VERFAHREN ZUR REINIGUNG VON IONISCHEN FLÜSSIGKEITEN
    4.
    发明公开
    VERFAHREN ZUR REINIGUNG VON IONISCHEN FLÜSSIGKEITEN 有权
    清理方法离子液体

    公开(公告)号:EP2742028A1

    公开(公告)日:2014-06-18

    申请号:EP12743750.7

    申请日:2012-08-08

    Applicant: BASF SE

    CPC classification number: C07D233/54

    Abstract: The invention relates to a method for purifying salts K
    + X
    - , K
    + is any cation and X
    - is an organic anion having at least 6 C atoms, characterized in that a) the salts K
    + X
    - are present in compositions that contain water-soluble salts (K
    + )
    n Y
    n- as contaminants, K
    + being the aforementioned cation, Y
    n- being an inorganic anion or an organic ion different from X
    - having at most 10 C atoms, and n being 1, 2, or 3, b) the anions X
    - of the salts K
    + X
    - are transformed into the acids HX by adding a water-soluble hydrogen acid (H
    + )
    m Z
    m- , m being 1, 2, or 3, two phases being formed, an organic phase, which contains HX, and an aqueous phase, which contains the water-soluble salts (K
    + )
    m Z
    m- and (K
    + )
    n Y
    n- or acids (H
    + )
    n Y
    n- , c) the organic phase is removed, d) the aqueous phase is conducted over a strongly basic anion exchanger, which binds the anions Z
    m- and Y
    n- and releases OH
    - , and thus an aqueous mixture, containing K
    + OH
    - is obtained, and e) the organic phase (containing HX) and the obtained aqueous mixture (containing KOH) are reacted, possibly with the addition of further HX, to form K
    + X
    - and H
    2 O.

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