摘要:
Disclosed is a rubber composition having a high storage modulus (G’) and a low loss tangent (tan δ). Specifically disclosed is a rubber composition characterized by containing 2-60 parts by mass of a low molecular-weight aromatic vinyl compound-conjugated diene compound copolymer (B) having at least one functional group per 100 parts by mass of a rubber component (A). The rubber component (A) is composed of at least one rubber selected from natural rubbers and synthetic diene rubbers. The low molecular-weight aromatic vinyl compound-conjugated diene compound (B) is characterized in that the aromatic vinyl compound content is 5-80% by mass, the vinyl bond content in the conjugated diene compound unit is 5-80% by mass, and the weight average molecular weight in terms of polystyrene as determined by gel permeation chromatography is 5,000-500,000.
摘要:
A rubber composition for tire sidewall which comprises a rubber component, which comprises polybutadiene rubber having a content of the cis-1,4-bond of 92% or greater and a content of the vinyl bond of 1.5% or smaller and natural rubber and/or at least one other diene-based synthetic rubber, and 10 to 70 parts by mass of carbon black having a specific surface area by nitrogen adsorption of 20 to 100 m 2 /g per 100 parts by mass of the rubber component and does not comprise a softener having an aniline point of 50°C or lower and a tire using the rubber composition for sidewall. Excellent resistance to cut growth is obtained while sufficient workability is surely exhibited.
摘要:
A method for producing a rubber-filler master batch which comprises mixing a rubber solution obtained by dissolving a diene-based rubber in an organic solvent into a slurry obtained by dispersing in water, in advance, carbon black, silica and/or at least one inorganic filler represented by the following general formula (I): €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒnM 1 ·xSiO y ·zH 2 O€ƒ€ƒ€ƒ€ƒ€ƒ(I) [wherein M 1 represents at least one selected from the group consisting of metals which are aluminum, magnesium, titanium, calcium and zirconium, oxides and hydroxides of the metals, hydrates thereof and carbonates of the metals, and n, x, y and z respectively represent an integer of 1 to 5, an integer of 0 to 10, an integer of 2 to 5 and an integer of 0 to 10.]
摘要:
A rubber composition comprises 10 to 70 parts by mass of carbon black having 20 to 100 m 2 /g of the specific surface area by nitrogen adsorption per 100 parts by mass of a rubber component comprising 20 to 80 parts by mass of a modified polybutadiene rubber and 80 to 20 parts by mass of natural rubber and/or at least one other diene-based synthetic rubber, wherein the modified polybutadiene is obtained by polymerizing 1,3-butadiene in an organic solvent using a compound having a rare earth element of the lanthanoid series, followed by modifying the obtained polybutadiene, and has a content of the cis-1,4-bond of 92% or greater, a content of vinyl bond of 1.5% or smaller and a fraction of the modified chain end of 20% or greater; and a tire using the rubber composition for a sidewall. The rubber composition exhibits excellent low heat buildup property and resistance to fracture.
摘要:
A method for producing a rubber-filler master batch which comprises mixing a rubber solution obtained by dissolving a diene-based rubber in an organic solvent into a slurry obtained by dispersing in water, in advance, carbon black, silica and/or at least one inorganic filler represented by the following general formula (I):
nM 1 ·xSiO y ·zH 2 O (I)
[wherein M 1 represents at least one selected from the group consisting of metals which are aluminum, magnesium, titanium, calcium and zirconium, oxides and hydroxides of the metals, hydrates thereof and carbonates of the metals, and n, x, y and z respectively represent an integer of 1 to 5, an integer of 0 to 10, an integer of 2 to 5 and an integer of 0 to 10.]
摘要:
The invention provides a method for producing a modified conjugated diene (co)polymer, the method including comprising: a modification reaction step including causing an organic silane compound to react with a conjugated diene (co)polymer having an active site at the active site, the organic silane compound having a characteristic group for forming a silanol group through hydrolysis and, in the vicinity of the characteristic group, (i) a functional group which binds the organic silane compound to the conjugated diene (co)polymer via addition to or substitution at the active site and which promotes reaction between the silanol group and a reinforcing filler after the addition or substitution reaction, or (ii) a functional group which promotes reaction between the silanol group and a reinforcing filler, and a hydrolyzation step performed after the modification reaction step; a modified conjugated diene (co)polymer having, at a molecular end of the conjugated diene (co)polymer, a silanol group, and a functional group in the vicinity of the silanol group, the functional group accelerating reaction between the silanol group and the reinforcing filler; a rubber composition containing the (co)polymer and carbon black having specific characteristics; and a tire formed from the rubber composition.
摘要:
The invention provides a method for producing a modified conjugated diene (co)polymer, the method including comprising: a modification reaction step including causing an organic silane compound to react with a conjugated diene (co)polymer having an active site at the active site, the organic silane compound having a characteristic group for forming a silanol group through hydrolysis and, in the vicinity of the characteristic group, (i) a functional group which binds the organic silane compound to the conjugated diene (co)polymer via addition to or substitution at the active site and which promotes reaction between the silanol group and a reinforcing filler after the addition or substitution reaction, or (ii) a functional group which promotes reaction between the silanol group and a reinforcing filler, and a hydrolyzation step performed after the modification reaction step; a modified conjugated diene (co)polymer having, at a molecular end of the conjugated diene (co)polymer, a silanol group, and a functional group in the vicinity of the silanol group, the functional group accelerating reaction between the silanol group and the reinforcing filler; a rubber composition containing the (co)polymer and carbon black having specific characteristics; and a tire formed from the rubber composition.
摘要:
The invention provides a process for producing a modified conjugated diene based polymer which attains favorable interaction between a rubber component and carbon black and/or silica, thereby improving dispersibility of the fillers, and which exhibits excellent properties such as heat-buildup-suppressing performance, fracture characteristics, and wear resistance; a modified conjugated diene based polymer produced through the process; a rubber composition containing the diene polymer; and a tire produced from the rubber composition and exhibiting the above properties. The process for producing a modified conjugated diene based polymer includes a step (a) of reacting a silicon compound with a conjugated diene based polymer having an active end so that the reaction takes place at the active end, the silicon compound having a protected primary amino group in the molecule thereof and a bi-functional silicon atom to which a hydrocarbyloxy group and a reactive group are bonded, to thereby modify the active end, and a step (b) of performing condensation reaction which involves the compound having a bi-functional silicon atom, in the presence of a titanium compound serving as a titanium-based condensation-accelerating agent.
摘要:
A rubber composition for tire sidewall which comprises a rubber component, which comprises polybutadiene rubber having a content of the cis-1,4-bond of 92% or greater and a content of the vinyl bond of 1.5% or smaller and natural rubber and/or at least one other diene-based synthetic rubber, and 10 to 70 parts by mass of carbon black having a specific surface area by nitrogen adsorption of 20 to 100 m 2 /g per 100 parts by mass of the rubber component and does not comprise a softener having an aniline point of 50°C or lower and a tire using the rubber composition for sidewall. Excellent resistance to cut growth is obtained while sufficient workability is surely exhibited.