represents hydrogen, C1-C4 alkyl, C3-C4 alkenyl, C3-C4 alkynyl or a group (=O)R51, wherein R51 stands for hydrogen, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy or C1-C4 haloalkoxy; R6 stands for C1-C4 alkyl, C1-C4 hydroxy alkyl or C1-C4 haloalkyl; R7, R8 stand, independently of one another, for hydrogen, OH, C1-C4 alkoxy, C1-C4 haloalkyoxy, C1-C4 alkyl or C1-C4 haloalkyl; R9, R10 are selected, independently of one another, from hydrogen, halogen, CN, NO2, C1-C4 alkyl, C1-C4 haloalkyl, C2-C4 alkenyl, C1-C4 alkoxy and C1-C4 haloalkoxy.

    摘要翻译： 本发明涉及下面定义的通式（I）的哌嗪化合物和它们作为除草剂的用途。 本发明还涉及作物保护剂和防治不希望的植物生长的方法。 在式（I）中，变量定义如下：R 1选自卤素，氰基，硝基，ZC（= O）-R 11，苯基和具有1,2,3或4个碳原子的5-或6-元杂环基团 4个选自O，N和S的杂原子作为环原子，其中苯基和杂环基未被取代或具有1,2,3或4个取代基R 1a; Z代表共价键或CH2基团; R 11代表氢，C 1 -C 6烷基，C 3 -C 6环烷基，C 2 -C 6烯基，C 5 -C 6环烯基，C 2 -C 6炔基等; R2表示氢，卤素，硝基，氰基，C1-C4烷基，C1-C4卤代烷基，C2-C4链烯基，C1-C4烷氧基，C1-C4卤代烷氧基，苄基或S（O）nR21基团， -C4烷基或C1-C4卤代烷基，n代表0,1或2; R3代表氢或卤素; R 4代表C 1 -C 4烷基，C 3 -C 4烯基或C 3 -C 4炔基; R 5代表氢，C 1 -C 4烷基，C 3 -C 4烯基，C 3 -C 4炔基或基团（= O）R 51，其中R 51代表氢，C 1 -C 4烷基，C 1 -C 4卤代烷基， C4卤代烷氧基; R6代表C1-C4烷基，C1-C4羟烷基或C1-C4卤代烷基; R 7，R 8彼此独立地代表氢，OH，C 1 -C 4烷氧基，C 1 -C 4卤代烷氧基，C 1 -C 4烷基或C 1 -C 4卤代烷基; R 9，R 10彼此独立地选自氢，卤素，CN，NO 2，C 1 -C 4烷基，C 1 -C 4卤代烷基，C 2 -C 4烯基，C 1 -C 4烷氧基和C 1 -C 4卤代烷氧基。

    SUBSTITUTED 1,2,5-OXADIAZOLE COMPOUNDS AND THEIR USE AS HERBICIDES II
    8.
    发明公开
    SUBSTITUTED 1,2,5-OXADIAZOLE COMPOUNDS AND THEIR USE AS HERBICIDES II 审中-公开
    取代的1,2,5-恶二唑及其作为除草剂II

    公开(公告)号：EP2780339A1

    公开(公告)日：2014-09-24

    申请号：EP12787713.2

    申请日：2012-11-15

    申请人： BASF SE

    发明人： KRAUS, Helmut ,  WITSCHEL, Matthias ,  SEITZ, Thomas ,  NEWTON, Trevor William ,  PARRA RAPADO, Liliana ,  APONTE, Raphael ,  KREUZ, Klaus ,  GROSSMANN, Klaus ,  LERCHL, Jens ,  EVANS, Richard R.

