Abstract:
The invention relates to a catalyst for decomposing nitrous oxide, to a method for producing same, and to the use thereof. The catalyst contains rhodium on a catalyst support, and the catalyst support is produced by mixing zirconium dioxide powder with a silicon compound as a binder and water so as to form a kneadable mass, homogenizing the mass, molding the mass into molded bodies, drying, and calcining. The binder is selected from silicon compounds of the general formula (I) to (IV) (Hal)xSiR4-x(l) (Hal)xSi(OR')4-x(II) (Hal)xSi(NR R )a-x(III) RxSi(OR')4-x (IV) RxSi(NR R )4-x(V) (R O)xSi(NR R )4-x(VI), where Hal independently of one another represents halogen (F, Cl, Br, or I), R independently of one another represents H or an optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkenyl, arylalkyl, or aryl group, R , R independently of one another represent H or an optionally substituted alkyl, acyl, arylalkyl, or aryl group, and x represents 0 to 4.
Abstract translation:本发明涉及用于分解一氧化二氮的催化剂,其制备方法及其用途。 催化剂在催化剂载体上含有铑,催化剂载体通过将二氧化锆粉末与作为粘结剂的硅化合物和水混合以形成可捏炼物质,均化该物质,将该物质成型为模制体,干燥, 并煅烧。 (I)至(IV)(Hal)x SiR 4-x(1)(Hal)x Si(OR')4-x(II)(Hal)x Si(NR 1) R 2 Si)x(V)(R 1 O)x Si(NR 1)R x Si(OR')4-x(IV)R x Si(NR 1 R 2)4-x R 2)4-x(VI),其中Hal彼此独立地表示卤素(F,Cl,Br或I),R彼此独立地表示H或任选取代的烷基,烯基,炔基,环烷基, 环烯基,芳基烷基或芳基,R 1,R 2彼此独立地表示H或任选取代的烷基,酰基,芳基烷基或芳基,并且x表示0至4。