LOW MOLECULAR WEIGHT HIGH-CIS POLYBUTADIENES
    2.
    发明授权
    LOW MOLECULAR WEIGHT HIGH-CIS POLYBUTADIENES 有权
    低分子高顺式含量

    公开(公告)号:EP1189983B1

    公开(公告)日:2010-04-21

    申请号:EP00936192.4

    申请日:2000-05-19

    IPC分类号: C08L9/00 C08F36/06 C08F4/54

    摘要: A process for polymerizing 1,3-butadiene into a low molecular weight high-cis polybutadiene is described using a catalyst system comprising: (a) a neodymium-containing compound, (b) an aluminoxane or a trialkyl aluminum compound, (c) an organoaluminum hydride, and (d) a halogen source. A blend of a high molecular weight high-cis polybutadiene and the low molecular weight high-cis polybutadiene is also disclosed for use in pneumatic tire treads. Desirably both the high and the low molecular weight polymers have high cis contents, with the low molecular weight polymer being at least 70 percent cis and the high molecular weight polymer being at least 92 percent cis. Desirably both polymers are made with a neodymium catalyst system. The blends provide a balance of properties including good snow traction, wet traction, and rolling resistance while providing a balance of good physical properties including tension at break, modulus etc.

    LOW MOLECULAR WEIGHT HIGH-CIS POLYBUTADIENES
    6.
    发明公开
    LOW MOLECULAR WEIGHT HIGH-CIS POLYBUTADIENES 有权
    低分子高顺式含量

    公开(公告)号:EP1189983A2

    公开(公告)日:2002-03-27

    申请号:EP00936192.4

    申请日:2000-05-19

    IPC分类号: C08L9/00 C08F36/06 C08F4/54

    摘要: A process for polymerizing 1,3-butadiene into a low molecular weight high-cis polybutadiene is described using a catalyst system comprising: (a) a neodymium-containing compound, (b) an aluminoxane or a trialkyl aluminum compound, (c) an organoaluminum hydride, and (d) a halogen source. A blend of a high molecular weight high-cis polybutadiene and the low molecular weight high-cis polybutadiene is also disclosed for use in pneumatic tire treads. Desirably both the high and the low molecular weight polymers have high cis contents, with the low molecular weight polymer being at least 70 percent cis and the high molecular weight polymer being at least 92 percent cis. Desirably both polymers are made with a neodymium catalyst system. The blends provide a balance of properties including good snow traction, wet traction, and rolling resistance while providing a balance of good physical properties including tension at break, modulus etc.