Abstract:
The invention relates to a method for producing transition metal carbonates having an average particle diameter in the range from 6 to 19 µm (D50), characterized in that at least one solution of at least one transition metal salt is combined with at least one solution of at least one alkali metal carbonate or alkali metal hydrogen carbonate in a stirring vessel, whereby an aqueous suspension of transition metal carbonate is produced. The invention is also characterized in that, in at least one further compartment, a mechanical power in the range from 50 to 10000 W/I is continuously applied to a fraction of the suspension, with respect to the fraction of the suspension, and that the fraction is subsequently fed back into the stirring vessel.
Abstract:
The invention relates to a method for producing electrode materials, characterised in that a mixed oxide, which has lithium and at least one transition metal as cations, is treated with at least one organic, oxygen-containing compound of sulphur or phosphorous, or a corresponding alkali metal or ammonium salt of an organic, oxygen-containing compound of sulphur or phosphorous, or a completely alkylated derivative of an oxygen-containing compound of sulphur or phosphorous.
Abstract:
The invention relates to a cathode (A) for Li-ion rechargeable batteries, comprising (a1) at least one accumulator, (a2) at least one layer comprising at least one cathode-active material storing and releasing Li-ions, at least part of the layer (a2) being compressed and/or the side of the layer (a2) facing the anode comprising at least one layer (a3) containing at least one solid electrolyte conducting Li-ions, the solid electrolyte being selected from the group consisting of inorganic solid electrolytes and mixtures thereof and being insoluble in the electrolyte system (B) used in the Li-ion rechargeable battery. The invention further relates to Li-ion rechargeable batteries comprising the cathode (A), and to a method for producing the cathode (A).
Abstract:
The present invention relates to an active cathode material of the general formula (I)
M x Ni a-y M 1 b M 2 c M 3 y O 2 (I)
in which the variables are each defined as follows: M is an alkali metal, M 1 is V, Cr, Mn, Fe, Co or a mixture thereof, M 2 is Ge, Sn, Ti, Zr or a mixture thereof, M 3 is Mg, Zn, Cu or a mixture thereof, x is in the range from 0.5 to 0.8, a is in the range from 0.1 to 0.4, b is in the range from 0.05 to 0.7, c is in the range from 0.02 to 0.6, y is in the range from 0.05 to 0.2 wherein a + b + c = 1. The present invention further relates to an electrode material comprising said active cathode material, to electrodes produced from or using said electrode material and to a rechargeable electrochemical cell comprising at least one electrode. The present invention further relates to a process for preparing said active cathode material of the general formula (I).
Abstract translation:本发明涉及一种通式(I)的活性阴极材料。ƒ€ƒ€ƒ€ƒ€ƒ€ƒM x Ni ay M 1 b M 2 c M 3 y O 2€ƒ€ 变量的定义如下:M是碱金属,M 1是V,Cr,Mn,Fe,Co或它们的混合物,M 2是Ge,Sn, Ti,Zr或其混合物,M 3为Mg,Zn,Cu或其混合物,x为0.5〜0.8,a为0.1〜0.4,b为0.05〜0.7的范围 ,c在0.02至0.6的范围内,y在0.05至0.2的范围内,其中a + b + c = 1。本发明还涉及包含所述活性阴极材料的电极材料, 所述电极材料和包括至少一个电极的可再充电电化学电池。 本发明还涉及制备所述通式(I)的活性阴极材料的方法。
Abstract:
The invention relates to spherical particles of transition metal carbonates, transition metal hydroxides or transition metal carbonate hydroxides that have cations of at least two transition metals, selected from nickel, cobalt, manganese, titanium, vanadium, chromium and iron, characterised in that the concentration of the cations of at least one of the transition metals, plotted over the radius of the particle in question, has at least one relative extreme value that lies neither in the centre nor at the edge of the particle in question.