摘要:
Sulfur-based electrodes, and associated systems and methods for their fabrication, are generally described. Certain embodiments relate to sulfur-based electrodes with smooth external surfaces. According to some embodiments, relatively large forces can be applied to compositions from which the sulfur-based electrodes are made during the fabrication process. In some such embodiments, the compositions can maintain relatively high porosities, even after the relatively large forces have been applied to them. Methods in which liquids are employed during the electrode fabrication process are also described.
摘要:
Electrode structures and methods for making the same are generally described. In certain embodiments, the electrode structures can include a plurality of particles, wherein the particles comprise indentations relative to their convex hulls. As the particles are moved proximate to or in contact with one another, the indentations of the particles can define pores between the particles. In addition, when particles comprising indentations relative to their convex hulls are moved relative to each other, the presence of the indentations can ensure that complete contact does not result between the particles (i.e., that there remains some space between the particles) and that void volume is maintained within the bulk of the assembly. Accordingly, electrodes comprising particles with indentations relative to their convex hulls can be configured to withstand the application of a force to the electrode while substantially maintaining electrode void volume (and, therefore, performance). Particles having indentations relative to their convex hulls also occupy a relatively small volume, compared to spheres or other particles including boundaries that fill substantially all of their convex hulls, allowing one to introduce a desired amount of void volume while reducing the percentage of volume within the electrode occupied by particulate material.
摘要:
The present invention relates to a layer composite, an electrode comprising or consisting of said layer composite, an electrochemical cell comprising said electrode and a method for forming said layer composite.
摘要:
Sulfur-based electrodes, and associated systems and methods for their fabrication, are generally described. Certain embodiments relate to sulfur-based electrodes with smooth external surfaces. According to some embodiments, relatively large forces can be applied to compositions from which the sulfur-based electrodes are made during the fabrication process. In some such embodiments, the compositions can maintain relatively high porosities, even after the relatively large forces have been applied to them. Methods in which liquids are employed during the electrode fabrication process are also described.
摘要:
Articles and methods including layers for protection of electrodes in electrochemical cells are provided. As described herein, a layer, such as a protective layer for an electrode, may comprise a plurality of particles (e.g., crystalline inorganic particles, amorphous inorganic particles). In some aspects, at least a portion of the plurality of particles (e.g., inorganic particles) are fused to one another. For instance, in some aspects, the layer may be formed by aerosol deposition or another suitable process that involves subjecting the particles to a relatively high velocity such that fusion of particles occurs during deposition. In some cases, the protective layer may be porous.
摘要:
An electrolyte composition (A) containing (i) at least one aprotic organic solvent; (ii) at least one conducting salt; (iii) at least one compound of formula (NC)(A1X1)C═C(X2A2)(CN) wherein X1 and X2 are independently from each other selected from N(R′), P(R1), O, and S, and A1 and A2 are selected from H or organic substituents; and electrochemical cells containing electrolyte composition (A).
摘要:
An electrolyte composition (A) containing (i) at least one aprotic organic solvent; (ii) at least one conducting salt; (iii) at least one compound of formula (NC)(A1X1)C═C(X2A2)(CN) wherein X1 and X2 are independently from each other selected from N(R′), P(R1), O, and S, and A1 and A2 are selected from H or organic substituents; and electrochemical cells containing electrolyte composition (A).
摘要翻译:一种电解质组合物(A),其包含:(i)至少一种非质子有机溶剂; •(ii)至少一种导电盐; (iii)至少一种式(NC)(A 1 X 1)C = C(X 2 A 2)(CN)的化合物,其中X 1和X 2彼此独立地选自N(R'),P (R 1),O和S,并且A 1和A 2选自H或有机取代基; 和含有电解质组合物(A)的电化学电池。