    IPC分类号： C07D409/12 ,  C07D413/12 ,  C07D417/12 ,  A01N43/82

    CPC分类号： C07D413/12 ,  A01N43/82 ,  C07D409/12 ,  C07D413/14 ,  C07D417/12

    摘要： The present invention relates to substituted 1,2,5-oxadiazole compounds of the formula (I) and the N-oxides and salts thereof and to compositions comprising the same. The invention also relates to the use of the 1,2,5-oxadiazole compounds or of the compositions comprising such compounds for controlling unwanted vegetation. Furthermore, the invention relates to methods of applying such compounds. In formula I, the variables have the following meanings: R is e.g. hydrogen, cyano, nitro, halogen, C
    1 -C
    6 -alkyl, C
    3 -C
    7 -cycloalkyl, C
    3 -C
    7 -cycloalkyl-C
    1 -C
    4 -alkyl, C
    1 -C
    6 -haloalkyl, C
    2 -C
    6 -alkenyl, C
    2 -C
    6 -haloalkenyl, C
    2 -C
    6 -alkynyl, C
    2 -C
    6 -haloalkynyl, C
    1 -C
    4 -alkoxy-C
    1 -C
    4 -alkyl, C
    1 -C
    4 -haloalkoxy-C
    1 -C
    4 -alkyl, O-R
    a , Z-S(O)
    n -R
    b , Z-C(=O)-R
    c , Z-C(=O)-OR
    d , Z-C(=O)-NR
    e R
    f , Z-NR
    g R
    h , Z-phenyl or Z-heterocyclyl;CYC is a bi- or tricyclic radical of the following formulae Cyc-1 or Cyc-2 where # is the point of attachment of the bicyclic radical to the carbonyl group, Q, Q' independently of each other are e.g. a fused 5-, 6-, 7-, 8-, 9- or 10-membered carbocycle or a fused 5-, 6-, 7-, 8-, 9- or 10-membered heterocycle; R
    1 is e.g. Z
    1 -cyano, halogen, nitro, C
    1 -C
    8 -alkyl, C
    2 -C
    8 -alkenyl, C
    2 -C
    8 -alkynyl, C
    1 -C
    8 -haloalkyl, C
    1 -C
    8 -alkoxy, C
    1 -C
    4 -alkoxy-C
    1 -C
    4 -alkyl, Z
    1 -C
    1 -C
    4 -alkoxy-C
    1 -C
    4 -alkoxy, C
    1 - C
    4 -alkylthio-C
    1 -C
    4 -alkyl, Z
    1 -C
    1 -C
    4 -alkylthio-C
    1 -C
    4 -alkylthio, C
    2 -C
    6 -alkenyloxy, C
    2 -C
    6 - alkynyloxy, C
    1 -C
    6 -haloalkoxy, C
    1 -C
    4 -haloalkoxy-C
    1 -C
    4 -alkyl, Z
    1 -C
    1 -C
    4 -haloalkoxy-C
    1 -C
    4 - alkoxy, Z
    1 -S(O)
    k -R
    1b , Z
    1 -phenoxy or Z
    1 -heterocyclyloxy; R
    3 is e.g. hydrogen, halogen, Z
    3 -OH, Z
    3 -NO
    2 , Z
    3 -cyano, C
    1 -C
    6 -alkyl, C
    2 -C
    8 - alkenyl, C
    2 -C
    8 -alkynyl, Z
    2 -C
    3 -C
    10 -cycloalkyl, Z
    3 -C
    3 -C
    10 -cycloalkoxy, C
    1 -C
    8 -haloalkyl, Z
    3 -C
    1 -C
    8 -alkoxy, Z
    3 -C
    1 -C
    8 -haloalkoxy, Z
    3 -C
    1 -C
    4 -alkoxy-C
    1 -C
    4 -alkoxy, Z
    3 -C
    1 -C
    4 -alkylthio-C
    1 -C
    4 -alkylthio, Z
    3 -C
    2 -C
    8 -alkenyloxy, Z
    3 -C
    2 -C
    8 -alkynyloxy, Z
    3 -C
    1 -C
    8 -haloalkoxy, Z
    3 -C
    2 -C
    8 - haloalkenyloxy, Z
    3 -C
    2 -C
    8 -haloalkynyloxy, Z
    3 -C
    1 -C
    4 -haloalkoxy-C
    1 -C
    4 -alkoxy, Z
    3 -(tri-C
    1 - C
    4 -alkyl)silyl, Z
    3 -S(O)
    k -R
    3b , Z
    3 -C(=O)-R
    3c , Z
    3 -C(=O)-OR
    3d , Z
    3 -C(=O)-NR
    3e R
    3f , Z
    3 - NR
    3g R
    3h , Z
    3a -phenyl or Z
    3a -heterocyclyl; R
    4 is hydrogen, halogen, cyano, nitro, C
    1 -C
    4 -alkyl or C
    1 -C
    4 -haloalkyl; R
    5 is hydrogen, halogen, C
    1 -C
    4 -alkyl or C
    1 -C
    4 -haloalkyl; provided that at least one of the radicals R
    4 and R
    5 is different from hydrogen; n is 0, 1 or 2; k is 0, 1 or 2; and the variables Z, Z
    1 , Z
    2 , Z
    3 , Z
    3a , R
    a , R
    b , R
    1b , R
    2b , R
    3b , R
    c , R
    2c , R
    3c , R
    d , R
    3d , R
    e , R
    f , R
    3e , R
    3f , R
    g , R
    h , R
    2g , R
    2h , R
    3g and R
    3h have the meanings given in the claims.